[(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] | 252032-16-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]
• 英文别名: [dppx*Ru(p-cym)Cl2]；dichlororuthenium;[4-(diphenylphosphanylmethyl)phenyl]methyl-diphenylphosphane;1-methyl-4-propan-2-ylbenzene
• CAS: 252032-16-9
• 化学式: C₄₂H₄₂Cl₂P₂Ru
• 分子量: 780.719
• InChiKey: FKFRWUCOTRSMHO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  硼烷四氢呋喃络合物 、 [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] 以 二氯甲烷 为溶剂， 以75.3%的产率得到[BH3*(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]
  参考文献：
  名称：

  [BH₃·PPh₂CH₂C₆H₄CH₂PPh₂·Ru(p-cym)Cl₂]:  A New Bifunctional Compound and Prototype of a Linked Borane/Metal Cluster Species

  摘要：

  The species [BH3. PPh2CH2C6H4CH2Ph2P .(p-cym)RuCl2], which is a bidentate phosphine ligand with a complexed Ru moiety at one end and a borane(1) group at the other end, has been prepared and characterized spectroscopically and the crystal structure reported. The molecule adopts a conformation in which the P atoms are syn to each other and the species exhibits novel long range 31P-31P NMR coupling.

  DOI：

  10.1021/ic990687s
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 α,α'-bis(diphenylphosphino)-p-xylene 以 二氯甲烷 为溶剂， 以62.1%的产率得到[(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]
  参考文献：
  名称：

  [BH₃·PPh₂CH₂C₆H₄CH₂PPh₂·Ru(p-cym)Cl₂]:  A New Bifunctional Compound and Prototype of a Linked Borane/Metal Cluster Species

  摘要：

  The species [BH3. PPh2CH2C6H4CH2Ph2P .(p-cym)RuCl2], which is a bidentate phosphine ligand with a complexed Ru moiety at one end and a borane(1) group at the other end, has been prepared and characterized spectroscopically and the crystal structure reported. The molecule adopts a conformation in which the P atoms are syn to each other and the species exhibits novel long range 31P-31P NMR coupling.

  DOI：

  10.1021/ic990687s

文献信息

• Degradation and modification of metallaboranes. Part 4: Synthesis and characterization of a series of hybrid bimetallaborane clusters of the type [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7-3-(BH2PPh2)CxHyPPh2RuCl2(p-cym)]
  作者：Paul McQuade、Rudolph E.K. Winter、Nigam P. Rath、Lawrence Barton

  DOI：10.1016/j.ica.2004.10.015

  日期：2005.3

  formula PPh 2 (CH 2 ) n PPh 2 , and the air stable hexaborane(10) analogue [2,2,2-(PPh 3 ) 2 (CO)- nido -2-OsB 5 H 9 ] ( 1 ), afford species of the type [(PPh 3 ) 2 (CO)OsB 4 H 7 }-3-BH 2 PPh 2 (CH 2 ) n (PPh 2 )}] ( 2 ) which contain a pendent PPh 2 group. In solution 2 can undergo an intramolecular substitution reaction to form the species [(PPh 3 )(CO)OsB 4 H 7 }-η 2 -3,2-BH 2 PPh 2 (CH 2 ) n (PPh

  一系列通式为PPh 2（CH 2）n PPh 2的双齿膦与空气稳定的六硼烷（10）类似物[2,2,2-（PPh 3）2（CO）-nido-2-的反应OsB 5 H 9]（1），提供[[（（PPh 3）2（CO）OsB 4 H 7} -3- BH 2 PPh 2（CH 2）n（PPh 2）}}（2 ），其中包含一个悬垂的PPh 2组。在溶液2中可以进行分子内取代反应以形成物质[（PPh 3）（CO）OsB 4 H 7}-η2 -3,2- BH 2 PPh 2（CH 2）n（PPh 2）} ]（4）。尽管如此，仍可研究悬垂的PPh 2基团的化学反应，并在此报道2与有机金属试剂[（p -cym）RuX 2] 2（X = Cl，I）的反应结果，从而得到杂化双金属劳工烷[2,2,2-（PPh 3）2（CO）-nido -2-OsB 4 H 7 -3-（BH 2 PPh 2）C x H y PPh