[Me4Pt2(1,2,4,5-tetrakis(6-tert-butylquinolin-8-yl)benzene)] | 1089179-16-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Me4Pt2(1,2,4,5-tetrakis(6-tert-butylquinolin-8-yl)benzene)]
• 英文别名: 6-tert-butyl-8-[2,4,5-tris(6-tert-butylquinolin-8-yl)phenyl]quinoline;carbanide;platinum(2+)
• CAS: 1089179-16-7
• 化学式: C₆₂H₇₀N₄Pt₂
• 分子量: 1261.42
• InChiKey: VTVSRINIGAFNFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.53
• 重原子数：
  68
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  氯仿 、 [Me4Pt2(1,2,4,5-tetrakis(6-tert-butylquinolin-8-yl)benzene)] 以 氯仿 为溶剂， 以94%的产率得到
  参考文献：
  名称：

  Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization

  摘要：

  Three novel tetradentate ligands with quinoline functionalities, 1,2,4,5-tetrakis(6-ethylquinolin-8-yl)benzene, 1,2,4,5-tetrakis(6-tert-butylquinolin-8-yl)benzene, and 1,2,4,5-tetrakis(6-(trifluoromethoxy)quinolin-8-yl)benzene, were synthesized through a three-step protocol and fully characterized by NMR spectroscopic, elemental, and X-ray diffraction analyses. The dinuclear dimethylplatinum(II) complexes of these ligands readily activate C-Cl bonds of CHCl3 at ambient temperature, leading to the formation of the corresponding dinuclear Pt(IV) complex. In these reactions, the central phenyl rings of the tetradentate ligands are reduced to cyclohexadiene dianions and still retain their planarity.

  DOI：

  10.1021/om800893r
• 作为产物：
  描述：

  bis[dimethyl(μ-dimethylsulfide)platinum(II)] 、 1,2,4,5-tetrakis(6-tert-butylquinolin-8-yl)benzene 以 四氢呋喃 、 乙醚 为溶剂， 以87%的产率得到[Me4Pt2(1,2,4,5-tetrakis(6-tert-butylquinolin-8-yl)benzene)]
  参考文献：
  名称：

  Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization

  摘要：

  Three novel tetradentate ligands with quinoline functionalities, 1,2,4,5-tetrakis(6-ethylquinolin-8-yl)benzene, 1,2,4,5-tetrakis(6-tert-butylquinolin-8-yl)benzene, and 1,2,4,5-tetrakis(6-(trifluoromethoxy)quinolin-8-yl)benzene, were synthesized through a three-step protocol and fully characterized by NMR spectroscopic, elemental, and X-ray diffraction analyses. The dinuclear dimethylplatinum(II) complexes of these ligands readily activate C-Cl bonds of CHCl3 at ambient temperature, leading to the formation of the corresponding dinuclear Pt(IV) complex. In these reactions, the central phenyl rings of the tetradentate ligands are reduced to cyclohexadiene dianions and still retain their planarity.

  DOI：

  10.1021/om800893r