4-[(2,4-二氨基-5-甲基苯基)氨基]苯酚 | 93918-03-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[(2,4-二氨基-5-甲基苯基)氨基]苯酚
• 英文名称: 4-(2,4-diamino-5-methyl-anilino)-phenol
• 英文别名: 4'-Oxy-4.6-diamino-3-methyl-diphenylamin；4-[(2,4-diamino-5-methylphenyl)amino]phenol；1,5-diamino-2-methyl-4-[N-(p-hydroxyphenyl)amino]benzene；4-((2,4-Diamino-5-methylphenyl)amino)phenol；4-(2,4-diamino-5-methylanilino)phenol
• CAS: 93918-03-7
• 化学式: C₁₃H₁₅N₃O
• 分子量: 229.282
• InChiKey: VDGHWKVBYSUBOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  84.3
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-[(2,4-二氨基-5-甲基苯基)氨基]苯酚 生成 4-(2,4-二氨基-5-甲基苯基)亚氨基环己-2,5-二烯-1-酮
  参考文献：
  名称：

  Ullmann; Gnaedinger, Chemische Berichte, 1912, vol. 45, p. 3441

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium hydroxide 、 sodium dithionite 作用下， 生成 4-[(2,4-二氨基-5-甲基苯基)氨基]苯酚
  参考文献：
  名称：

  Ullmann; Gnaedinger, Chemische Berichte, 1912, vol. 45, p. 3441

  摘要：

  DOI：

文献信息

• HAIR COLORING COMPOSITIONS
  申请人：——

  公开号：US20020032933A1

  公开（公告）日：2002-03-21

  A hair coloring composition comprising: (a) from about 0.0003 moles (per 100 g of composition) to less than about 0.09 moles (per 100 g of composition) of an inorganic peroxygen oxidizing agent; and (b) an oxidative hair coloring agent; wherein the pH of each of (a) and (b) is in the range of from about 1 to about 6 and wherein the combined mixture of (a) and (b) has a pH in the range of from about 1 to about 6. The products can provide excellent hair coloring and in-use efficacy benefits including excellent initial color and good wash fastness in combination with reduced hair damage at low pH.

  一种染发组合物，包括：(a)约0.0003摩尔（每100克组合物）至约0.09摩尔（每100克组合物）的无机过氧化氧化剂；和(b)氧化性染发剂；其中(a)和(b)的pH值在约1至约6的范围内，且(a)和(b)的混合物的pH值在约1至约6的范围内。该产品可以提供出色的染发效果和使用效果，包括出色的初始颜色和良好的耐洗性，同时在低pH值下减少头发损伤。
• Hair colouring and conditioning compositions
  申请人：The Procter & Gamble Company

  公开号：US20030113286A1

  公开（公告）日：2003-06-19

  A hair colouring and conditioning composition comprising: (a) a hair colouring agent; and (b) a hair conditioning agent; wherein the composition provides an Average Combing Index Value of greater than 1.2 as measured by the Combing Technical Test Method. The products can provide excellent hair colouring together with excellent conditioning, reduced hair damage, brittleness and dryness, and is convenient and easy to use.

  一种包括： (a) 染发剂；和 (b) 护发剂； 的染发和护理组合物； 其中该组合物通过梳理技术测试方法测得的平均梳理指数值大于1.2。 该产品可以提供优秀的染发效果以及优秀的护理效果，减少头发损伤、脆弱和干燥，且使用方便。
• Hair conditioning compositions and their use in hair colouring compositions
  申请人：The Procter & Gamble Company

  公开号：US20030219399A1

  公开（公告）日：2003-11-27

  The present invention relates to a hair care composition comprising a aminofunctional polysiloxane having a specified average effective particle size which provides improved durable conditioning particularly when utilised in conjunction with a hair colouring composition.

  本发明涉及一种头发护理组合物，包括具有特定平均有效粒径的氨基官能聚硅氧烷，当与染发组合物一起使用时，能提供改善的持久调理效果。
• Use of metal salts and chelates together with chlorites as oxidants in hair coloring
  申请人：Bristol-Myers Squibb Company

  公开号：EP0621029A1

  公开（公告）日：1994-10-26

  An aqueous hair dye composition containing from about 0.05% to 20% by weight of sodium chlorite; from about 0.001% to 5% by weight of a water soluble copper, iron, manganese or cobalt salt, a chelate of said salt, or a mixture thereof, and an oxidative hair dye precursor in an amount which will oxidize to form a tinctorially effective amount of a hair dye. Also provided are a packaged form of the components of the composition and a method of dyeing hair with the composition.

  一种水性染发组合物，含有约 0.05%至 20%（按重量计）的亚氯酸钠；约 0.001%至 5%（按重量计）的水溶性铜、铁、锰或钴盐，所述盐的螯合物，或它们的混合物，以及氧化性染发剂前体，其用量可氧化形成锡有效量的染发剂。此外，还提供了组合物组分的包装形式和用组合物染发的方法。
• Hair coloring composition
  申请人：Bristol-Myers Squibb Company

  公开号：EP0640335A2

  公开（公告）日：1995-03-01

  A two part aqueous composition for coloring and providing durable conditioning to human hair which forms a gel on mixing of an alkaline aqueous lotion first part having a pH of from about 7 to about 11 containing from about 0.005% by weight to about 5% by weight of at least one primary intermediate and at least one coupler for the formation of oxidation dyes, from about 0.1% to about 5% of a cationic polymer, from about 0.5% to about 15% by weight of an anionic or amphoteric surfactant or mixture thereof and at least 70% by weight water, and an aqueous developer second part having a pH of from about 2 to about 6 containing from about 0.5% by weight to about 40% by weight of a peroxide oxidizer and from about 0.1% by weight to about 20% by weight of an anionic polymer, the anionic polymer being characterized in that it is insoluble in the developer and dissolves in the gel which forms when the lotion and developer are mixed.

  一种用于人类头发着色和提供持久护理的双组分水性组合物，它在混合第一部分碱性水性乳液时形成凝胶，第一部分的 pH 值约为 7 至 11，其中含有约 0.005%（重量）至约 5%（重量）的至少一种初级中间体和至少一种用于形成氧化染料的偶联剂、约 0.1%至约 5%（重量）的阳离子聚合物、约 0.5%至约 15%（重量）的阴离子或两性表面活性剂或其混合物以及至少 70%（重量）的水。5%至约 15%（按重量计）的阴离子或两性表面活性剂或其混合物和至少 70%（按重量计）的水，以及 pH 值为约 2 至约 6 的第二部分水性显影剂，其中含有约 0.5%（按重量计）至约 40%（按重量计）的过氧化物氧化剂和约 0.1%（按重量计）至约 20%（按重量计）的阴离子聚合物。