1-H-5-trifluoromethylperfluoroheptane | 34944-39-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1-H-5-trifluoromethylperfluoroheptane
• 英文别名: 2H,6H-dodecafluoro-2-trifluoromethyl-hexane；1H-Pentadecafluoro-5-methyl-hexan；1,1,1,2,3,3,4,4,5,5,6,6-Dodecafluoro-2-(trifluoromethyl)hexane
• CAS: 34944-39-3
• 化学式: C₇HF₁₅
• 分子量: 370.061
• InChiKey: AEWVEJOWJSPPNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为产物：
  描述：

  全氟异庚基碘化物 在 二甲基硫 作用下， 生成 1-H-5-trifluoromethylperfluoroheptane
  参考文献：
  名称：

  甲基多氟烷基硫化物和多氟链烷磺酸的合成

  摘要：

  通过两种新途径合成的甲基多氟烷基硫化物：（i）多氟碘代烷与二甲基硫醚或二甲基二硫化物的光化学反应，和（ii）多氟碘代烷与甲烷硫醇钠在二甲基二硫化物存在下的反应是多氟链烷磺酸的有用前体。

  DOI：

  10.1039/c39720000249

文献信息

• Process for producing polyether
  申请人：Miyanaga Seiichi

  公开号：US20050004344A1

  公开（公告）日：2005-01-06

  The present invention provides a process for efficiently obtaining polyethers having its high degree of polymerization by easily polymerizing substituted epoxides which could hardly or could not be made so far to provide a high degree of polymerization. That is, a polyether is obtained by a process which comprises ring-opening-polymerizing at least one substituted epoxide, except for propylene oxide and epihalohydrin, in the presence of a rare earth metal compound represented by the formula (I) and a reducing compound: Wherein M represents a rare earth element selected from Sc, Y and lanthanide, and L 1 , L 2 and L 3 are same as or different from each other and each of them represents an oxygen-binding ligand.

  本发明提供了一种高效获得高聚度聚醚的方法，通过简单地聚合很难或迄今为止不能得到高聚度的取代环氧化物来提供高聚度聚醚。也就是说，通过在稀土金属化合物(I)和还原化合物的存在下，开环聚合至少一种取代环氧化物（丙烯酸丙烯酯和环氧氯丙烷除外）来获得聚醚：其中，M代表从Sc、Y和镧系元素中选择的稀土元素，L1、L2和L3相同或不同，每个代表一个氧结合配体。
• MODIFIED RUBBER ELASTIC BODY AND ELECTROPHOTOGRAPHIC MEMBER
  申请人：Sumitomo Riko Company Limited

  公开号：EP2980140A1

  公开（公告）日：2016-02-03

  A modified rubber elastic body 12 has a rubber elastic body 121 having rubber elasticity and a surface-treated layer 122 composed of a cured product of photocurable composition impregnated into the rubber elastic body 121 from the surface thereof. The photocurable composition is configured to include a (meth)acryl monomer, a photopolymerizable polymer having a silicone group and/or a fluorine-containing group and a (meth) acryloyl group in a molecule, and a photopolymerization initiator. An electrophotographic device member can be configured as a roll member 1, a blade member 2, a belt member 3 or the like, and the modified rubber elastic body 12 is used as a material for a portion including the surfaces of the respective members.

  改性橡胶弹性体 12 具有橡胶弹性体 121 和表面处理层 122，表面处理层 122 由从橡胶弹性体 121 表面浸渍到橡胶弹性体 121 中的光固化组合物固化产物组成。光固化组合物包括（甲基）丙烯酰单体、分子中含有硅酮基团和/或含氟基团和（甲基）丙烯酰基团的可光聚合聚合物以及光聚合引发剂。电子照相设备部件可配置为辊部件 1、刀片部件 2、带部件 3 或类似部件，改性橡胶弹性体 12 用作包括各部件表面在内的部分的材料。
• LITHOGRAPHIC PRINTING INK, VARNISH FOR LITHOGRAPHIC INKS, AND METHOD FOR PRODUCING PRINTED MATTER USING SAID INK
  申请人：Toray Industries, Inc.

  公开号：EP3351602A1

  公开（公告）日：2018-07-25

  A lithographic ink which has a highly sensitive curability for active energy beam simultaneously with a high washability with water, and which also has excellent resistance to surface staining in the printing and high water resistance of the cured film is provided. Also provided are a varnish for such lithographic ink and a method for producing printed material. The lithographic ink comprises (a) a pigment and (b) a resin having an ethylenically unsaturated group and a hydrophilic group, and it has a highly sensitive curability for active energy beam simultaneously with a high washability with water, and also, excellent resistance to surface staining in the printing and high water resistance of the cured film.

  本发明提供了一种平版印刷油墨，该油墨对活性能量光束具有高灵敏度的固化能力，同时还具有较高的水洗能力，并且在印刷过程中具有出色的抗表面沾污能力和固化膜的高耐水性。此外，还提供了用于这种平版印刷油墨的上光剂和生产印刷材料的方法。这种平版印刷油墨由 (a) 颜料和 (b) 具有乙烯不饱和基团和亲水基团的树脂组成，对活性能量光束具有高灵敏度的固化性，同时具有很高的水洗性，而且在印刷中具有优异的抗表面沾污性，固化膜具有很高的耐水性。
• LITHOGRAPHIC INK
  申请人：Toray Industries, Inc.

  公开号：EP3381988A1

  公开（公告）日：2018-10-03

  Provided is a lithographic ink having superior surface staining resistance and fluidity. Also provided is a method for manufacturing a printed material using the lithographic ink. The lithographic ink has all of a viscosity (A) at a rotational speed of 0.5 rpm, a viscosity (B) at a rotational speed of 20 rpm, and a viscosity (C) at a rotational speed of 50 rpm of 5 Pa·s or more and 100 Pa·s or less, the viscosities (A), (B), and (C) being measured by using a cone-plate rotating viscometer at 25°C, and has a viscosity ratio (C)/(B) of 0.8 or more and 1.0 or less.

  本发明提供了一种平版印刷油墨，它具有优异的表面耐沾污性和流动性。还提供了一种使用该平版印刷油墨制造印刷材料的方法。平版印刷油墨在转速为 0.5rpm时的粘度(A)、20rpm时的粘度(B)和50rpm时的粘度(C)分别为5Pa-s以上和100Pa-s以下，粘度(A)、(B)和(C)是在25℃下使用锥板旋转粘度计测量的，粘度比(C)/(B)为0.8以上和1.0以下。
• METHOD FOR MANUFACTURING PRINTED MATTER USING PLANOGRAPHIC PRINTING INK, AND PLANOGRAPHIC PRINTING INK SET
  申请人：Toray Industries, Inc.

  公开号：EP3521047A1

  公开（公告）日：2019-08-07

  To provide is a manufacturing method for obtaining printed material in which, in lithographic printing, a printed part where multiple colors are superimposed on each other has a high gloss, and also a lithographic printing ink set. The method for manufacturing printed material according to the present invention includes a step of coating at least black ink for lithographic printing, cyan ink for lithographic printing, magenta ink for lithographic printing, and yellow ink for lithographic printing on a substrate, in which a difference in surface tension between the inks to be coated on a substrate is at most equal to 3.5 mN/m. The lithographic printing ink set according to the present invention is a lithographic printing ink set including at least black ink, cyan ink, magenta ink, and yellow ink, in which a difference in surface tension between the inks included in the lithographic printing ink set is at most equal to 3.5 mN/m.

  本发明的目的是提供一种用于获得印刷材料的制造方法，在这种印刷材料中，在平版印刷中，多色叠加的印刷部分具有较高的光泽度，同时还提供一种平版印刷油墨组。根据本发明制造印刷材料的方法包括在基材上涂布至少平版印刷用黑色油墨、平版印刷用青色油墨、平版印刷用品红色油墨和平版印刷用黄色油墨的步骤，其中在基材上涂布的油墨之间的表面张力差最多等于 3.5 mN/m。根据本发明的平版印刷油墨组是一种平版印刷油墨组，至少包括黑色油墨、青色油墨、品红色油墨和黄色油墨，其中平版印刷油墨组中的油墨之间的表面张力差最多等于 3.5 mN/m。