2-(4-tert-butylphenyl)-imidazo[4,5-f]-1,10-phenanthroline | 865169-10-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2-(4-tert-butylphenyl)-imidazo[4,5-f]-1,10-phenanthroline
• 英文别名: 2-(4-tert-butylphenyl)imidazo[4,5-f]-1,10-phenanthroline；bpimp；2-(4-tert-butylphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline
• CAS: 865169-10-4
• 化学式: C₂₃H₂₀N₄
• 分子量: 352.439
• InChiKey: CFFMHVPWVSRXJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  54.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(4-tert-butylphenyl)-imidazo[4,5-f]-1,10-phenanthroline 在 tBuOK or Et₃N 作用下， 以 甲醇 、 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Platinum(II) imidazo[4,5-f]-1,10-phenanthroline chloride and thiolate complexes: Synthesis and crystal structures

  摘要：

  The planar aromatic imidazo[4,5-f]-1,10-phenanthroline ligands have been used to prepare platinum(II) chloride and thiolate complexes. The X-ray structures of two thiolate compounds are reported, which show column-like packing in the solid state due to intermolecular aromatic pi-pi interactions. The compounds absorb moderately in the visible region, owing to {charge-transfer-to-diimine} electronic transition. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.007

文献信息

• Zn^IIComplexes Coordinated by Fluorescent Ligand 2-(4-<i>tert</i>-Butylphenyl)imidazo[4,5-<i>f</i>]-1,10-phenanthroline
  作者：Tomoharu Ama、Takahiko Sakaguchi、Katsuhira Yoshida、Masanori Yamaguchi

  DOI：10.1246/cl.2009.508

  日期：2009.5.5

  New ZnII complexes with fluorescent ligand [Zn(bpimp)3]X2 (bpimp: 2-(4-tert-butylphenyl)imidazo[4,5-f]-1,10-phenanthroline) were prepared. While the ligand does not exhibit fluorescence in the solid state, the new ZnII complexes exhibit fluorescence in solution and solid states. On the other hand, NiII– and CoII–bpimp complexes do not exhibit strong fluorescence in solution and in the solid states.

  新型锌(II)配合物 [Zn(bpimp)3]X2（bpimp: 2-(4-叔丁基苯基)咪唑[4,5-f]-1,10-菲啰啉）被制备出来。虽然该配体在固态下不表现出荧光，但新型锌(II)配合物在溶液和固态下均表现出荧光。另一方面，镍(II)和钴(II)的 bpimp 配合物在溶液和固态下均未表现出强荧光。