p-xylylenebis(triethylammonium) chloride | 19171-43-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-xylylenebis(triethylammonium) chloride
• 英文别名: 1,6-bis(triethylmethylammonium)xylol dichloride；1,6-bis(triethylmethylammonium)cylol dichloride；btx*Cl2；triethyl-[[4-[(triethylazaniumyl)methyl]phenyl]methyl]azanium;chloride
• CAS: 19171-43-8
• 化学式: C₂₀H₃₈N₂*2Cl
• 分子量: 377.441
• InChiKey: OGRPREOVXSSODB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.44
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  p-xylylenebis(triethylammonium) chloride 、 zinc(II) chloride 在 硫氰酸铵 作用下， 以 盐酸 为溶剂， 生成 (p-xylylenebis(triethylammonium))[Zn(SCN)4]
  参考文献：
  名称：

  Shashkin, M. A.; Zubareva, S. V.; Inozemtseva, U. A., Russian Journal of Inorganic Chemistry, 1980, vol. 25, p. 1421 - 1422

  摘要：

  DOI：
• 作为产物：
  描述：

  三乙胺 、 1,4-对二氯苄 以 乙腈 为溶剂， 生成 p-xylylenebis(triethylammonium) chloride
  参考文献：
  名称：

  Syntheses, Crystal Structures, UV-Vis Absorption, and Fluorescent Properties of a Complex: [btx][Cu₂I₄]

  摘要：

  The self-assembly reaction of organic cation and metal iodides yielded a novel binuclear coordination compound, namely [btx][Cu2I4](1) [btx = 1,6-bis(triethylmethylammonium)xylol], which is characterized by X-ray crystallography, IR spectroscopy, fluorescence spectra, and UV-vis absorption spectra. The compound 1 crystallizes in Monoclinic, space group P2(1)/c with a = 8.2246(12), b = 11.5843(17), c = 15.005(2), alpha = 90 degrees, beta = 94.218(2)degrees, gamma = 90 degrees. In the anion [Cu2I4](2-), each Cu center is triangularly coordinated by two mu(2)-I(2) atoms and one terminal I(1) atom. The organic cationic [btx](2+) existed around it through supramolecular interactions.

  DOI：

  10.1080/15533174.2011.611205

文献信息

• Syntheses, Crystal Structures, and Catalytic Activities of Two Inorganic–Organic Hybrid Materials: [py]₂[Hpy]₃[PMo₁₂O₄₀]·H₂O and [btx]₂[Mo₈O₂₆]·H₂O
  作者：Yun-Yin Niu、Hai-Juan Du、Ling-Fang Wang、Wen-Long Dong、Xiao-Rui Lv

  DOI：10.1080/15533174.2011.591324

  日期：2011.9.1

  Two novel organic-inorganic hybrid supramolecular compounds based on organic cations and POMs, namely, [py](2)[Hpy](3)[PMo12O40]center dot H2O (1) and [btx]2[Mo8O26]center dot H2O ( 2) [ btx = 1,6-bis(triethylmethylammonium) xylol], have been hydrothermally synthesized and characterized by single-crystal x-ray diffraction, infrared (IR) spectroscopy, and thermal gravimetric analysis (TGA). The compound 1 crystallizes in the monoclinic, space group P2(1)/c with a = 17.7932(18) angstrom, b = 19.427(2) angstrom, c = 15.2515(16) angstrom, beta = 98.479(2)degrees. Compound 2 crystallizes in the triclinic, space group P-1 with a = 11.6245(8)angstrom, b = 11.9573(13)angstrom, c = 12.8756(10)angstrom, alpha = 63.830(6)degrees, beta = 75.285(5)degrees, gamma = 68.024(5)degrees. Compound 1 contained the classical Keggin-type discrete [PMo12O40](3-) anion and 2 had the a-[Mo8O26](4-) cluster. Moreover, it was indicated that these polyacid compounds had definite catalytic activities on the reaction of acetaldehyde oxidation to acetic acid.
• Shashkin, M. A.; Zubareva, S. V.; Inozemtseva, U. A., Russian Journal of Inorganic Chemistry, 1980, vol. 25, p. 1421 - 1422
  作者：Shashkin, M. A.、Zubareva, S. V.、Inozemtseva, U. A.、Kravtsov, V. S.

  DOI：——

  日期：——
• Syntheses, Crystal Structures, UV-Vis Absorption, and Fluorescent Properties of a Complex: [btx][Cu₂I₄]
  作者：Hai-Juan Du、Yu Liang、Ling-Fang Wang、Yun-Yin Niu

  DOI：10.1080/15533174.2011.611205

  日期：2012.3.1

  The self-assembly reaction of organic cation and metal iodides yielded a novel binuclear coordination compound, namely [btx][Cu2I4](1) [btx = 1,6-bis(triethylmethylammonium)xylol], which is characterized by X-ray crystallography, IR spectroscopy, fluorescence spectra, and UV-vis absorption spectra. The compound 1 crystallizes in Monoclinic, space group P2(1)/c with a = 8.2246(12), b = 11.5843(17), c = 15.005(2), alpha = 90 degrees, beta = 94.218(2)degrees, gamma = 90 degrees. In the anion [Cu2I4](2-), each Cu center is triangularly coordinated by two mu(2)-I(2) atoms and one terminal I(1) atom. The organic cationic [btx](2+) existed around it through supramolecular interactions.