2-硝基-1-萘甲酸 | 91059-58-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-硝基-1-萘甲酸
• 英文名称: 2-nitro-[1]naphthoic acid
• 英文别名: 2-Nitro-[1]naphthoesaeure；2-Nitro-naphthoesaeure-(1)；2-Nitro-naphthoesaeure-1；2-Nitronaphthalene-1-carboxylic acid
• CAS: 91059-58-4
• 化学式: C₁₁H₇NO₄
• 分子量: 217.181
• InChiKey: OKTCWIPWLOOKDD-UHFFFAOYSA-N

物化性质

• 沸点：
  445.2±28.0 °C(Predicted)
• 密度：
  1.468±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  83.1
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-溴-1-甲基-2-硝基萘 在 吡啶 、 氢氧化钾 、 sodium hydroxide 、 potassium permanganate 、 potassium ethoxide 、 乙酸酐 、 copper(II) oxide 作用下， 生成 2-硝基-1-萘甲酸
  参考文献：
  名称：

  Topsom; Vaughan, Journal of the Chemical Society, 1957, p. 2842

  摘要：

  DOI：

文献信息

• A hydrolyzable resin composition and an antifouling coating composition containing the same
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0204456A1

  公开（公告）日：1986-12-10

  A hydrolyzable resin composition based on a resin having at least one side chain bearing a particular metal containing terminal group. There is also provided an antifouling coating composition containing such a hydrolyzable resin composition as a resinous vehicle. More particularly, the resin has at least one side chain bearing at least one terminal group of the formula where M is a metal selected from zinc, copper and tellurium, and X and R are particularly defined.

  一种可水解树脂组合物，它基于一种树脂，该树脂至少有一个侧链带有特定的含金属末端基团。此外，还提供了一种防污涂料组合物，其中含有这种作为树脂载体的可水解树脂组合物。更具体地说，该树脂具有至少一条侧链，其中至少含有一个式中的末端基团 其中 M 是选自锌、铜和碲的金属，X 和 R 特别定义。
• Resinous composition capable of releasing a bioactive substance at a controlled rate
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0220965A2

  公开（公告）日：1987-05-06

  A bioactive substance control-releasing resinous composition comprising a resin having main chain and side chains, at least one side chain bearing at the end portion thereof an organic acid moiety having a biological activity through a metal ester bonding. The resin is hydrolyzed in an ionic atmosphere at a controlled rate to generate a bioactive substance as well as metal ions and is useful in various field and especially as resinous vehicle of coating composition.

  一种生物活性物质控制释放树脂组合物，由具有主链和侧链的树脂组成，其中至少一条侧链的末端部分通过金属酯键连接具有生物活性的有机酸分子。该树脂在离子气氛中以可控速率水解，生成生物活性物质和金属离子，可用于各种领域，特别是用作涂料组合物的树脂载体。
• Disintegration type resin particles, its preparation and coating composition containing the same
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0286243A1

  公开（公告）日：1988-10-12

  Disintegration type resin particles having an average grain diameter of 0.01 to 250u. and being composed of a crosslinked resin having at least one crosslinking structure carried metal ester bond of the formula: R1 is a monovalent, bioactive organic acid residue; M stands for a polyvalent metal having a valence of 3 or more; m is an integer of 2 or more; n is an integer of 1 or more, providing that the sum of m and n is equal to the valence of said metal @, and a coating composition containing said resin particles are provided. The coating obtained is characterized in that it is gradually hydrolyzed in an ionic atmosphere as in sea water and dissolved out, liberating a bioactive organic acid as well as metal ions.

  崩解型树脂颗粒，其平均粒径为 0.01 至 250u： R1 是一价的生物活性有机酸残基；M 代表价数为 3 或更多的多价金属；m 是 2 或更多的整数；n 是 1 或更多的整数，条件是 m 和 n 的总和等于所述金属 @ 的价数；本发明还提供了一种含有所述树脂颗粒的涂料组合物。所获得的涂层的特征在于，它在海水等离子环境中逐渐水解并溶解，释放出生物活性有机酸和金属离子。
• Metal-containing monomer dissolved mixture, metal-containing resin and antifouling paint composition
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP1167398A2

  公开（公告）日：2002-01-02

  A metal-containing monomer dissolved mixture comprising a reaction product of an inorganic metal compound with a carboxyl group-containing radical polymerizable monomer, an organic solvent including at least an alcohol-based solvent, and water, wherein the water content is from 0.01 to 30% by weight; a metal-containing resin obtained by copolymerizing the metal-containing monomer (A) in this dissolved mixture with the other radical-polymerizable unsaturated monomer (B); an antifouling paint composition obtained by using this metal-containing resin; and an antifouling paint composition comprising a divalent metal-containing resin (C), a compound (D) of R1-SH (wherein, R1 represents an organic group having 1 to 30 carbon atoms.), and copper oxide (E), are disclosed.

  一种含金属单体的溶解混合物，包括无机金属化合物与含羧基可自由基聚合单体的反应产物、有机溶剂（至少包括醇基溶剂）和水，其中水含量为 0.本发明公开了一种无机金属化合物与含羧基的可自由基聚合单体和水的混合物，其中水含量为 0.01 至 30% (重量)；一种含金属树脂，通过将该溶解混合物中的含金属单体 (A) 与另一种可自由基聚合的不饱和单体 (B) 共聚而获得；一种防污漆组合物，通过使用该含金属树脂而获得；以及一种防污漆组合物，包括二价含金属树脂 (C)、R1-SH 的化合物 (D) (其中，R1 代表具有 1 至 30 个碳原子的有机基团。) 和氧化铜 (E)。
• TRIPHENYLBORON-CONTAINING POLYMERS AND USE THEREOF
  申请人：Yoshitomi Fine Chemicals, Ltd.

  公开号：EP1227111A1

  公开（公告）日：2002-07-31

  A polymer containing a triphenylboron-containing constituting unit of the formula [I]: wherein each symbol is as defined in the specification, shows a superior adhesion-preventive effect against aquatic fouling organisms, such as coelenterates, shellfish, tubicolous polychaetes and the like, for a long time, shows a function of not only an active ingredient but also a binder, the polymer characteristically shows fine miscibility with other coating resins and a less adverse influence on the environment. Therefore, it can be used as a superior preventive of fouling due to the adhesion of aquatic fouling organisms.

  一种含有式[I]的含三苯基硼构成单元的聚合物： 其中各符号如本说明书所定义，对水生污损生物（如腔肠动物、贝类、管状多毛类动物等）具有卓越的长期防污效果，不仅具有活性成分的功能，还具有粘合剂的功能，该聚合物与其他涂层树脂具有良好的混溶性，对环境的不利影响较小。因此，它可用作防止水生污损生物附着造成污损的优质防污剂。