PtPh2(μ-[bis((diphenylphosphinoethyl)phenylphosphino)methane])PtPh2 | 518344-53-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: PtPh2(μ-[bis((diphenylphosphinoethyl)phenylphosphino)methane])PtPh2
• 英文别名: Pt2Ph4(μ-rac-[((diphenylphosphino)ethyl)phenylphosphino]methane)；[Pt2Ph4(μ-bis((diphenylphosphinoethyl)phenylphosphino)methane)]
• CAS: 518344-53-1；518344-54-2
• 化学式: C₆₅H₆₀P₄Pt₂
• 分子量: 1355.25
• InChiKey: GZSWVBCFMYRGEH-XUCAVMFKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ((R)-(2-(2-二苯基磷酰)乙基)(苯基)磷酰)((S)-(2-二苯基磷酰)乙基)(苯基)磷酰)甲烷 以 丙酮 为溶剂， 生成 PtPh2(μ-[bis((diphenylphosphinoethyl)phenylphosphino)methane])PtPh2
  参考文献：
  名称：

  Approaches to bi- and trimetallic platinum and palladium complexes using the DPPEPM ligand

  摘要：

  Bis {(diphenylphosphinoethyl)phenylphosphino}methane (DPPEPM) reacts with [PtR2(cod)] in 1:1 ratio to give [PtR2? (DPPEPM-PP)] (2a, R = Me; 2b, R = Ph), whereas with [PtCl2(cod)] or [PdCl2(cod)] it yields the ionic species [M(DPPEPM-PP)(2)](2+) (3 and 4). With [MClMe(cod)], the product is [MMe(DPPEPM-PPP)](+) (5, M Pt; 6, M = Pd), in which one of the internal P atoms of the ligand is uncoordinated. These complexes undergo oxidation of the free P atom to give 7 and 8 on standing in solution. Complexes 2-4 may be used to construct bimetallic and trimetallic mixed metal complexes. The molecular structures of 7 and [PtMe2(mu-DPPEPM)PdCl2] (11) are reported. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.08.004

文献信息

• Palladium and Platinum Complexes Containing the Linear Tetraphosphine Bis[((diphenylphosphino)ethyl)phenylphosphino]methane
  作者：Padma Nair、Gordon K. Anderson、Nigam P. Rath

  DOI：10.1021/om0209069

  日期：2003.3.1

  The linear tetraphosphine bis[((diphenylphosphino)ethyl)phenylphosphino]methane (DPPEPM) has been prepared and separated into its meso and racemic forms. Each has been reacted with elemental sulfur, and the structure of the meso compound DPPEPM-S4 has been determined crystallographically. The meso or racemic form of DPPEPM reacts with 2 equiv of [MCl2(cod)] (M = Pd, Pt) or [PtR2(cod)] (R = Me, Ph,

  制备了线性四膦基双[（（（二苯基膦基）乙基）苯基膦基]甲烷（DPPEPM），并将其分离为内消旋和外消旋形式。每种均已与元素硫反应，并且通过晶体学确定了内消旋化合物DPPEPM-S 4的结构。DPPEPM的内消旋或外消旋形式与2当量的[MCl 2（cod）]（M = Pd，Pt）或[PtR 2（cod）]（R = Me，Ph，CH 2 Ph，C 6 H 4 Me -4）形成[M 2 X 4（μ-DPPEPM）]形式的络合物，其中DPPEPM既充当螯合配体又是桥接配体。含其他氯桥的配合物，[M 2 R 2（μ-Cl）（μ-DPPEPM）] PF 6是由DPPEPM和[PtClR（cod）]（R = Me，Ph，CH 2 Ph），[PdClR（cod）]（R = Me，CH 2 Ph）或[Pd 2 R 2（μ-Cl）2（AsPh 3）2 ]（R = Ph，COMe），然后是TlPF 6。氯化物桥联的化合物也可以通过用1当量的TlPF
• Unsymmetrical complexes containing the linear tetraphosphine ligand DPPEPM
  作者：Padma Nair、Colin P. White、Gordon K. Anderson、Nigam P. Rath

  DOI：10.1016/j.jorganchem.2005.09.021

  日期：2006.1

  The tetraphosphine DPPEPM reacts with [PtMe2(cod)] to produce [PtMe2(DPPEPM-PP)] (1) in near quantitative yield. On standing in solution, the free P atoms become oxidized to give [PtMe2(DPPEPM(O)(2)-PP)] (1a), which has been characterized by X-ray crystallography. In contrast, reactions of DPPEPM with [MCl2(cod)] (M = Pd, Pt) yield ionic products of the form [M(DPPEPM-PP)2]MC]4 (3, 4). When a solution of the platinum complex was allowed to stand, crystals of [Pt(mu-Cl)(mu-DPPEPM)(2)]Cl-3 (5) were obtained. In a third set of reactions, treatment of [PtCIR(cod)] (R = Me, Ph) or [PdClMe(cod)] with DPPEPM gives species of the type [MR(DPPEPM-PPP)]Cl (6-8), in which one of the internal P atoms is uncoordinated. Reactions of [PtR2(DPPEPM-PP)] with [PtR2'(cod)] or [MCl2(Cod)] (M = Pd, Pt), or of [PtR(DPPEPM-PPP)]Cl with [MCl2(cod)], lead to unsymmetrical bimetallic complexes. [PtMe2(mu-DPPEPM)PdCl2] (11) and [PtClPh(mu-DPPEPM)PdCl2] (14) have been characterized crystallographically. Trimetallic complexes of the form [PtR2(mu-DPPEPM)}(2)M][MCl4] (M = Pd, Pt, 15-17) are produced by reaction of [PtR2(DPPEPM-PP)] with [MCl2(cod)]. (c) 2005 Elsevier B.V. All rights reserved.