1,3-(Ph2P(o-C6H4)CH=N)2C6H4 | 1307797-30-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-(Ph2P(o-C6H4)CH=N)2C6H4
• 英文别名: 1-(2-diphenylphosphanylphenyl)-N-[3-[(2-diphenylphosphanylphenyl)methylideneamino]phenyl]methanimine
• CAS: 1307797-30-3
• 化学式: C₄₄H₃₄N₂P₂
• 分子量: 652.715
• InChiKey: YSTMLEVGLMPHHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  48
• 可旋转键数：
  10
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 1,3-(Ph2P(o-C6H4)CH=N)2C6H4 以 乙腈 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Synthesis of a new tetradentate bis(imino-phosphine) ligand and its complexation with copper(I) ions

  摘要：

  Schiff base condensation of m-phenylenediamine with two equivalents of o-(diphenylphophino) benzaldehyde products the potentially tetradentate molecule 1,3-(Ph(2)P(o-C(6)H(4))CH=N)(2)C(6)H(4) (1) in high yield. The reaction of 1 and [Cu(NCMe)(4)]BF(4) affords the dinuclear complex [(1,3-(Ph(2)P(o-C(6)H(4))CH=N)(2)C(6)H(4))(2)-Cu(2)](BF(4))(2) (2) through coordination of the imino-phosphine groups. The structure of 2 has been determined by an X-ray diffraction study. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.015
• 作为产物：
  描述：

  2-二苯基膦苯甲醛 、 间苯二胺 以 苯 为溶剂， 反应 8.0h， 以90%的产率得到1,3-(Ph2P(o-C6H4)CH=N)2C6H4
  参考文献：
  名称：

  Synthesis of a new tetradentate bis(imino-phosphine) ligand and its complexation with copper(I) ions

  摘要：

  Schiff base condensation of m-phenylenediamine with two equivalents of o-(diphenylphophino) benzaldehyde products the potentially tetradentate molecule 1,3-(Ph(2)P(o-C(6)H(4))CH=N)(2)C(6)H(4) (1) in high yield. The reaction of 1 and [Cu(NCMe)(4)]BF(4) affords the dinuclear complex [(1,3-(Ph(2)P(o-C(6)H(4))CH=N)(2)C(6)H(4))(2)-Cu(2)](BF(4))(2) (2) through coordination of the imino-phosphine groups. The structure of 2 has been determined by an X-ray diffraction study. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.015

文献信息

• Synthesis of a new tetradentate bis(imino-phosphine) ligand and its complexation with copper(I) ions
  作者：Chi-Shian Chen、Wen-Yann Yeh

  DOI：10.1016/j.ica.2011.02.015

  日期：2011.5

  Schiff base condensation of m-phenylenediamine with two equivalents of o-(diphenylphophino) benzaldehyde products the potentially tetradentate molecule 1,3-(Ph(2)P(o-C(6)H(4))CH=N)(2)C(6)H(4) (1) in high yield. The reaction of 1 and [Cu(NCMe)(4)]BF(4) affords the dinuclear complex [(1,3-(Ph(2)P(o-C(6)H(4))CH=N)(2)C(6)H(4))(2)-Cu(2)](BF(4))(2) (2) through coordination of the imino-phosphine groups. The structure of 2 has been determined by an X-ray diffraction study. (C) 2011 Elsevier B. V. All rights reserved.