N-{1-(2'-pyridyl)-1-oxo-2-ethyl}pyridinium iodide | 662148-54-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-{1-(2'-pyridyl)-1-oxo-2-ethyl}pyridinium iodide
• 英文别名: 1-(2-pyridinylcarbonyl)pyridinium iodide；(2-pyridylcarbonyl)pyridinium iodide；1-(2-pyridacyl)pyridinium iodide；1-(Pyridine-2-carbonyl)pyridin-1-ium iodide；pyridin-1-ium-1-yl(pyridin-2-yl)methanone;iodide
• CAS: 662148-54-1
• 化学式: C₁₁H₉N₂O*I
• 分子量: 312.11
• InChiKey: VNDNSDWZFCZXPP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.94
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  33.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-{1-(2'-pyridyl)-1-oxo-2-ethyl}pyridinium iodide 在 四(三苯基膦)钯 ammonium acetate 、 potassium carbonate 作用下， 以 甲醇 、 乙二醇二甲醚 为溶剂， 反应 19.0h， 生成 3,5-bis(2,2':6',2''-terpyridin-4'-phen-3-yl)toluene
  参考文献：
  名称：

  Design, characterization, and X-ray structure of an interlocked dinuclear chair-like metallomacrocycle: [Fe^II₂(3,5-bis(2,2′:6′,2″-terpyridin-4′-phen-3-yl)toluene)₂][4PF₆⁻]

  摘要：

  3,5-双(2,2²:6²,2³-三联吡啶-4²-苯-3-基)甲苯与等摩尔量的FeII盐的自组装产生了高产量的互锁双核四价“分子齿轮”，这一点已通过单晶X射线数据得到证实。

  DOI：

  10.1039/b616014j

文献信息

• Tuning solid emission by salts of the [Pt{4′-(o-CH3–Ph)trpy}Cl]+ and [Pt{4′-(o-CF3–Ph)trpy}Cl]+ luminophores: crystal structures of [Pt{4′-(o-CH3–Ph)trpy}Cl]A (A = BF4 or SbF6) and [Pt{4′-(o-CF3–Ph)trpy}Cl]SbF6 (trpy = 2,2′:6′,2″-terpyridine)
  作者：John S. Field、Raymond J. Haines、David R. McMillin、Grant C. Summerton

  DOI：10.1039/b107113k

  日期：——

  characterisation of 4′-(2‴-methylphenyl)-2,2′:6′,2″-terpyridine [4′-(o-CH3–Ph)trpy] and 4′-(2‴-trifluoromethylphenyl)-2,2′:6′,2″-terpyridine [4′-(o-CF3–Ph)trpy] are described. Reaction of these ligands with [Pt(PhCN)2Cl2] in the presence of the appropriate silver salt afforded [Pt4′-(o-CH3–Ph)trpy}Cl]A and [Pt4′-(o-CF3–Ph)trpy}Cl]A (A = BF4 or SbF6). The crystal structure of the SbF6− salt of the [Pt4′-(o-CH3–Ph)trpy}Cl]+

  4′-（2′-甲基苯基）-2,2′：6′，2″-吡啶[4′-（o -CH 3 -Ph）trpy]和4′-（2′-三氟甲基苯基）的合成与表征）-2,2'：6'，2''-吡啶[4'-（o -CF 3 -Ph）trpy]被描述。这些配体与[Pt（PhCN）2 Cl 2 ]在适当的银盐存在下反应，得到[Pt 4'-（o -CH 3 -Ph）trpy} Cl] A和[Pt 4'-（o -CF 3 –Ph）trpy} Cl] A（A = BF 4或SbF 6）。该SBF的晶体结构6 -的[铂4'的盐- （ø -CH 3–Ph）trpy} Cl] +阳离子由阳离子和阴离子组成的列，这些阳离子平行且头对尾堆叠，并且具有恒定的Pt⋯Pt距离[3.368（1）Å]和沿其的晶面间距（3.36Å）堆栈。在BF的晶体4 -盐还包含阳离子和阴离子具有堆叠平行且头-尾阳离子的列。但是，连续阳离子对的铂原子相对于垂
• Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents
  作者：Sipke H. Wadman、Duncan M. Tooke、Anthony L. Spek、Gerard P.M. van Klink、Gerard van Koten

  DOI：10.1016/j.ica.2009.12.008

  日期：2010.5

  Two new, potentially cyclometalating terdentate ligands bearing phosphonate substituents, Et2O3P-N boolean AND C(H)boolean AND N(5) and Et2O3P-C(H)boolean AND N boolean AND N (7), have been prepared. The corresponding ruthenium complexes, [1](+) and [2](+), respectively, were obtained by reaction with [RuCl3(tpy)]. Complexes [1](+) and [2](+) display electronic properties characteristic for cyclometalated ruthenium complexes. The platinum complex [3], of N boolean AND C(H)boolean AND N ligand 5, was also prepared and is highly phosphorescent in solution. In general, the phosphonate group electronically behaves equivalent to a carboxylate moiety. (C) 2009 Elsevier B. V. All rights reserved.
• Development of Polynuclear Molecular Wires Containing Ruthenium(II) Terpyridine Complexes
  作者：Teng-Yuan Dong、Mei-ching Lin、Michael Yen-Nan Chiang、Jing-Yun Wu

  DOI：10.1021/om0497386

  日期：2004.8.1

  The preparations of multinuclear supramolecules assembled from 1',1'''-bis(terpyridyl)-biferrocene redox-active subunits with Ru2+ metal centers are described. The electrochemical measurements of the series of Ru2+-coordinated 1',1"'-bis(terpyridyl)biferrocene complexes are dominated by the Ru2+/Ru3+ redox couple (E-1/2 at similar to1.35 V), Fe2+/Fe3+ redox couples (E(1/)2 from similar to0.4 to similar to0.9 V), and terpy/terpy(-)herpy(2-) redox couples (E-1/2 at similar to-1.2 and similar to-1.4 V). The appreciable variations detected in the Fe2+/Fe3+ oxidation potentials indicate that there is an interaction between the spacer and the Ru2+ metal centers. On the coordination of Ru2+ metal centers with 1',1"'-bis(terpyridyl)biferrocene, there is a rise to a red-shifted and more intense (1)[(d(pi)(Fe))(6)] --> (1)[d(pi)(Fe))(5)(pi*(Ru)(terp))(1)] transition in the visible region. The observed red-shifted absorption from similar to510 nm in monomeric [Ru(terpy)(2)](2+) and [Ru(terpy)(fcterpy)](2+) complexes to similar to570 nm in polynuclear Ru2+ 1',1'''-bis(terpyridyl)biferrocene complexes reveals that there is a qualitative electronic coupling within the array. The coordination of Ru2+ transition-metal centers lowers the energy of the pi*(terpy) orbitals, giving a more red-shifted transition.
• Luminescent dual-network hydrogels based on terpyridine-Eu(III) supramolecular coordination: Fluorene as antenna
  作者：Pan Liu、Chenchen Ma、Zihan Ma、Ziyuan He、Xianjian Wang、Longhao Zhao、Xuegang Chen

  DOI：10.1016/j.dyepig.2023.111362

  日期：2023.8
• Design, characterization, and X-ray structure of an interlocked dinuclear chair-like metallomacrocycle: [Fe^II₂(3,5-bis(2,2′:6′,2″-terpyridin-4′-phen-3-yl)toluene)₂][4PF₆⁻]
  作者：Ibrahim Eryazici、Pingshan Wang、Charles N. Moorefield、Matthew Panzer、Semih Durmus、Carol D. Shreiner、George R. Newkome

  DOI：10.1039/b616014j

  日期：——

  The self-assembly of 3,5-bis(2,2′:6′,2″-terpyridin-4′-phen-3-yl)toluene with an equimolar amount of a FeII salt afforded a high yield of an interlocked dinuclear tetracationic “molecular gear” that was confirmed by single crystal X-ray data.

  3,5-双(2,2²:6²,2³-三联吡啶-4²-苯-3-基)甲苯与等摩尔量的FeII盐的自组装产生了高产量的互锁双核四价“分子齿轮”，这一点已通过单晶X射线数据得到证实。