di-9-fluorenyl sulfide | 1053-93-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: di-9-fluorenyl sulfide
• 英文别名: di-fluoren-9-yl sulfide；Di-fluoren-9-yl-sulfid；Bis--sulfid；Difluorenyl-(9.9')-sulfid；Di-fluorenyl-(9)-sulfid；Difluorenyl-(9)-sulfid；9-(9H-fluoren-9-ylsulfanyl)-9H-fluorene
• CAS: 1053-93-6
• 化学式: C₂₆H₁₈S
• 分子量: 362.495
• InChiKey: HEXHWNCJCVNKNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  di-9-fluorenyl sulfide 在 双氧水 作用下， 以 溶剂黄146 为溶剂， 生成 di-fluoren-9-yl sulfone
  参考文献：
  名称：

  芴的脂肪族化学：第八部分。苄基 9-氟代亚砜和一些 9-氟代亚砜

  摘要：

  烯丙基 9-芴基硫化物、苄基 9-芴基硫化物和二-9-芴基硫化物对沸腾的醚苯基锂稳定，与相应的醚形成鲜明对比。已经制备了苄基 9-芴基亚砜，并且显示出比 9-芴基砜更弱的酸性。

  DOI：

  10.1139/v62-037
• 作为产物：
  描述：

  9-氯芴 在 sodium hydrogensulfide 、 乙醇 作用下， 生成 di-9-fluorenyl sulfide
  参考文献：
  名称：

  Bergmann; Hervey, Chemische Berichte, 1929, vol. 62, p. 915

  摘要：

  DOI：

文献信息

• Studies of reactions leading to sulfine formation. 6. Base-catalyzed decomposition of di-9-fluorenyl sulfoxide
  作者：John L. Kice、Lidia Kupczyk-Subotkowska

  DOI：10.1021/jo00004a018

  日期：1991.2

  When treated with CH3ONa in CH3OH-CH2Cl2, di-9-fluorenyl sulfoxide (3) undergoes elimination readily to afford 9-thiofluorenone S-oxide (4) and fluorene (eq 2). Comparison of the rate of the elimination to the rate of disappearance in the presence of CD3OD of the H-1 NMR signal for the 9-H in 3 shows that the mechanism of this sulfine-forming elimination is (E1cB)rev, the rate of cleavage of the intermediate alpha-sulfinyl carbanion 7 to give 4 and a 9-fluorenyl carbanion being over 100 times slower than the rate at which 7 is protonated to regenerate 3. The (E1cB)rev behavior of this elimination is contrasted with the (E1cB)rev/(E1cB)irrev borderline behavior of the elimination of diarylmethyl (arylmethyl)sulfonyl sulfoxides 1, 2 and a reason for this at first sight unexpected difference in behavior is presented.
• ORGANIC LIGHT-EMITTING DEVICE AND DISPLAY APPARATUS
  申请人：Iwasaki Yohei

  公开号：US20090082439A1

  公开（公告）日：2009-03-26

  An organic light-emitting device adapted for coating and having good emission efficiency and luminance. The organic light-emitting device employs an anode, a cathode, and a layer including an organic compound sandwiched between the anode and cathode. The layer containing the organic compound includes a bisfluorene compound represented by General Formula [1] below. wherein in Formula [1], A is a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted silylene group, a substituted germylene group, an oxygen atom, and a sulfur atom.
• US7723915B2
  申请人：——

  公开号：US7723915B2

  公开（公告）日：2010-05-25
• US8673885B1
  申请人：——

  公开号：US8673885B1

  公开（公告）日：2014-03-18
• Bergmann; Hervey, Chemische Berichte, 1929, vol. 62, p. 915
  作者：Bergmann、Hervey

  DOI：——

  日期：——