3,4-Dimethyl-1-mercaptomethyl-benzol | 4496-95-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4-Dimethyl-1-mercaptomethyl-benzol
• 英文别名: 3,4-Dimethylbenzylmercaptan；(3,4-dimethyl-phenyl)-methanethiol；(3,4-Dimethyl-phenyl)-methanthiol；(3,4-Dimethylphenyl)methanethiol
• CAS: 4496-95-1
• 化学式: C₉H₁₂S
• mdl: MFCD00176518
• 分子量: 152.26
• InChiKey: ZELNMWPKGYYFIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3,4-Dimethyl-1-mercaptomethyl-benzol 在 双氧水 、 溶剂黄146 、 碘甲烷 作用下， 生成 (3,4-dimethyl-benzyl)-methyl sulfone
  参考文献：
  名称：

  Miyasaki et al., Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1954, vol. 74, p. 723

  摘要：

  DOI：
• 作为产物：
  描述：

  3,4-二甲基氯苄 在 硫脲 作用下， 生成 3,4-Dimethyl-1-mercaptomethyl-benzol
  参考文献：
  名称：

  Cagniant,P. et al., Bulletin de la Societe Chimique de France, 1961, p. 2225 - 2235

  摘要：

  DOI：

文献信息

• Nitric Acid Mediated Oxidative Transformation of Thiols to Disulfides
  作者：Anup Kumar Misra、Geetanjali Agnihotri

  DOI：10.1081/scc-120028640

  日期：2004.12.31

  Abstract Oxidation of thiols to disulfides are reported using nitric acid/methylene chloride. Environmentally benign, economically convenient and simple reaction condition represents an attractive alternative to the existing approaches on both the laboratory and the industrial scale. #C.D.R.I. Communication No: 6412.

  摘要 据报道，使用硝酸/二氯甲烷将硫醇氧化成二硫化物。环境友好、经济方便和简单的反应条件代表了实验室和工业规模现有方法的有吸引力的替代方案。#CDRI 通讯编号：6412。
• Olefin polymerization catalyst and process for producing olefin polymer
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1081167A1

  公开（公告）日：2001-03-07

  An olefin polymerization catalyst prepared by contacting a specified transition metal compound(A) having a cyclopentadiene type anion skeletons in its molecule with a modified aluminum oxy compound (B) obtained by reacting an aluminum oxy compound(B1) with a compound having a hydroxyl group(B2), and a process for producing an olefin polymer using the olefin polymerization catalyst.

  一种烯烃聚合催化剂，其制备方法是将分子中含有环戊二烯型阴离子骨架的特定过渡金属化合物（A）与铝氧化合物（B1）和具有羟基的化合物（B2）反应得到的改性铝氧化合物（B）接触，以及使用该烯烃聚合催化剂生产烯烃聚合物的工艺。
• Catalyst component and catalyst for addition polymerization, and process for producing addition polymer
  申请人：——

  公开号：US20040186009A1

  公开（公告）日：2004-09-23

  A catlyst component obtained by a process comprising contacting (a), (b) and (c) described below, a catalyst for addition polymerization using the catalyst component, and a process for producing an addition polymer with the catalyst for addition polymerization: (a) a compound represented by the chemical formula, BiL 1 r , (b) a compound represented by the chemical formula, R 1 s-1 T 1 H, and (c) a compound represented by the chemical formula, R 2 t-2 T 2 H 2 , wherein r is a numeral corresponding to a valence of Bi; L 1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a hydrocarbon oxy group; respective T 1 and T 2 independently represents a non-metallic atom of Group 15 or 16 of the periodic table; s represents a numeral corresponding to a valence of T 1 ; t represents a numeral corresponding to a valence of T 2 ; R 1 is an electron-withdrawing group or an electron-withdrawing group-containing group; and R 2 represents a hydrocarbon group.

  一种通过以下工艺获得的催化剂组分，该工艺包括将下述(a)、(b)和(c)接触，使用该催化剂组分的加成聚合催化剂，以及使用该加成聚合催化剂生产加成聚合物的工艺： (a) 化学式为 BiL 1 r , (b) 化学式为 R 1 s-1 T 1 H，以及 (c) 化学式为 R 2 t-2 T 2 H 2 , 其中 r 是与 Bi 的化合价相对应的数字； L 1 是氢原子、卤素原子、烃基或烃氧基；各自的 T 1 和 T 2 分别代表元素周期表中第 15 或 16 族的非金属原子；s 代表与 T 1 代表与 T 1 的化合价相对应的数字； t 代表与 T 2 的化合价相对应的数字。 2 ; R 1 是一个吸电子基团或一个含电子吸附基团；以及 R 2 代表烃基。
• Metal compound, and catalyst component and catalyst for addition polymerization, and process for producing addition polymer
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20040209762A1

  公开（公告）日：2004-10-21

  A metal compound obtained by a process comprising the step of contacting, in a specific ratio, a compound represented by the formula M 1 L 1 r , a compound represented by the formula R 1 s-1 TH, and a compound represented by the formula R 2 4-n J(OH) n ; a catalyst component for addition polymerization comprising the metal compound; a catalyst for addition polymerization using the catalyst component; and a process for producing an addition polymer using the catalyst.

  一种金属化合物，通过以下工艺获得，该工艺包括以下步骤：按特定比例将式 M 所代表的化合物与以下物质接触 1 L 1 r 和式 R 1 s-1 TH 所代表的化合物，以及由式 R 2 4-n J(OH) n 由金属化合物组成的加成聚合催化剂组分；使用该催化剂组分进行加成聚合的催化剂；以及使用该催化剂生产加成聚合物的工艺。
• Contact product, and catalyst component and catalyst for addition polymerization, and process for producing addition polymer
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20040209767A1

  公开（公告）日：2004-10-21

  A contact product obtained by a process comprising the step of contacting a compound (a) represented by the formula, M 1 L 1 r , a compound (b) represented by the formula, R 1 s-1 T 1 H a compound (c) represented by the formula, R 2 t-2 T 2 H 2 , and a nonionic surfactant (d) having no active hydrogen; a catalyst component for addition polymerization comprising said contact product; a catalyst for addition polymerization obtained by a process comprising the step of contacting said catalyst component with a compound of a metal selected from the group consisting of metals of the Groups 3 to 12 and Lanthanide Series of the Periodic Table, and optionally an organoaluminum compound; and a process for producing an addition polymer comprising the step of polymerizing an addition polymerizable monomer in the presence of said catalyst.

  一种接触产品，其制备过程包括以下步骤：将由式 M 1 L 1 r 和由式 R 代表的化合物 (b) 1 s-1 T 1 H 由式 R 2 t-2 T 2 H 2 和无活性氢的非离子表面活性剂 (d)；加成聚合用催化剂组分，包括所述接触产物；加成聚合用催化剂，其工艺包括将所述催化剂组分与选自元素周期表第 3 至 12 族金属和镧系元素组成的金属化合物以及有机铝化合物接触的步骤；以及生产加成聚合物的工艺，包括在所述催化剂存在下聚合可加成聚合单体的步骤。