cis,cis-1,3,5-tris-(diphenylphosphino)cyclohexane | 156835-67-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis,cis-1,3,5-tris-(diphenylphosphino)cyclohexane
• 英文别名: 1,3,5-cis,cis-tris(diphenylphosphino)cyclohexane；cis,cis-1,3,5-tris(diphenylphosphino)cyclohexane
• CAS: 156835-67-5
• 化学式: C₄₂H₃₉P₃
• 分子量: 636.693
• InChiKey: VLFOIOMLYCWRFS-CFPDXYPDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.67
• 重原子数：
  45.0
• 可旋转键数：
  9.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  三羰基环庚三烯基钼 、 cis,cis-1,3,5-tris-(diphenylphosphino)cyclohexane 以 甲苯 为溶剂， 以60%的产率得到tricarbonyl[cis,cis-1,3,5-tris(diphenylphosphino)cyclohexane]molybdenum(0)
  参考文献：
  名称：

  cis,cis-1,3,5-Tris(diphenylphosphino)cyclohexane (tdppcy). A new tripodal phosphine that forms metal complexes with adamantane-type structures. rystal structure of Ir(tdppcy)Cl3

  摘要：

  The novel tridentate phosphine cis,cis-1,3,5-tris(diphenylphosphino)cyclohexane (tdppcy) (3) has been synthesized. Treatment of tdppcy with Mo(C7H8)(CO)3 and lr(PPh3)2(CO)CI yields octahedral Mo(tdppcy)(CO)3 (4) and trigonal-bipyramidal Ir(tdppcy)(CO)Cl.(5), respectively. Compound S is transformed into either Ir(tdppcy)(CO)H (6) or lr(tdppcy)(CO)(H)2+ (7) by treatment with NaBH4 in refluxing THF. Complex 5 can be oxidized by dichloromethane or Cl2 to the trichloro complex lr(tdppcy)Cl3 (8), which can be converted into the dihydride Ir(tdppcy)(H)2Cl (9) by treatment with NaBH4 in THF. The dynamic behavior of the highly fluxional pentacoordinate complexes 5 and 6 has been studied by VT P-31{H-1} NMR spectroscopy. An X-ray diffraction study has been carried out on 8 . 3CH2Cl2.

  DOI：

  10.1016/0022-328x(94)80221-1
• 作为产物：
  描述：

  cis,cis-1,3,5-cyclohexanetritosylate 、 二苯基膦 在 正丁基锂 作用下， 生成 cis,cis-1,3,5-tris-(diphenylphosphino)cyclohexane
  参考文献：
  名称：

  cis,cis-1,3,5-Tris(diphenylphosphino)cyclohexane (tdppcy). A new tripodal phosphine that forms metal complexes with adamantane-type structures. rystal structure of Ir(tdppcy)Cl3

  摘要：

  The novel tridentate phosphine cis,cis-1,3,5-tris(diphenylphosphino)cyclohexane (tdppcy) (3) has been synthesized. Treatment of tdppcy with Mo(C7H8)(CO)3 and lr(PPh3)2(CO)CI yields octahedral Mo(tdppcy)(CO)3 (4) and trigonal-bipyramidal Ir(tdppcy)(CO)Cl.(5), respectively. Compound S is transformed into either Ir(tdppcy)(CO)H (6) or lr(tdppcy)(CO)(H)2+ (7) by treatment with NaBH4 in refluxing THF. Complex 5 can be oxidized by dichloromethane or Cl2 to the trichloro complex lr(tdppcy)Cl3 (8), which can be converted into the dihydride Ir(tdppcy)(H)2Cl (9) by treatment with NaBH4 in THF. The dynamic behavior of the highly fluxional pentacoordinate complexes 5 and 6 has been studied by VT P-31{H-1} NMR spectroscopy. An X-ray diffraction study has been carried out on 8 . 3CH2Cl2.

  DOI：

  10.1016/0022-328x(94)80221-1

文献信息

• Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm
  作者：Thomas Weyrich、Jan Krahmer、Tobias A. Engesser、Christian Näther、Felix Tuczek

  DOI：10.1039/c8dt04738c

  日期：——

  We report the first molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand. By employing several spectroscopic methods we are able to pinpoint the pentaphosphine environment and evaluate the activation of the dinitrogen ligand. Furthermore, we conduct protonation experiments and obtain spectroscopic evidence for the formation of a hydrazido-species.

  我们报告了由基于环己烷的三膦配体支持的第一个钼二氮配合物。通过采用几种光谱方法，我们能够查明五膦环境并评估二氮配体的活化。此外，我们进行质子化实验，并获得了形成肼苯二胺物种的光谱证据。