3,7-Bis(3-bromo-4,5-dimethoxyphenyl)furo[2,3-f][1]benzofuran-2,6-dione | 1310739-87-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,7-Bis(3-bromo-4,5-dimethoxyphenyl)furo[2,3-f][1]benzofuran-2,6-dione
• 英文别名: 3,7-bis(3-bromo-4,5-dimethoxyphenyl)furo[2,3-f][1]benzofuran-2,6-dione
• CAS: 1310739-87-7
• 化学式: C₂₆H₁₈Br₂O₈
• 分子量: 618.232
• InChiKey: NEIXMOBPXAVDFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  在 硝基苯 作用下， 生成 3,7-Bis(3-bromo-4,5-dimethoxyphenyl)furo[2,3-f][1]benzofuran-2,6-dione
  参考文献：
  名称：

  Low-Bandgap Benzodifuranone-Based Polymers

  摘要：

  pi-Conjugated monomers and polymers containing benzodifuranone units in the main chain were prepared. Polymers were obtained using palladium-catalyzed Suzuki and Stifle polycondensation reactions of dibromo-substituted benzodifuranone derivatives with either dihexylfluorene diboronester or bis(trimethylstannyl)thiophene. The optical and electronic properties were investigated using UV/vis absorption spectroscopy and cyclic voltammetry. It was found that the polymers show very broad absorption bands with a high extinction coefficient up to 32500 L mol(-1) cm(-1). The polymers also show reversible redox behavior, giving small HOMO-LUMO gaps up to 1.30 eV with strong donor-acceptor character.

  DOI：

  10.1021/ma2008628

文献信息

• [EN] POLYMERS BASED ON BENZODIONES<br/>[FR] POLYMÈRES À BASE DE BENZODIONES
  申请人：BASF SE

  公开号：WO2012017005A2

  公开（公告）日：2012-02-09

  The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I): wherein Y is a group of formula (AA), or (BB) and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
• Low-Bandgap Benzodifuranone-Based Polymers
  作者：Kai Zhang、Bernd Tieke

  DOI：10.1021/ma2008628

  日期：2011.6.28

  pi-Conjugated monomers and polymers containing benzodifuranone units in the main chain were prepared. Polymers were obtained using palladium-catalyzed Suzuki and Stifle polycondensation reactions of dibromo-substituted benzodifuranone derivatives with either dihexylfluorene diboronester or bis(trimethylstannyl)thiophene. The optical and electronic properties were investigated using UV/vis absorption spectroscopy and cyclic voltammetry. It was found that the polymers show very broad absorption bands with a high extinction coefficient up to 32500 L mol(-1) cm(-1). The polymers also show reversible redox behavior, giving small HOMO-LUMO gaps up to 1.30 eV with strong donor-acceptor character.