1,6-Dichlor-trans-2-hexen | 63974-06-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1,6-Dichlor-trans-2-hexen
• 英文别名: 1,6-dichloro-hex-2t-ene；(E)-1,6-dichlorohex-2-ene
• CAS: 63974-06-1
• 化学式: C₆H₁₀Cl₂
• 分子量: 153.051
• InChiKey: DSNNJGIAAQGHMJ-HNQUOIGGSA-N

物化性质

• 沸点：
  210.8±20.0 °C(Predicted)
• 密度：
  1.063±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,6-Dichlor-trans-2-hexen 在 Lindlar's catalyst 吡啶 、 氢气 、 三溴化磷 作用下， 以 喹啉 、 乙醚 、 Petroleum ether 为溶剂， 生成 1-chloro-nonadeca-4t,7c,10c,13c-tetraene
  参考文献：
  名称：

  Egmond,G.J.N. et al., Recueil des Travaux Chimiques des Pays-Bas, 1977, vol. 96, p. 172 - 175

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Hexyne-1,6-diol 在 氯化亚砜 、 氨 、 sodium 、 tri-tert-butylamine 作用下， 生成 1,6-Dichlor-trans-2-hexen
  参考文献：
  名称：

  Egmond,G.J.N. et al., Recueil des Travaux Chimiques des Pays-Bas, 1977, vol. 96, p. 172 - 175

  摘要：

  DOI：

文献信息

• METHODS OF MAKING ORGANIC COMPOUNDS BY METATHESIS
  申请人：Elevance Renewable Sciences, Inc.

  公开号：EP3281931A1

  公开（公告）日：2018-02-14

  Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.

  本发明描述了通过偏合成化学制造有机化合物的方法。本发明的方法特别适用于从可再生原料（如天然油）中提取的起始组合物开始制造工业上重要的有机化合物。这些方法利用与烯烃化合物的交叉甲基化步骤，生成具有预定双键位置的官能化烯中间体。一旦分离出来，官能化烯中间体可进行自甲基化或交叉甲基化（例如与第二种官能化烯），以生产所需的有机化合物或其前体。该方法可用于制造双官能团有机化合物，如二酸、二酯、二羧酸盐、酸/酯、酸/胺、酸/醇、酸/醛、酸/酮、酸/卤化物、酸/腈、酯/胺、酯/醇、酯/醛、酯/酮、酯/卤化物、酯/腈等。
• Methods of making organic compounds by metathesis
  申请人：Wilmar Trading Pte Ltd

  公开号：US10906861B2

  公开（公告）日：2021-02-02

  Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.

  本发明描述了通过偏合成化学制造有机化合物的方法。本发明的方法特别适用于从可再生原料（如天然油）中提取的起始组合物开始制造工业上重要的有机化合物。这些方法利用与烯烃化合物的交叉甲基化步骤，生成具有预定双键位置的官能化烯中间体。一旦分离出来，官能化烯中间体可进行自甲基化或交叉甲基化（例如与第二种官能化烯），以生产所需的有机化合物或其前体。该方法可用于制造双官能团有机化合物，如二酸、二酯、二羧酸盐、酸/酯、酸/胺、酸/醇、酸/醛、酸/酮、酸/卤化物、酸/腈、酯/胺、酯/醇、酯/醛、酯/酮、酯/卤化物、酯/腈等。
• Methods of Making Organic Compounds by Metathesis
  申请人：Elevance Renewable Sciences, Inc.

  公开号：US20150307438A1

  公开（公告）日：2015-10-29

  Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.
• US9120742B2
  申请人：——

  公开号：US9120742B2

  公开（公告）日：2015-09-01
• Egmond,G.J.N. et al., Recueil des Travaux Chimiques des Pays-Bas, 1977, vol. 96, p. 172 - 175
  作者：Egmond,G.J.N. et al.

  DOI：——

  日期：——