2-Amino-4-[[4-chloro-6-[4-(2-sulfooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]benzenesulfonic acid | 85946-21-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Amino-4-[[4-chloro-6-[4-(2-sulfooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]benzenesulfonic acid
• CAS: 85946-21-0
• 化学式: C₁₇H₁₇ClN₆O₉S₃
• 分子量: 581.008
• InChiKey: KBOOJILXHNRGLD-UHFFFAOYSA-N

物化性质

• 密度：
  1.807±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  36
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  266
• 氢给体数：
  5
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  2-Amino-4-[[4-chloro-6-[4-(2-sulfooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]benzenesulfonic acid 在 盐酸 、 sodium nitrite 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Mixtures of reactive dyes and their use

  摘要：

  混合染料包括至少一种具有下列公式的染料和至少一种具有下列公式的染料，其中公式中所示的基团根据权利要求书的定义进行定义，适用于染色或印刷纤维素纤维材料，具有良好的建立行为和产生深色染料的良好耐久性。

  公开号：

  US20060207038A1
• 作为产物：
  描述：

  2,4-二氨基苯磺酸 以 水 、 丙酮 为溶剂， 反应 2.0h， 生成 2-Amino-4-[[4-chloro-6-[4-(2-sulfooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]benzenesulfonic acid
  参考文献：
  名称：

  Synthesis and application of novel reactive dyes based on Dimedone moiety

  摘要：

  The aim of this study is synthesising, characterizing and finding out properties of some new bifunctional dye Bis (monochlorotriazine) (MCT) and heterobifunctional (monochlorotriazine / sulphatoethylsulphone) (MCT/SES) reactive dyes using Dimedone moiety (5,5-Dimethylcyclohexane-1,3-dione) to enhance favorable properties such as, color strength and light fastness. The first dye A was prepared then coupled with diazonium salts having the reactive groups. But the second dye B was synthesiezed of Dimedone moiety (2-amino4,4-dimethy,3-cyano,6-oxo-beno[b] thiophene) after that we diazotized and coupled it with 1-amino-8-naphthol-3,6-disulphonic acid (H-acid) to produce mono azo intermediate. This product was reacted with 2,4,6-trichloro-1,3,5-triazine in 1:1 molar ratio via The aim of this study is synthesising, characterizing and finding out properties of some new bifunctional dye Bis (monochlorotriazine) (MCT) and heterobifunctional (monochlorotriazine / sulphatoethylsulphone) (MCT/SES) reactive dyes using Dimedone moiety (5,5-Dimethylcyclohexane-1,3-dione) to enhance favorable properties such as, color strength and light fastness. The first dye A was prepared then coupled with diazonium salts having the reactive groups. But the second dye B was synthesiezed of Dimedone moiety (2-amino4,4-dimethy,3-cyano,6-oxo-beno[b] thiophene) after that we diazotized and coupled it with 1-amino-8-naphthol-3,6-disulphonic acid (H-acid) to produce mono azo intermediate. By reacting this product with 2,4,6-trichloro-1,3,5-triazine with 1:1 molar ratio via nucleophilic displacement with 1,4-phenylenediamine in 2:1 molar ratio to produce bis monochlorotriazine reactive dyes thus yielding the new reactive dye. These two dyes were applied onto fabrics of silk, cotton and wool under the optimum conditions of the dyeing exhaust, then the dyeing properties were examined. The results indicate quality of the highest dyeing properties. However, the homobifunctional (bis MCT) dyes showed higher values of exhaustion and fixation, fastness properties and color yield than heterobifunctional (MCT/SES).

  DOI：

  10.21608/ejchem.2020.24092.2437

文献信息

• 반응성 황색 염료 조성물
  申请人：RIFA INDUSTRIAL CO.,LTD. 이화산업 주식회사(119990439243) Corp. No ▼ 110111-0018138

  公开号：KR20150050818A

  公开（公告）日：2015-05-11

  본 발명은 일반식 (I)로 표시되는 화합물 90-99 중량부와 일반식 (II)으로 표시되는 화합물 1-10 중량부로 혼합된 황색 염료 조성물. .......... (I) .......... (II) 여기서 A는 아래와 같다. .......... (III) .......... (IV) .......... (V) .......... (VI) 상기 식에서 R, R, R, R, R, R, R, R, R은 서로 독립적으로 수소, 메틸, 에틸, 페닐, 할로겐, 메톡시, 에톡시, 하이드록시, 우레이도, 설포, 메틸아미노, 에틸아미노, 설파모일, 카르복시기 등이고, Q는 비닐기 또는 일반식 -CHCH-L 이며, L은 -Cl, -Br, -F, -OSOH, -SSOH, -OCOCH, -OPOH, -OCO-CH, -OSO-C~C 알킬 등 이고, X는 -Cl 또는 -F 이다. 상기 염료 조성물은 높은 염착율을 갖는다. [색인어] 황색, 염료, 셀룰로스계 섬유

  本发明涉及一种混合的黄色染料组合物，其中包含90-99重量部的化合物（I）和1-10重量部的化合物（II），其分别用通式（I）和（II）表示。其中A如下所示：(III) (IV) (V) (VI)在上述公式中，R，R，R，R，R，R，R，R，R分别独立地表示氢，甲基，乙基，苯基，卤素，甲氧基，乙氧基，羟基，尿素，硫酰，甲基氨基，乙基氨基，硫代甲酰基，羧基等，Q表示乙烯基或通式-CHCH-L，L表示-Cl，-Br，-F，-OSOH，-SSOH，-OCOCH，-OPOH，-OCO-CH，-OSO-C~C烷基等，X表示-Cl或-F。该染料组合物具有高染色率。[索引词]黄色，染料，纤维素纤维
• [EN] REACTIVE DYES, THEIR PREPARATION AND THEIR USE<br/>[FR] COLORANTS REACTIFS, LEUR PREPARATION ET LEUR APPLICATION
  申请人：CIBA SC HOLDING AG

  公开号：WO2006034967A1

  公开（公告）日：2006-04-06

  Reactive dyes of formula (I) are suitable for dyeing cellulosic or amide-group-containing fibre materials.

  式(I)的反应染料适用于染色纤维素或含酰胺基团的纤维材料。
• Verfahren zum Mono-, Di- oder Trichromie-Färben oder Bedrucken von natürlichen oder synthetischen Polyamidfasermaterialien
  申请人：DyStar Textilfarben GmbH & Co. Deutschland KG

  公开号：EP1529817B1

  公开（公告）日：2007-04-11
• MORIMITSU, TOSHIHIKO;KIKKAWA, SADANOBU;HARADA, NAOKI;OMURA, TAKASHI
  作者：MORIMITSU, TOSHIHIKO、KIKKAWA, SADANOBU、HARADA, NAOKI、OMURA, TAKASHI

  DOI：——

  日期：——
• FASERREAKTIVE AZOFARBSTOFFE SOWIE FARBSTOFFGEMISCHE, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ZUM FÄRBEN ODER BEDRUCKEN
  申请人：CHT Switzerland AG

  公开号：EP3521379B1

  公开（公告）日：2020-10-14