1-[3,5-双(1-羟乙基)苯基]乙醇 | 37394-26-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-[3,5-双(1-羟乙基)苯基]乙醇
• 英文名称: α,α',α''-trimethyl-1,3,5-benzenetrimethanol
• 英文别名: 1,1',1''-(benzene-1,3,5-triyl)triethanol；1,3,5-tris-(1-hydroxy-ethyl)-benzene；1,3,5-Tris-(1-hydroxy-aethyl)-benzol；1-[3,5-Bis(1-hydroxyethyl)phenyl]ethanol
• CAS: 37394-26-6；143394-14-3；143394-15-4；143394-16-5；143394-17-6；147977-11-5；147977-12-6
• 化学式: C₁₂H₁₈O₃
• 分子量: 210.273
• InChiKey: UAHZWJCHJDIXSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-[3,5-双(1-羟乙基)苯基]乙醇 在 喹啉 、 三溴化磷 作用下， 生成 1,3,5-三(乙烯基)苯
  参考文献：
  名称：

  Effenberger,F.; Kurtz,W., Chemische Berichte, 1973, vol. 106, p. 511 - 524

  摘要：

  DOI：
• 作为产物：
  描述：

  三乙酰基苯 在 甲醇 、 sodium tetrahydroborate 作用下， 生成 1-[3,5-双(1-羟乙基)苯基]乙醇
  参考文献：
  名称：

  TfOH催化水合和Ru催化串联不对称加氢将炔烃转化为手性醇

  摘要：

  开发了一种在简单条件下通过TfOH催化水合再加上Ru催化串联T对称不对称氢化将炔烃转化为手性醇的新型全原子经济方法。获得了具有广泛的官能团耐受性，良好的产率和优异的立体选择性的一系列手性醇。

  DOI：

  10.1021/acs.orglett.8b00034

文献信息

• Polyester resin composition
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0382487A2

  公开（公告）日：1990-08-16

  A polyester resin composition of improved heat-resistant flexibility comprises: (A) a polyester copolymer prepared by the polycondensation of a component (a) mainly comprising an aromatic dicarboxylic acid or an ester-forming derivative thereof, with both a component (b) mainly comprising an aliphatic glycol, and a branch-forming component (c), wherein the component (c) is contained in an amount of 0.001 to 1.0 mole % based on the component (a), and (B) 0.1 to 10% by weight (based on the total amount of the composition) of a bisoxazoline compound.

  一种具有更好耐热柔韧性的聚酯树脂组合物包括 (A) 一种聚酯共聚物，由主要由芳香族二羧酸或其酯类衍生物组成的组分 (a) 与主要由脂肪族乙二醇组成的组分 (b) 和分支形成组分 (c) 缩聚而成、 其中组分（c）的含量为 0.001 至 1.0 摩尔%（基于组分（a）），以及 (B) 0.1 至 10%（按组合物总量计算）的双恶唑啉化合物。
• Actinic ray-sensitive or radiation-sensitive resin composition, actinic ray-sensitive or radiation-sensitive film, mask blank including actinic ray-sensitive or radiation-sensitive film, pattern forming method, and method for manufacturing electronic device
  申请人：FUJIFILM Corporation

  公开号：US10545405B2

  公开（公告）日：2020-01-28

  Provided are an actinic ray-sensitive or radiation-sensitive resin composition including a compound (A) whose dissolution rate in an alkali developer decreases by the action of an acid, a resin (B) having a group that decomposes by the action of an alkali developer to increase the solubility in the alkali developer and having at least one of a fluorine atom or a silicon atom, and a resin (C) having a phenolic hydroxyl group, different from the resin (B), an actinic ray-sensitive or radiation-sensitive film and a mask blank, each formed using the actinic ray-sensitive or radiation-sensitive resin composition, a pattern forming method using the actinic ray-sensitive or radiation-sensitive resin composition, and a method for manufacturing an electronic device.

  本发明提供了一种感光性或辐射敏感性树脂组合物，包括在酸的作用下在碱显影剂中的溶解度降低的化合物 (A)、具有在碱显影剂中分解以增加在碱显影剂中的溶解度的基团且至少具有一个氟原子或硅原子的树脂 (B) 以及具有与树脂 (B) 不同的酚羟基的树脂 (C)、使用感光性或辐射敏感性胶片和掩膜坯形成的感光性或辐射敏感性胶片和掩膜坯、和一种具有不同于树脂（B）的酚羟基的树脂（C），一种感光胶片或感光胶片和一种掩膜坯，它们分别使用感光胶片或感光胶片树脂组合物形成，一种使用感光胶片或感光胶片树脂组合物的图案形成方法，以及一种制造电子设备的方法。
• Vinyl Aromatic Compounds. VII. 1,3,5-Trivinylbenzene¹
  作者：David T. Mowry、Eugene L. Ringwald

  DOI：10.1021/ja01161a044

  日期：1950.5
• Separation of remote diol and triol stereoisomers by enzyme-catalyzed esterification in organic media or hydrolysis in aqueous media
  作者：J. Shield Wallace、Bruce W. Baldwin、Cary Morrow

  DOI：10.1021/jo00045a042

  日期：1992.9

  The separation of symmetric, remote, secondary diol stereoisomers by steroselective enzyme-catalyzed acetylation with acetic anhydride in anhydrous, low polarity organic solvents or by stereoselective enzyme-catalyzed hydrolysis of the corresponding peracetate in aqueous media is described. Whether or not an alcohol is acetylated or an acetate is hydrolyzed is determined solely by its own stereochemical arrangement and not by the stereochemistry at any other stereogenic center. Since the enzyme used, Amano P lipoprotein lipase from Pseudomonas species, acetylates secondary alcohol stereogenic centers of the (R)-configuration, an (R,R)-diol is converted to its diacetate, a meso-diol is converted to the monoacetate at its (R)-stereogenic center, and an (S,S)-diol is left unchanged. Similarly, when hydrolysis is used, (R)-stereogenic centers are hydrolyzed so that the (R,R)-stereoisomer is converted to the corresponding diol while the (S,S)-stereoisomer remains a diacetate. The resulting mixture is separated, and the remaining acetates are removed by hydrolysis to give diols and triols of high stereochemical purity. Diols successively separated by esterification include alpha,alpha-dimethyl-1,4-benzenedimethanol, 1, alpha,alpha'-dimethyl-1,3-benzenedimethanol, 4, alpha,alpha'-dimethyl-2,6-pyridinedimethanol, 5, and alpha,alpha-dimethyl-4,4-biphenylenedimethanol, 6. For two cases, alpha,alpha'-dimethyl-2,6-pyridinedimethanol, 5, and alpha,alpha',alpha''-trimethyl-1,3,5-benzenetrimethanol, 7, the separation was achieved using the hydrolysis procedure. The stereochemical purity of each of the separated diol stereoisomers was determined by evaluating the NMR spectrum of its bis-MTPA ester. In most cases, it was possible to establish both the stereochemical purity of the fraction and the amount of each contaminating stereoisomer that was present. The diol products are expected to be of value for preparing optically active polymers and optically active crown ethers.
• VINYL-CONTAINING COMPOUNDS AND PROCESSES FOR MAKING THE SAME
  申请人：Reichhold LLC 2

  公开号：EP2539387B1

  公开（公告）日：2019-06-05