2,3,2'-BIPHENYLTRICARBOXYLIC ACID | 4371-39-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,2'-BIPHENYLTRICARBOXYLIC ACID
• 英文别名: biphenyltricarboxylic acid；biphenyl-2,3,2'-tricarboxylic acid；Biphenyl-2,3,2'-tricarbonsaeure；3-(2-Carboxyphenyl)phthalic acid
• CAS: 4371-39-5
• 化学式: C₁₅H₁₀O₆
• 分子量: 286.241
• InChiKey: HDWIHVKOYQRVNJ-UHFFFAOYSA-N

物化性质

• 熔点：
  195-196 °C (decomp)
• 沸点：
  518.8±45.0 °C(Predicted)
• 密度：
  1.488±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  硫酸 、 2,3,2'-BIPHENYLTRICARBOXYLIC ACID 生成 9-oxo-fluorene-1,5-dicarboxylic acid
  参考文献：
  名称：

  Charrier; Ghigi, Chemische Berichte, 1936, vol. 69, p. 2211,2227

  摘要：

  DOI：
• 作为产物：
  描述：

  2'-formyl-biphenyl-2,3'-dicarboxylic acid 在 盐酸 、 potassium permanganate 、 amalgamated zinc 、 溶剂黄146 作用下， 生成 2,3,2'-BIPHENYLTRICARBOXYLIC ACID
  参考文献：
  名称：

  Pozzo-Balbi, Gazzetta Chimica Italiana, 1951, vol. 81, p. 125,127

  摘要：

  DOI：

文献信息

• Process for production of 2, 3, 3', 4'-biphenyltetracarboxylic dianhydride
  申请人：Nakayama Tatsushi

  公开号：US20060247445A1

  公开（公告）日：2006-11-02

  A process for producing 2,3,3′,4′-biphenyltetracarboxylic dianhydride (a-BPDA), comprising dehydrating 2,3,3′,4′-biphenyltetracarboxylic acid in an inert gas atmosphere under heating at 180 to 195° C is disclosed. This process produces high-purity a-BPDA which is suitable for production of a polyimide.

  生产2,3,3′,4′-联苯四羧酐（a-BPDA）的方法包括在惰性气氛下，在180至195°C的加热下脱水2,3,3′,4′-联苯四羧酸。该过程生产适用于聚酰亚胺生产的高纯度a-BPDA。
• Metallo-β-lactamase inhibitory activity of phthalic acid derivatives
  作者：Yukiko Hiraiwa、Akihiro Morinaka、Takayoshi Fukushima、Toshiaki Kudo

  DOI：10.1016/j.bmcl.2009.07.018

  日期：2009.9

  4-Butyl-3-methylphthalic acid was recognized as a metallo-β-lactamase inhibitor. The structure–activity relationship study of substituted phthalic acids afforded 3-phenylphthalic acid derivatives as potent IMP-1 inhibitors. On the other hand, 3-substituted with 4-hydroxyphenyl phthalic acid derivative displayed a potent combination effect with biapenem (BIPM) against Pseudomonas aeruginosa that produce

  4-丁基-3-甲基邻苯二甲酸被认为是金属β-内酰胺酶抑制剂。取代邻苯二甲酸的结构-活性关系研究提供了3-苯基邻苯二甲酸衍生物作为有效的IMP-1抑制剂。另一方面，用4-羟基苯基邻苯二甲酸衍生物进行的3-取代显示出与比安培南（BIPM）对产生IMP-1的铜绿假单胞菌的有效组合作用。
• [EN] MULTIMER FORMS OF MONO- AND BIS-ACYLPHOSPHINE OXIDES<br/>[FR] FORMES MULTIMERIQUES D'OXYDES DE MONOACYLPHOSPHINE ET DE BISACYLPHOSPHINE
  申请人：CIBA SC HOLDING AG

  公开号：WO2003104245A1

  公开（公告）日：2003-12-18

  The invention relates to dimer and multimer forms of BAPO compounds of the formula (1) dimer and multimer forms of MAPO compounds of the formula (II) wherein R1, R2, and R3 independently of one another are unsubstituted or substituted C1-C12alkyl, benzyl, C1-C12alkoxy, C3-C6cycloalkyl or C5-C14aryl; Q is a di-tri or tetravalent arylene residue; n is 1-4, m is 0-2, n+m is 2, 3 or 4, with the proviso, that R1 and R3 are different from each other. The invention further relates to a process for the preparation of dimer or multimer forms of BAPO compounds of the formula (I) and of dimer or multimer forms of MAPO compounds of the formula (II), characterized in the (n + m) equivalents of a dimetalated-phosphine R1P(M)2 is reacted with one equivalent of a di-or polycarboxylic acid halogenide to form an intermediate of the formula III the intermediate is then reacted either with (n + m) equivalents of a further carboxylic acid halogenide (R2-CO-Hal) or with a halogenide R3-Hal, the reaction products are then oxidized to form phosphine oxides of the formula I or II.

  本发明涉及公式（I）的BAPO化合物的二聚体和多聚体形式以及公式（II）的MAPO化合物的二聚体和多聚体形式，其中R1，R2和R3彼此独立地是未取代或取代的C1-C12烷基，苯甲基，C1-C12烷氧基，C3-C6环烷基或C5-C14芳基; Q是二-三或四价芳基残基; n为1-4，m为0-2，n+m为2、3或4，但R1和R3不同于对方。本发明还涉及制备公式（I）的BAPO化合物的二聚体或多聚体形式以及公式（II）的MAPO化合物的二聚体或多聚体形式的方法，其特征在于将（n+m）当量的二金属化磷R1P（M）2与一个当量的二或多羧酸卤化物反应形成公式III的中间体，然后将中间体与（n+m）当量的进一步羧酸卤化物（R2-CO-Hal）或卤化物R3-Hal反应，然后将反应产物氧化成公式I或II的氧化磷化合物。
• DIAMINE COMPOUND, AND HEAT-RESISTANT RESIN OR HEAT-RESISTANT RESIN PRECURSOR USING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20170334837A1

  公开（公告）日：2017-11-23

  Provided are a photosensitive resin composition which has excellent pattern processabilities (high sensitivity and high resolution) and is excellent in chemical resistance and thermal resistance after thermally treated; a heat-resistant resin or heat-resistant resin precursor used for the composition; and a diamine compound which is a raw material of the resin and the precursor. The diamine compound is a diamine compound represented by a general formula (1).

  提供了一种具有优异图案加工性（高灵敏度和高分辨率）且在热处理后具有优异化学耐性和热耐性的光敏树脂组合物；用于该组合物的耐热树脂或耐热树脂前体；以及作为树脂和前体原料的二胺化合物。该二胺化合物是由通式（1）表示的二胺化合物。
• Process and Catalyst for Oxidizing Aromatic Compounds
  申请人：Gong William H.

  公开号：US20090069594A1

  公开（公告）日：2009-03-12

  Catalytic compositions for conversion of substituted aromatic feed materials to oxidized products comprising aromatic carboxylic acid derivatives of the substituted aromatic feed materials comprise at least two metal or metalloid elements, at least one of which is palladium, platinum, vanadium or titanium, and at least one of which is a Group 5, 6, 14 or 15 metal or metalloid. A process for oxidizing substituted aromatic feed materials comprises contacting the feed material with oxygen in the presence of such a catalytic composition in a liquid reaction mixture.

  用于将取代芳香族原料转化为含取代芳香族羧酸衍生物的氧化产物的催化组合物至少包含两种金属或金属元素，其中至少一种是钯、铂、钒或钛，而至少一种是第5、6、14或15组金属或金属元素。一种氧化取代芳香族原料的方法包括在液体反应混合物中，在存在这样的催化组合物的情况下，将原料与氧接触。