bis((2,4,6,2'',4'',6''-hexaisopropyl-1,1':3';1''-terphenyl-2')amino)tetramethyldisilazane | 1542799-95-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis((2,4,6,2'',4'',6''-hexaisopropyl-1,1':3';1''-terphenyl-2')amino)tetramethyldisilazane
• 英文别名: Bis((2,4,6,2'',4'',6''-hexaisopropyl-1,1':3';1''-terphenyl-2')amino)tetramethyldisilazane；N-[[[[2,6-bis[2,4,6-tri(propan-2-yl)phenyl]anilino]-dimethylsilyl]amino]-dimethylsilyl]-2,6-bis[2,4,6-tri(propan-2-yl)phenyl]aniline
• CAS: 1542799-95-0
• 化学式: C₇₆H₁₁₃N₃Si₂
• 分子量: 1124.92
• InChiKey: HAGHXOMCPDAIPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  24.35
• 重原子数：
  81
• 可旋转键数：
  22
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  36.1
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  tris(tetramethyldisilazanido)bis(tetrahydrofuran)praseodymium 、 H₂N[2,6-(2,4,6-(i-Pr)₃C₆H₂)₂(C₆H₃)] 反应 48.0h， 生成 bis((2,4,6,2'',4'',6''-hexaisopropyl-1,1':3';1''-terphenyl-2')amino)tetramethyldisilazane
  参考文献：
  名称：

  Formation of Novel T-Shaped NNN Ligands via Rare-Earth Metal-Mediated Si–H Activation

  摘要：

  Reactions of silylamides [Ln{N-(SiHMe2)(2)}(3)(thf)(2)] with sterically crowded terphenylamine DmpNH(2) (Dmp = 2,6-Mes(2)C(6)H(3) with Mes = 2,4,6-Me3C6H2) afforded via a template reaction the formation of a new tridentate ligand, and derived complexes of composition [LnN{SiMe2N(Dmp)}(2)] (Ln = Ce, Pr) were obtained. Usage of the even more bulky amine Ar*NH2 (Ar* = 2,6-Trip(2)C(6)H(3) with Trip = 2,4,6-iPr(3)C(6)H(2)) yielded the free protonated ligand NH-{SiMe2NH(Ar*)}(2).

  DOI：

  10.1021/ic402941z

文献信息

• Formation of Novel T-Shaped NNN Ligands via Rare-Earth Metal-Mediated Si–H Activation
  作者：Denis Bubrin、Mark Niemeyer

  DOI：10.1021/ic402941z

  日期：2014.2.3

  Reactions of silylamides [LnN-(SiHMe2)(2)}(3)(thf)(2)] with sterically crowded terphenylamine DmpNH(2) (Dmp = 2,6-Mes(2)C(6)H(3) with Mes = 2,4,6-Me3C6H2) afforded via a template reaction the formation of a new tridentate ligand, and derived complexes of composition [LnNSiMe2N(Dmp)}(2)] (Ln = Ce, Pr) were obtained. Usage of the even more bulky amine Ar*NH2 (Ar* = 2,6-Trip(2)C(6)H(3) with Trip = 2,4,6-iPr(3)C(6)H(2)) yielded the free protonated ligand NH-SiMe2NH(Ar*)}(2).