Benzolsulfinsaeurefluorid | 657-98-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzolsulfinsaeurefluorid
• 英文别名: Benzolsulfinylfluorid；Phenylsulfinylfluorid；benzenesulfinyl fluoride
• CAS: 657-98-7
• 化学式: C₆H₅FOS
• 分子量: 144.17
• InChiKey: FEMCXRDTPSJDPG-UHFFFAOYSA-N

物化性质

• 沸点：
  60 °C(Press: 2.5 Torr)
• 密度：
  1.36±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Benzolsulfinsaeurefluorid 在 三氟化硼 作用下， 以 一氟三氯甲烷 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Isolierbare,o-verbrückte sulfinsäurefluorid/BF3-addukte ArS(F)O⋯BF3[1]

  摘要：

  DOI：

  10.1016/s0022-1139(00)84019-1
• 作为产物：
  描述：

  phenylsulfur trifluoride 在 苯甲醛 作用下， 生成 Benzolsulfinsaeurefluorid
  参考文献：
  名称：

  Alkyl- and Arylsulfur Trifluorides

  摘要：

  DOI：

  10.1021/ja00875a005

文献信息

• [EN] TETRAZOLINONE COMPOUNDS AND ITS USE AS PESTICIDES<br/>[FR] COMPOSÉS DE TÉTRAZOLINONE ET LEUR UTILISATION EN TANT QUE PESTICIDES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2013162072A1

  公开（公告）日：2013-10-31

  The present invention provides a compound having an excellent efficacy for controlling pests. A tetrazolinone compound of a formula (1): [wherein R1 represents an C6-C16 aryl group, an C1-C12 alkyl group, or a C3-C12 cycloalkyl group, etc., which each optionally be substituted; R2, R3, R4 and R5 represent independently of each other a hydrogen atom, a halogen atom or an C1-C3 alkyl group, etc.; R6 represents an C1-C6 alkyl group, a C3-C6 cycloalkyl group, a halogen atom, a C1-C6 haloalkyl group, an C2-C6 alkenyl group, an C1-C6 alkoxy group, or a C1-C6 haloalkoxy group, etc.; R7, R8 and R9 represent independently of each other a hydrogen atom, a halogen atom, or an C1-C4 alkyl group, etc.; X represents an oxygen atom or a sulfur atom; and R10 represents an C1-C6 alkyl group, etc.] shows an excellent controlling efficacy on pests.

  本发明提供了一种具有优异杀虫效果的化合物。公式（1）的四唑酮化合物：[其中R1代表C6-C16芳基、C1-C12烷基或C3-C12环烷基等，每个都可以选择性地被取代；R2、R3、R4和R5分别独立地代表氢原子、卤素原子或C1-C3烷基等；R6代表C1-C6烷基、C3-C6环烷基、卤素原子、C1-C6卤代烷基、C2-C6烯基、C1-C6烷氧基或C1-C6卤代烷氧基等；R7、R8和R9分别独立地代表氢原子、卤素原子或C1-C4烷基等；X代表氧原子或硫原子；R10代表C1-C6烷基等]在杀虫方面表现出优异的控制效果。
• [EN] TETRAZOLINONE COMPOUNDS AND ITS USE<br/>[FR] COMPOSÉS DE TÉTRAZOLINONE ET LEUR UTILISATION
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2013162077A1

  公开（公告）日：2013-10-31

  The present invention provides a compound having an excellent efficacy for controlling pests. A tetrazolinone compound of a formula (1): [wherein, R1 represents an C6-C16 aryl group, an C1-C12 alkyl group, a C3-C12 cycloalkyl group or an adamantyl group, etc., which each optionally be substituted; R2 represents a hydrogen atom, an C1-C12 alkyl group, or a halogen atom, etc.; R4 and R5 represent independently of each other a hydrogen atom or an C1-C3 alkyl group, etc.; R6, R7, R8 and R9 represent independently of each other a hydrogen atom, a halogen atom, an C1-C12 alkyl group, a C1-C12 haloalkyl group, an C2-C12 alkenyl group, a C3-C12 cycloalkyl group, an C1-C12 alkoxy group or a C1-C12 haloalkoxy group, etc.; X and Y represent independently of each other a sulfur atom or an oxygen atom; Q represents an oxygen atom or a sulfur atom; and R10 represents an C1-C6 alkyl group, etc.] shows an excellent controlling efficacy on pests.

  本发明提供了一种具有优异杀虫效果的化合物。式（1）中的四氮杂酮化合物：[其中，R1代表一个C6-C16芳基，一个C1-C12烷基，一个C3-C12环烷基或一个金刚烷基等，每个都可以选择性地被取代；R2代表一个氢原子，一个C1-C12烷基或一个卤素原子等；R4和R5分别独立地代表一个氢原子或一个C1-C3烷基等；R6、R7、R8和R9分别独立地代表一个氢原子，一个卤素原子，一个C1-C12烷基，一个C1-C12卤代烷基，一个C2-C12烯基，一个C3-C12环烷基，一个C1-C12烷氧基或一个C1-C12卤代烷氧基等；X和Y分别独立地代表一个硫原子或一个氧原子；Q代表一个氧原子或一个硫原子；R10代表一个C1-C6烷基等]对害虫有极佳的控制效果。
• [EN] COMPOUNDS AND METHODS TO INHIBIT HISTONE DEACETYLASE (HDAC) ENZYMES<br/>[FR] COMPOSÉS ET PROCÉDÉS POUR INHIBER LES ENZYMES HISTONE DÉSACÉTYLASES (HDAC)
  申请人：GLAXOSMITHKLINE LLC

  公开号：WO2013066833A1

  公开（公告）日：2013-05-10

  The invention relates to compounds that inhibit histone deacetylase (HDAC) enzymes, the preparation of these compounds, the use of these compounds in the treatment of diseases or conditions ameliorated by inhibition of HDAC activity, and pharmaceutical compositions comprising these compounds. Specifically, the invention relates to compounds having the formula (I), wherein A, X, Y, R, and B are as defined herein, and methods of making and using the same.

  本发明涉及抑制组蛋白去乙酰化酶（HDAC）酶的化合物，这些化合物的制备，使用这些化合物治疗通过抑制HDAC活性改善的疾病或病症，以及包含这些化合物的制药组合物。具体来说，本发明涉及具有公式（I）的化合物，其中A、X、Y、R和B的定义如本文所述，以及制备和使用这些化合物的方法。
• De‐risking S‐F bond formation:A gas cylinder‐free strategy to access S(IV) and S(VI) fluorinated compounds.
  作者：Reza Kordnezhadian、Armir Zogu、Carlotta Borgarelli、Ruben Van Lommel、Joachim Demaerel、Wim M. De Borggraeve、Ermal Ismalaj

  DOI：10.1002/chem.202300361

  日期：——

  Herein we report the oxidative halogenation of thiols via the ex situ generation of chlorine by employing calcium hypochorite as solid bench-stable precursor. This approach enables the synthesis of three distinct classes of compounds (R-SF3, RSO2F and RSF4Cl). Metastable R-SF4Cl intermediates are further postfunctionalized to access structures of higher complexity, and computational analysis elucidate

  在此，我们报道了使用次氯酸钙作为固体工作台稳定前体，通过异位产生氯来氧化卤化硫醇。这种方法能够合成三种不同类别的化合物（R-SF 3、RSO 2 F 和 RSF 4 Cl）。亚稳态 R-SF 4 Cl 中间体进一步后官能化以获得更复杂的结构，计算分析阐明了导致某些杂芳族 SF 4 Cl 结构顺式选择性的潜在途径。
• Novel aromatic sulfonium salt compound, photo-acid generator comprising the same and photopolymerizable composition containing the same, resin composition for optical three-dimensional shaping, and method of optically forming three-dimensional shape
  申请人：Adeka Corporation

  公开号：EP2308865A1

  公开（公告）日：2011-04-13

  Novel aromatic sulfonium salt compounds of general formula (I), photo-acid generators comprising the same, and photo-polymerizable compositions containing the same, capable of providing stereolithographic resin compositions which do not suffer from the hindrance to curing by oxygen, can easily give shaped articles having desired sizes by virtue of the high accuracy thereof in curing, can attain a satisfactory curing depth owing to the high sensitivity thereof for radiant energy and can be employed for wide usage, such as photoresist and ink for foods-packing medium, since the release of benzene is suppressed; and a stereolithographic process, using said stereolithographic resin composition.

  通式(I)的新型芳香族锍盐化合物、包含这些化合物的光酸发生器以及包含这些化合物的可光聚合组合物，能够提供不受氧气固化阻碍的立体平版印刷树脂组合物、由于其固化精度高，可以很容易地生产出具有所需尺寸的成型物品；由于其对辐射能的敏感度高，可以达到令人满意的固化深度；由于抑制了苯的释放，可以广泛用于食品包装介质的光刻胶和油墨等；使用所述立体平版印刷树脂组合物的立体平版印刷工艺。