[Cu(μ-pyridine-2,5-dicarboxylic acid)₂]_n | 30207-39-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(μ-pyridine-2,5-dicarboxylic acid)₂]_n
• 英文别名: copper;6-carboxypyridine-3-carboxylate
• CAS: 30207-39-7
• 化学式: C₁₄H₈CuN₂O₈
• 分子量: 395.772
• InChiKey: UJCFMHDOWAMVGA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Cu(μ-pyridine-2,5-dicarboxylic acid)₂]_n 、 三甲基氯化锡 反应 4.0h， 生成 [Cu(Me3Sn)2-(μ-pyridine-2,5-dicarboxylic acid)2]n
  参考文献：
  名称：

  Two-Dimensional Homometallic- to a Three Dimensional Heterometallic Coordination Polymer: A Metalloligand Approach

  摘要：

  A metalloligand type of synthetic route has been followed to generate a novel heterometallic three-dimensional (3D)-coordination polymer containing Cu(II) and trimethyltin as nodes. The first step of this synthetic path consisted of the preparation of a two-dimensional-coordination polymer of Cu(II), [Cu(mu-LH)(2)](n) (1) (LH2 = pyridine-2,5-dicarboxylic add). The reaction of in situ generated 1 with Me3SnCl afforded the heterometallic 3D-coordination polymer, [Cu(Me3Sn)(2)-(mu-L)(2)](n), (2). The latter is a 4,4-connected polymer with a sqc topology. This 3D-framework contains a paddle-wheel-shaped core comprised of two heterometallic (Cu-II/Sn-IV) macrocycles.

  DOI：

  10.1021/cg401698a
• 作为产物：
  描述：

  2,5-二吡啶羧酸 、 copper(II) nitrate trihydrate 在 三乙胺 作用下， 反应 3.0h， 生成 [Cu(μ-pyridine-2,5-dicarboxylic acid)₂]_n
  参考文献：
  名称：

  Two-Dimensional Homometallic- to a Three Dimensional Heterometallic Coordination Polymer: A Metalloligand Approach

  摘要：

  A metalloligand type of synthetic route has been followed to generate a novel heterometallic three-dimensional (3D)-coordination polymer containing Cu(II) and trimethyltin as nodes. The first step of this synthetic path consisted of the preparation of a two-dimensional-coordination polymer of Cu(II), [Cu(mu-LH)(2)](n) (1) (LH2 = pyridine-2,5-dicarboxylic add). The reaction of in situ generated 1 with Me3SnCl afforded the heterometallic 3D-coordination polymer, [Cu(Me3Sn)(2)-(mu-L)(2)](n), (2). The latter is a 4,4-connected polymer with a sqc topology. This 3D-framework contains a paddle-wheel-shaped core comprised of two heterometallic (Cu-II/Sn-IV) macrocycles.

  DOI：

  10.1021/cg401698a

文献信息

• Construction of polynuclear copper(II) complexes from mono- and binuclear modules
  作者：Andrei A. PATRASCU、Catalin MAXIM、Marius ANDRUH

  DOI：10.33224/rrch.2020.65.6.04

  日期：——

  A trinuclear complex and a 1D coordination polymer, [Cu2L1(mu-OH)}Cu(2,5-pydc)(2)(dmf)}]center dot 4H(2)O (1) and (infinity)[Cu2L2}Cu(2,5-pydc)(2)(OClO3)(2)}][Cu2L2(OH2)(2)] (2), have been assembled using two binuclear copper(II) complexes with an end-off-, and, respectively, macrocyclic Robson ligands, and a mononuclear metalloligand, [Cu(2,5-pydc)(2)](2-) (HL1 and H2L2 are bicompartmental Schiff-base ligands resulting from condensation reactions between 2,6-diformyl-p-cresol with N,N-dimethylethylenediamine and, respectively, ethylenediamine; 2,5-pydc(2-) = the dianion of the 2,5-pyridyl-dicarboxilc acid). The crystal structures of the two compounds have been solved.
• MUTAFCHIEVA E.; ALEKSANDROV N.; GOSPODINOV N.; PAXHEBA YA., FARMATSIYA (NRB), 1974, 24, HO 6, 1-5
  作者：MUTAFCHIEVA E.、 ALEKSANDROV N.、 GOSPODINOV N.、 PAXHEBA YA.

  DOI：——

  日期：——