bis-β-phenylethylmercury | 956-73-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-β-phenylethylmercury
• 英文别名: bis(2-phenylethyl)mercury；bis(2-phenethyl)mercury；diphenethyl-mercury；Diphenaethyl-quecksilber
• CAS: 956-73-0
• 化学式: C₁₆H₁₈Hg
• 分子量: 410.909
• InChiKey: SPQVESFYZCFQQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.39
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis-β-phenylethylmercury 在 lithium 作用下， 以 甲苯 为溶剂， 反应 48.0h， 以64%的产率得到苯乙基锂
  参考文献：
  名称：

  (Phenylalkyl)palladium Complexes Containing β-Hydrogen Atoms: Synthesis and Characterization of [PdR2(dppe)], [PdR(SPh)(dppe)] (R = CH2CH2Ph, CH2CH2CH2Ph, CH2CHMePh), and [Pd(CH2CH2CH2Ph)X(dppe)] (X = I, Br, Cl)

  摘要：

  DOI：

  10.1002/1099-0682(200211)2002:11<2868::aid-ejic2868>3.0.co;2-s
• 作为产物：
  描述：

  Phenethylmagnesium chloride 在 mercury dichloride 作用下， 以 乙醚 为溶剂， 生成 氯(2-苯基乙基)汞 、 bis-β-phenylethylmercury
  参考文献：
  名称：

  Criegee, R.; Dimroth, P.; Schempf, R., Chemische Berichte, 1957, vol. 90, p. 1337 - 1342

  摘要：

  DOI：

文献信息

• Synthesis, Structure, and Reactivity of O-Donor Ir(III) Complexes:  C−H Activation Studies with Benzene
  作者：Gaurav Bhalla、Xiang Yang Liu、Jonas Oxgaard、William A. Goddard、Roy A. Periana

  DOI：10.1021/ja051532o

  日期：2005.8.1

  water-stable alkyl and aryl analogues of (acac-O,O)2Ir(R)(L), R-Ir-L (acac-O,O = kappa2-O,O-acetylacetonate, -Ir- is the trans-(acac-O,O)2Ir(III) motif, R = CH3, C2H5, Ph, PhCH2CH2, L = Py) have been synthesized using the dinuclear complex [Ir(mu-acac-O,O,C3)-(acac-O,O)(acac-C3)]2, [acac-C-Ir]2, or acac-C-Ir-H2O. The dinuclear Ir (III) complexes, [Ir(mu-acac-O,O,C3)-(acac-O,O)(R)]2 (R = alkyl), show fluxional

  (acac-O,O)2Ir(R)(L), R-Ir-L（acac-O,O = kappa2-O,O-乙酰丙酮化物，-）的各种新的热空气和水稳定的烷基和芳基类似物Ir- 是反式-(acac-O,O)2Ir(III) 基序，R = CH3, C2H5, Ph, PhCH2CH2, L = Py) 已使用双核复合物 [Ir(mu-acac-O,O ,C3)-(acac-O,O)(acac-C3)]2、[acac-C-Ir]2 或 acac-C-Ir-H2O。双核 Ir (III) 配合物 [Ir(mu-acac-O,O,C3)-(acac-O,O)(R)]2 (R = 烷基)，显示出具有五坐标的通量行为，16通过解离途径形成电子复合物。吡啶加合物 R-Ir-Py 通过具有 Ph-Ir-Py 激活参数的解离机制进行简并 Py 交换（deltaH++ = 22.8 +/- 0.5 kcal/mol；deltaS++
• Preparation of polyfunctional diorganomercurials and their transmetallation to diorganozincs. Applications to the preparation of optically active secon
  作者：Michael J. Rozema、Duddu Rajagopal、Charles E. Tucker、Paul Knochel

  DOI：10.1016/0022-328x(92)88002-z

  日期：1992.10

  Two new methods of preparation of functionalized diorganomercurials have been developed. The first method involves a substitution reaction of (ICH2)2Hg with zinc-copper reagents FG-RCu(CN)ZnI in THF/DMF at - 60-degrees-C. Functional groups such as an ester, nitrile, ketone, phosphonate, halide, and boronic ester are tolerated in this reaction. The second method involves a reductive transmetallation between polyfunctional organozinc halides and mercurous chloride (Hg2Cl2). This very convenient procedure provides a rapid route to various functionalized diorganomercurials in good yields (61-89% yield). The synthetic utility of these mercury organometallics is demonstrated. Their transmetallation with zinc dust (toluene, 80-degrees-C, 3-5 h) affords dialkylzincs which add enantioselectively to aldehydes in the presence of a catalytic amount (20 mol%) of the norephedrine derivative 13. This transmetallation can also be used to prepare stereoselectively (E)-alkenylzinc halides (> 98% E). Addition of Cl(H)ZrCp2 to (E)-5-chloropentenylzinc bromide in CH2Cl2 (25-degrees-C, 1 min) affords a 1,1-bimetallic of zinc and zirconium Cl(CH2)4CH(ZnBr)ZrCp2(Cl) which reacts stereoselectively with an aldehyde providing the (E)-disubstituted olefin (49% yield; 100% E).
• �ber die Zersetzung von symmetrischen quecksilberorganischen Verbindungen mit Salzs�ure
  作者：Friedrich Nerdel、Samuel Makower

  DOI：10.1007/bf00635560

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B2, 110, page 628 - 631
  作者：

  DOI：——

  日期：——
• Criegee et al., Chemische Berichte, 1957, vol. 90, p. 1337,1342
  作者：Criegee et al.

  DOI：——

  日期：——