2,4-bis(4-(tert-butyl)phenyl)-6-(6-phenylpyridin-3-yl)-1,3,5-triazine | 1202823-73-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,4-bis(4-(tert-butyl)phenyl)-6-(6-phenylpyridin-3-yl)-1,3,5-triazine
• 英文别名: 2,4-Bis(4-tert-butylphenyl)-6-(6-phenylpyridin-3-yl)-1,3,5-triazine
• CAS: 1202823-73-1
• 化学式: C₃₄H₃₄N₄
• 分子量: 498.671
• InChiKey: ALDKFPYSHJBKAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  38
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4-bis(4-(tert-butyl)phenyl)-6-(6-phenylpyridin-3-yl)-1,3,5-triazine 在 iridium(III) chloride trihydrate 作用下， 以 乙二醇乙醚 、 水 为溶剂， 反应 15.0h， 生成
  参考文献：
  名称：

  METAL COMPLEX, POLYMER, AND ELEMENT OBTAINED USING SAME

  摘要：

  公开号：

  EP2492276B1
• 作为产物：
  描述：

  2,4-双[4-(叔丁基)苯基]-6-氯-1,3,5-三嗪 、 2-苯基吡啶-5-硼酸 在 四(三苯基膦)钯 sodium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 17.0h， 生成 2,4-bis(4-(tert-butyl)phenyl)-6-(6-phenylpyridin-3-yl)-1,3,5-triazine
  参考文献：
  名称：

  METAL COMPLEX, POLYMER, AND ELEMENT OBTAINED USING SAME

  摘要：

  公开号：

  EP2492276B1

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20160359122A1

  公开（公告）日：2016-12-08

  Novel ligands for metal complexes containing five-membered ring fused on pyrimidine ring combined with partially fluorinated side chains exhibiting improved external quantum efficiency and lifetime are disclosed.

  本发明揭示了一种含有五元环融合在嘧啶环上的金属配合物新配体，其与部分氟化侧链结合，表现出改善的外部量子效率和寿命。
• POLYMERIC COMPOUND CONTAINING METAL COMPLEX RESIDUE AND ELEMENT COMPRISING SAME
  申请人：Akino Nobuhiko

  公开号：US20110124808A1

  公开（公告）日：2011-05-26

  A polymeric compound containing a residue of a metal complex represented by formula (1) [wherein M represents a metal atom selected from ruthenium, rhodium, palladium, osmium, iridium and platinum; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 8 independently represent a hydrogen atom, a halogen atom, an alkyl group, or the like; m represents an integer of 1 to 3; n represents an integer of 0 to 2; Z 1 , Z 2 , Z 3 , Z 4 and Z 5 independently represent a carbon atom or a nitrogen atom, provided that at least two member of Z 1 , Z 2 , Z 3 , Z 4 and Z 5 represent a nitrogen atom, and when any one member of Z 1 , Z 2 , Z 3 , Z 4 and Z 5 represents a carbon atom, a hydrogen atom bound to the carbon atom may be substituted by a substituent; a moiety represented by formula (2) represents a bidentate monoanionic ligand; and Rx and Ry are atoms bound to the metal atom M and independently represent a carbon atom, an oxygen atom or a nitrogen atom] and a bivalent group.

  一种聚合物化合物，其中包含由公式（1）表示的金属配合物残基 [其中M代表从钌、铑、钯、锇、铱和铂中选择的金属原子；R1、R2、R3、R4、R5、R6和R8分别独立地表示氢原子、卤素原子、烷基或类似物；m表示1到3的整数；n表示0到2的整数；Z1、Z2、Z3、Z4和Z5独立地表示碳原子或氮原子，但至少有两个成员是氮原子，当Z1、Z2、Z3、Z4和Z5中的任何一个成员表示碳原子时，与碳原子结合的氢原子可以被取代；由公式（2）表示的基团表示一个双齿单负离子配体；Rx和Ry是与金属原子M结合的原子，独立地表示碳原子、氧原子或氮原子]和一个二价基团。
• HIGH MOLECULAR COMPOUND, METHOD FOR PRODUCING SAME, AND LIGHT-EMITTING ELEMENT
  申请人：Goto Osamu

  公开号：US20130248778A1

  公开（公告）日：2013-09-26

  A polymer compound is provided for achieving satisfactory brightness even at a low driving voltage when applied to a light-emitting device. A preferred embodiment includes multiple first groups and a block (A) having a structure in which the first groups are linked by a second group represented by formula (0-0), and includes at least one of a group represented by formula (0-1) or a group represented by formula (0-2) as the first group; wherein Ar 0 represents an optionally substituted arylene group or divalent aromatic heterocyclic group having a structure different from the first group; n represents an average chain length of Ar 0 and equals 1.0 to 8.0; and X 11 to X 16 and X 21 to X 25 each represent a carbon atom or a nitrogen atom, where two or three of X 11 to X 16 are a nitrogen atom and three of X 21 to X 25 are a nitrogen atom.

  提供了一种聚合物化合物，可在低驱动电压下应用于发光装置，以实现令人满意的亮度。首选实施例包括多个第一组和一个具有结构的块(A)，其中第一组由由公式(0-0)表示的第二组连接，并且至少包括由公式(0-1)或公式(0-2)表示的一组作为第一组;其中Ar0表示结构不同于第一组的可选取代芳基或二价芳香杂环基；n表示Ar0的平均链长，等于1.0至8.0；X11到X16和X21到X25分别表示碳原子或氮原子，其中X11到X16中的两个或三个为氮原子，X21到X25中的三个为氮原子。
• Film production method
  申请人：Sumitomo Chemical Company, Limited

  公开号：US10964902B2

  公开（公告）日：2021-03-30

  A method of producing a film having excellent external quantum efficiency when used in a light emitting layer of a light emitting device is provided. A method of film production includes preparing an ink containing a specific metal complex, storing the ink for 3 days or more under light shielding, and forming a film by using the stored ink. The total content of metal complexes having a molecular weight larger by 16, 32 or 48 than that of the specific metal complex according to an area percentage value determined by liquid chromatography is 0.6 or less when the content of the specific metal complex is taken as 100.

  本发明提供了一种生产薄膜的方法，该薄膜用于发光器件的发光层时具有极佳的外部量子效率。薄膜的生产方法包括制备含有特定金属络合物的墨水，在遮光条件下将墨水储存 3 天或更长时间，然后使用储存的墨水形成薄膜。根据液相色谱法测定的面积百分比值，分子量比特定金属络合物大 16、32 或 48 倍的金属络合物的总含量在特定金属络合物含量为 100 时为 0.6 或以下。
• METAL COMPLEX, POLYMER COMPOUND AND DEVICE USING THE SAME
  申请人：Okamura Rei

  公开号：US20120205585A1

  公开（公告）日：2012-08-16

  A metal complex represented by the following formula (1): wherein R 1 to R 6 , R 8 and R 11 to R 20 represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkylthio group, an aryl group, an aryloxy group, an arylthio group, an arylalkyl group, an arylalkoxy group, an arylalkylthio group, an acyl group, an acyloxy group, an amide group, an acid imide group, an imine residue, a substituted amino group, a substituted silyl group, a substituted silyloxy group, a substituted silylthio group, a substituted silylamino group, a monovalent heterocyclic group, a heteroaryloxy group, a heteroarylthio group, an arylalkenyl group, an arylalkynyl group, a substituted carboxyl group or a cyano group; Z 1 to Z 5 represent —C(R*)═ or a nitrogen atom, wherein R* represents a hydrogen atom or a substituent, provided that at least two of Z 1 to Z 5 are nitrogen atoms; m represents 1 or 2.