(p-Methoxy-phenyldiazo)-phenyl-sulfid | 114650-58-7

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 炔丙基型1，3-偶极有机化合物
• 英文名称: (p-Methoxy-phenyldiazo)-phenyl-sulfid
• 英文别名: (4-Methoxyphenyl)diazo phenyl sulfide
• CAS: 114650-58-7
• 化学式: C₁₃H₁₂N₂OS
• 分子量: 244.317
• InChiKey: DWHSQHDXFVTELZ-CCEZHUSRSA-N

物化性质

• 熔点：
  47-48 °C
• 沸点：
  379.9±44.0 °C(Predicted)
• 密度：
  1.13±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.49
• 重原子数：
  17.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  33.95
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  氰化四丁基铵 、 (p-Methoxy-phenyldiazo)-phenyl-sulfid 以20%的产率得到
  参考文献：
  名称：

  PETRILLO, GIOVANNI;NOVI, MARINO;GARBARINO, GIACOMO;DELLERBA, CARLO, TETRAHEDRON, 43,(1987) N 20, 4625-4634

  摘要：

  DOI：
• 作为产物：
  描述：

  甲氧苯胺 、 苯硫酚 在 盐酸 、 sodium nitrite 作用下， 生成 (p-Methoxy-phenyldiazo)-phenyl-sulfid
  参考文献：
  名称：

  Aromatic fluorination by silver-ion promoted decomposition of aryl diazo sulfides: efficient utilization of substoichiometric levels of fluoride ion

  摘要：

  DOI：

  10.1021/jo00016a040

文献信息

• Fast, efficient and convenient method for the preparation of arylazo sulfides using aryl diazonium silica sulfates under mild and solvent-free conditions
  作者：Amin Zarei、Leila Khazdooz、Abdol R. Hajipour、Hamidreza Aghaei

  DOI：10.1016/j.dyepig.2011.02.010

  日期：2011.10

  An efficient, fast, and straightforward procedure for the synthesis of arylazo sulfides and arylazo thiosulfonates is described in the present paper by using aryl diazonium silica sulfates and sodium thiolates. Using the present method, different kinds of aryl diazonium silica sulfates, containing electron-withdrawing groups as well as electron-donating groups, were rapidly converted to the corresponding arylazo sulfides in good yield and short reaction time. These reactions were carried out at room temperature under mild and solvent-free conditions. The use of non-toxic and inexpensive materials, simple and clean work-up, short reaction times and good yields are the advantages of this method. (C) 2011 Elsevier Ltd. All rights reserved.