(Z)-1-phenyl-3-(2-propan-2-ylsulfanylethylamino)but-2-en-1-one | 1058113-01-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (Z)-1-phenyl-3-(2-propan-2-ylsulfanylethylamino)but-2-en-1-one
• CAS: 1058113-01-1
• 化学式: C₁₅H₂₁NOS
• 分子量: 263.404
• InChiKey: OUDCRLDLGZYBSQ-QBFSEMIESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-(异丙基硫代)乙胺 、 1-苯基-1,3-丁二酮 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 24.0h， 生成 (Z)-1-phenyl-3-(2-propan-2-ylsulfanylethylamino)but-2-en-1-one
  参考文献：
  名称：

  [O-NX] Ni（II）配合物的合成，表征和高选择性乙烯二聚为1-丁烯

  摘要：

  已经合成和表征了一系列镍（II）配合物。分子结构分析表明，采用了围绕镍的正方形平面几何形状。通过MAO活化后，这些镍（II）络合物可有效催化乙烯二聚，从而提供1-丁烯，其活性最高可达1.4×10 7 g /（mol·h·atm）。络合物中侧臂的杂原子被证明对1-丁烯的活性和选择性有很大的影响。

  DOI：

  10.1002/cjoc.201100443

文献信息

• ORGANIC COMPOUNDS CONTAINING HETEROATOMS AND THEIR USE IN ZIEGLER-NATTA CATALYST WITH SINGLE ACTIVATION CENTER
  申请人：SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES

  公开号：EP2039677A1

  公开（公告）日：2009-03-25

  Organic compounds containing heteroatoms and their use in preparing Ziegler-Natta (Z-N) catalyst with single activation center. The Z-N olefin polymerization catalyst is prepared by adding organic or inorganic solid carrier or compound of them which is pre-activated by heating or pre-treated chemically, organic compound containing heteroatoms and metallic compound into magnesium compound/tetrahydrofuran solution. The Z-N olefin polymerization catalyst prepared in the present invention is fluidizable powder and can prepare ethene homopolymer and copolymer of controllable construction with high catalytic activity, during homo-polymerization and combined polymerization with alpha-olefin of C3-C8 under action of catalyst promoter such as alkyl aluminium, alkyl aluminoxane, and so on.

  含有杂原子的有机化合物及其在制备具有单活化中心的齐格勒-纳塔（Z-N）催化剂中的应用。Z-N 烯烃聚合催化剂的制备方法是在镁化合物/四氢呋喃溶液中加入经加热预活化或化学预处理的有机或无机固体载体或它们的化合物、含杂原子的有机化合物和金属化合物。本发明制备的 Z-N 烯烃聚合催化剂为可流动粉末，在烷基铝、烷基铝氧烷等催化剂促进剂的作用下，与 C3-C8 α-烯烃进行均聚和联合聚合时，可制备结构可控、催化活性高的乙烯均聚物和共聚物。
• Organic compounds containing heteroatoms and their use in ziegler-natta catalyst with single activation center
  申请人：SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES

  公开号：EP2039677B1

  公开（公告）日：2014-04-23
• CLASS OF ORGANIC COMPOUNDS CONTAINING HETEROATOM AND ITS APPLICATIONS IN PREPARING SINGLE-SITE ZIEGLER-NATTA CATALYST
  申请人：TANG Yong

  公开号：US20090137383A1

  公开（公告）日：2009-05-28

  Organic compounds containing heteroatoms and their use in preparing Ziegler-Natta (Ziegler-Natta) catalyst with single activation center. The Ziegler-Natta olefin polymerization catalyst is preparing by adding organic or inorganic solid carrier or compound of them which is pre-activated by heating or pre-treated chemically, organic compound containing heteroatoms and metallic compound into magnesium compound/tetrahydrofuran solution. The Ziegler-Natta olefin polymerization catalyst prepared in the present invention is fluidizable powder and can prepare ethene homopolymer and copolymer of controllable construction with high catalytic activity, during homo-polymerization and combined polymerization with alpha-olefin of C 3 ˜C 18 under action of catalyst promoter such as alkyl aluminum, alkyl aluminoxane, and so on.
• Synthesis, Characterization, and Highly Selective Ethylene Dimerization to 1-Butene of [O−NX]Ni(II) Complexes
  作者：Chongjie Xu、Qi Shen、Xiuli Sun、Yong Tang

  DOI：10.1002/cjoc.201100443

  日期：2012.5

  series of nickel(II) complexes have been synthesized and characterized. Molecular structure analysis exhibits that a square planar geometry around nickel is adopted. Upon activation with MAO, these nickel(II) complexes are efficient in catalyzing the ethylene dimerization, providing 1‐butene with an activity of up to 1.4×107 g/(mol·h·atm). The heteroatoms of the sidearm in the complexes were proved to

  已经合成和表征了一系列镍（II）配合物。分子结构分析表明，采用了围绕镍的正方形平面几何形状。通过MAO活化后，这些镍（II）络合物可有效催化乙烯二聚，从而提供1-丁烯，其活性最高可达1.4×10 7 g /（mol·h·atm）。络合物中侧臂的杂原子被证明对1-丁烯的活性和选择性有很大的影响。