| 53154-54-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 53154-54-4；725230-18-2；12149-89-2
• 化学式: C₂₆H₂₀N₂NiO₂S₂
• 分子量: 515.279
• InChiKey: AGBPNVLNLOOBQG-ZNVPEIAMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 solid 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  PREPARATION AND THERMAL STUDY OF NEW COMPLEXES OF SALICYLIDENE-2-AMINOTHIOPHENOL SCHIFF BASES

  摘要：

  New complexes of the Schiff base salicylidene-2-aminothiophenol with VO(IV), Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized and studied by thermogravimetric analysis and a general scheme of thermal decomposition of these complexes is proposed. The thermal dehydration and decomposition of these complexes were studied kinetically using the integral method applying the Coats-Redfern equation. It was found that the thermal decompositions of the complexes follow first order kinetics. The thermodynamic parameters of the decomposition are also reported.

  DOI：

  10.1081/sim-120014307
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 2-(亚水杨基氨基)硫代苯酚 在 ammonium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  PREPARATION AND THERMAL STUDY OF NEW COMPLEXES OF SALICYLIDENE-2-AMINOTHIOPHENOL SCHIFF BASES

  摘要：

  New complexes of the Schiff base salicylidene-2-aminothiophenol with VO(IV), Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized and studied by thermogravimetric analysis and a general scheme of thermal decomposition of these complexes is proposed. The thermal dehydration and decomposition of these complexes were studied kinetically using the integral method applying the Coats-Redfern equation. It was found that the thermal decompositions of the complexes follow first order kinetics. The thermodynamic parameters of the decomposition are also reported.

  DOI：

  10.1081/sim-120014307