1-(2-phenylbenzo[b]thiophen-3-yl)perfluorocyclopentene | 1337915-86-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 1-(2-phenylbenzo[b]thiophen-3-yl)perfluorocyclopentene
• CAS: 1337915-86-2
• 化学式: C₁₉H₉F₇S
• 分子量: 402.335
• InChiKey: JUUOZAQIZGCEJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.17
• 重原子数：
  27.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  1,1-dimethyl-3-iodo-2-phenylbenzo[b]silole 、 1-(2-phenylbenzo[b]thiophen-3-yl)perfluorocyclopentene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以12%的产率得到1-(1,1-dimethyl-2-phenylbenzo[b]silol-3-yl)-2-(2-phenylbenzo[b]thiophen-3-yl)perfluorocyclopentene
  参考文献：
  名称：

  Photochromism of diarylethene derivatives bearing a benzo[b]silole unit

  摘要：

  Photochromic benzo[b]silole derivatives, 1-(1,1-dimethyl-2-phenylbenzo[b]silol-3-yl)-2-(2-phenylbenzo[b]thien-3-yl)perfluorocyclopentene and 1-(1,1-dimethyl-2-phenylbenzo[b]silol-3-yl)-2-(2-phenyl-1-benzofuran-3-yl)perfluorocyclopentene, were synthesized and their photochromic performance was examined in solution. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.08.063
• 作为产物：
  描述：

  3-bromo-2-phenylbenzo[b]thiophene 、 全氟环戊烯 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以32%的产率得到3,3'-(perfluorocyclopent-1-ene-1,2-diyl)bis(2-phenylbenzo[b]thiophene)
  参考文献：
  名称：

  Photochromism of diarylethene derivatives bearing a benzo[b]silole unit

  摘要：

  Photochromic benzo[b]silole derivatives, 1-(1,1-dimethyl-2-phenylbenzo[b]silol-3-yl)-2-(2-phenylbenzo[b]thien-3-yl)perfluorocyclopentene and 1-(1,1-dimethyl-2-phenylbenzo[b]silol-3-yl)-2-(2-phenyl-1-benzofuran-3-yl)perfluorocyclopentene, were synthesized and their photochromic performance was examined in solution. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.08.063