Cp*Fe(η-C₅H₅BMe) | 184349-19-7

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: Cp*Fe(η-C₅H₅BMe)
• 英文别名: [(C5(CH3)5)Fe(η-C5H5BMe)]；iron(2+);1-methyl-1-boranuidacyclohexa-1,3,5-triene;1,2,3,4,5-pentamethylcyclopenta-1,3-diene
• CAS: 184349-19-7
• 化学式: C₁₆H₂₃BFe
• 分子量: 282.017
• InChiKey: DUUXZSIFQKHQDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cp*Ru(CH3CN)3]OTf 、 Cp*Fe(η-C₅H₅BMe) 以 二氯甲烷 为溶剂， 以62%的产率得到iron(2+);1-methyl-1-boranuidacyclohexa-1,3,5-triene;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;ruthenium(2+);trifluoromethanesulfonate
  参考文献：
  名称：

  Triple-Decker Complexes. 12.¹ Triple-Decker Complexes with Bridging Boratabenzene Ligands. Syntheses, Structures of [(μ-C₅H₅BMe)(FeCp*)₂]PF₆ and of [(μ-C₅H₅BMe){Rh(COD)}₂]CF₃SO₃, and Boratabenzene Transfer Reactions

  摘要：

  The orange complex Cp*Fe(C(5)H(5)BMe) (1a) was synthesized from [Cp*Fe(NCMe)(3)]PF6 and Li(C(5)H(5)BMe) in 91% yield. Electrophilic stacking reactions with metalloelectrophiles gave the triple-decker salts [(mu-C(5)H(5)BMe)(FeCp*)(2)]PF6 (4), [(mu-C(5)H(5)BMe)(FeCp*)(RuCp*)]CF3SO3 (5), and [(mu-C(5)H(5)BMe)(FeCp*)(MCp**)](CF3SO3)(2) with M = Rh (for 6) and M = Ir (for 7). Electrophilic stacking of Rh(C(5)H(5)BMe)(COD) (8) with [(COD)Rh(MeNO(2))(x)]CF3SO3 gave [(mu-C(5)H(5)BMe){Rh(COD)}2CF3SO3 (10). The structures of the two triple-decker complexes 4 and 10 were determined by X-ray diffraction. Boratabenzene transfer reactions were found for the heterobimetallic salts 5-7.

  DOI：

  10.1021/om960536m
• 作为产物：
  描述：

  [(C5(CH3)5)Fe(μ-η:η-C5H5BCH3)Rh(C5H5)](BF4)2 以 乙腈 为溶剂， 生成 Cp*Fe(η-C₅H₅BMe)
  参考文献：
  名称：

  Dicationic triple-decker complexes with a bridging boratabenzene ligand

  摘要：

  New dicationic triple-decker complexes with a bridging boratabenzene ligand [Cp*Fe(mu-eta:eta-C5H5BMe)ML]X-2 (ML = CoCp*, 6(CF3SO3)(2); RhCp, 7(BF4)(2); IrCp, 8(CF3SO3)(2); Ru(eta-C5H6), 9(CF3SO3)(2); Ru(eta-C6H3Me3-1,3,5), 10(CF3SO3)(2); Ru(eta-C6Me6), 11(CF3SO3)(2)) were synthesized by stacking reactions of Cp*Fe(eta-C5H5BMe) (2) with the corresponding half-sandwich fragments [ML](2+). The structure of 10(CF3SO3)(2) was determined by X-ray diffraction study. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0022-328x(02)01109-9

文献信息

• (C 4 Me 4 )Co-containing triple-decker complexes with bridging heterocyclic ligands
  作者：Dmitry A. Loginov、Yulia V. Nelyubina、Alexander R. Kudinov

  DOI：10.1016/j.jorganchem.2018.06.025

  日期：2018.9

  2PF6, and 3aPF6 were determined by X-ray diffraction. The μ-pentaphospholyl complex 3a was also synthesized by exchange of sandwich compounds in the μ-cyclopentadienyl triple-decker complexes [(μ-η:η-Cp)Co(C4Me4)}2]+ or [(C4Me4)Co(μ-η:η-Cp)FeCp]+. Complexes 1, 2, and 3a undergo nucleophilic degradation by acetone and acetonitrile with selective elimination of the [(C4Me4)Co]+ fragment giving the starting

  （C 4 Me 4）Co与桥联的硼和磷杂环配体[（C 4 Me 4）Co（μ-η：η-L）MCa href=https://www.molaid.com/MS_6449 target="_blank">CP *] +（1：M = Fe，L =通过光化学合成C 5 H 5 BMe；2：M ＝ Fe，L ＝ C 4 Me 4 P；3a：M ＝ Fe，L ＝ 环-P 5；3b：M ＝ Ru，L ＝ 环-P 5）。 [（C 4 Me 4）Co（C 6 H 6）]的反应+含夹心化合物CP * ML。分离它们与PF盐6 -阴离子，和的结构1 PF 6，2 PF 6，和图3a PF 6通过X射线衍射确定。μ-pentaphospholyl复杂3A也是由在μ -环戊二烯基三重双层复合夹心化合物的交换合成[（μ-η：η-CP）钴（C 4我4）} 2 ] +或[（C 4 Me 4）Co（μ-η：η-CP）FeCP] +。配合物1，2，和3a通过丙酮和乙腈进行亲核降解，并选择性消除[（C 4 Me 4）Co] +片段