Cd(4,4′-(carbonylimino)dibenzoato)(H2O) | 1431562-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cd(4,4′-(carbonylimino)dibenzoato)(H2O)
• CAS: 1431562-76-3
• 化学式: C₁₅H₉NO₅*Cd*H₂O
• 分子量: 413.665
• InChiKey: RNHDIEKIAASVLU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.16
• 重原子数：
  23.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  140.86
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  cadmium(II) nitrate tetrhydrate 、 水 、 4-[(4-羧基苯甲酰基)氨基]苯甲酸 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 Cd(4,4′-(carbonylimino)dibenzoato)(H2O)
  参考文献：
  名称：

  Supramolecular assembly of a series of new coordination polymers based on 4,4′-(carbonylimino)dibenzoic acid: Syntheses, structures and photoluminescence investigation

  摘要：

  Assembly reactions of acylamide-containing dicarboxylate ligand 4,4'-(carbonylimino)dibenzoic acid (H2L) with corresponding divalent metal ions resulted in the formation of seven new coordination polymers, namely Cd(L)(H2O) (1), Zn(L)(H2O) (2), Zn-5(L)(2)(OH)(6) (3), [Ni(L)(H2O)(2)]center dot H2O (4), [Cd(L)(py)(H2O)]center dot(DMF)center dot(C6H5Cl) (5), [Cd(L)(py)(2)]center dot 2CH(3)OH (6) and [Mn (HL)(2)(py)(2)]center dot 2DMF (7). In complex 1, the double chains composed Cd-II and L2- are connected by interlayer Cd-O bonds to form a three-dimensional architecture. Complex 2 exhibits a three-dimensional supramolecular architecture extended by hydrogen bonds involving O-H center dot center dot center dot O and N-H center dot center dot center dot O types. Complex 3 displays a three-dimensional framework consisting of zinc-hydroxide layers and L2- pillars. Complex 4 is also a supramolecular three-dimensional network generated from linkage of Ni-O chains via versatile hydrogen bonds. Complex 5 exhibits an interdigitated network in which the cavities are occupied by guest DMF and C6H5Cl molecules. In complex 6, two-dimensional square-grid network was generated by linkage of Cd-2 units with L2- ligands. Mono-depronated ligand presents in complex 7. The adjacent [Mn(py)(HL)] chains are arranged parallel to each other by forming hydrogen bonding between the acylamide groups and guest DMF molecules. The stability properties of 2, 3, 4, 6 and 7 have been presented. In addition, photoluminescence properties of complexes 2, 3, 5 and 6 are investigated. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.03.029