Ni(salicylidene 2-aminothiophenol(-2H))(H2O) | 41678-13-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ni(salicylidene 2-aminothiophenol(-2H))(H2O)
• 英文别名: {Ni(salicylidene-o-aminothiophenol(2-))(H2O)}
• CAS: 41678-13-1
• 化学式: C₁₃H₁₁NNiO₂S
• 分子量: 303.992
• InChiKey: IWHINNBUUFZONP-CAJRCRMVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ni(salicylidene 2-aminothiophenol(-2H))(H2O) 以 solid 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  PREPARATION AND THERMAL STUDY OF NEW COMPLEXES OF SALICYLIDENE-2-AMINOTHIOPHENOL SCHIFF BASES

  摘要：

  New complexes of the Schiff base salicylidene-2-aminothiophenol with VO(IV), Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized and studied by thermogravimetric analysis and a general scheme of thermal decomposition of these complexes is proposed. The thermal dehydration and decomposition of these complexes were studied kinetically using the integral method applying the Coats-Redfern equation. It was found that the thermal decompositions of the complexes follow first order kinetics. The thermodynamic parameters of the decomposition are also reported.

  DOI：

  10.1081/sim-120014307
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 2-(亚水杨基氨基)硫代苯酚 在 ammonium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 以89%的产率得到Ni(salicylidene 2-aminothiophenol(-2H))(H2O)
  参考文献：
  名称：

  PREPARATION AND THERMAL STUDY OF NEW COMPLEXES OF SALICYLIDENE-2-AMINOTHIOPHENOL SCHIFF BASES

  摘要：

  New complexes of the Schiff base salicylidene-2-aminothiophenol with VO(IV), Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized and studied by thermogravimetric analysis and a general scheme of thermal decomposition of these complexes is proposed. The thermal dehydration and decomposition of these complexes were studied kinetically using the integral method applying the Coats-Redfern equation. It was found that the thermal decompositions of the complexes follow first order kinetics. The thermodynamic parameters of the decomposition are also reported.

  DOI：

  10.1081/sim-120014307

文献信息

• Synthesis, spectroscopy and thermal study of some nickel(II) complexes containing tridentate Schiff bases and substituted amine ligands, X-ray crystal structure of nickel(II) complex
  作者：Ali Hossein Kianfar、Masomeh Bahramian、Hamid Reza Khavasi

  DOI：10.1016/j.saa.2012.03.039

  日期：2012.8

  and has four coordinate in the solid state. The thermogravimmetry (TG) and differential thermoanalysis (DTA) of the synthesized complexes were carried out in the range of 20–700 °C, leading to decomposition of ONO type in two stages and of ONS type in three stages. The ONO and ONS complexes were decomposed to NiO and NiS respectively. Thermal decomposition of the complexes is closely the depends upon

  合成了一些新的[NiL（胺）]的三齿ONO和ONS Schiff碱配合物（L =水杨基2-氨基苯酚和水杨基2-氨基硫代苯酚，胺=苄胺，吗啉，吡咯烷和哌啶），并用红外光谱，紫外可见光谱，1 H NMR光谱和元素分析。[NiL 2的几何通过X射线晶体学测定的[bzlan]表明该络合物具有平面结构并且在固态具有四个坐标。合成配合物的热重分析（TG）和差示热分析（DTA）在20–700°C的范围内进行，导致ONO型分解为两个阶段，ONS型分解为三个阶段。将ONO和ONS配合物分别分解为NiO和NiS。配合物的热分解与席夫碱配体的性质密切相关，并通过一级动力学进行。
• Stability studies in relation to IR data of some schiff base complexes of transition metals and their biological and pharmacological studies
  作者：R.K. Parashar、R.C. Sharma、Anil Kumar、Govind Mohan

  DOI：10.1016/s0020-1693(00)83468-4

  日期：1988.3