6-phenyl-5,6-dihydro-dibenzo[c,e][1,2]azaphosphinine 6-oxide | 110059-84-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6-phenyl-5,6-dihydro-dibenzo[c,e][1,2]azaphosphinine 6-oxide
• 英文别名: 10-Phenyl-9,10-dihydro-9,10-aza-phospha-phenanthrenoxid-(10)；10-Phenyl-9,10-dihydro-9-aza-10-phospha-phenanthren-10-oxid；6-phenyl-5H-benzo[c][2,1]benzazaphosphinine 6-oxide
• CAS: 110059-84-2
• 化学式: C₁₈H₁₄NOP
• 分子量: 291.289
• InChiKey: QJXVKUPQDOBNGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-氨基联苯 以 二氯甲烷 为溶剂， 生成 6-phenyl-5,6-dihydro-dibenzo[c,e][1,2]azaphosphinine 6-oxide
  参考文献：
  名称：

  New Heteroaromatic Compounds. Part VI. Novel Heterocyclic Compounds of Phosphorus

  摘要：

  DOI：

  10.1021/ja01506a032

文献信息

• New Heteroaromatic Compounds. Part VI. Novel Heterocyclic Compounds of Phosphorus
  作者：M. J. S. Dewar、Ved P. Kubba

  DOI：10.1021/ja01506a032

  日期：1960.11
• 5,6-DIPHENYL-5,6-DIHYDRO-DIBENZ[C,E][1,2]AZAPHOSPHORIN AND 6-PHENYL-6H-DIBENZO[C,E][1,2]THIAZIN-5,5-DIOXIDE DERIVATIVES AND SIMILAR COMPOUNDS AS ORGANIC ELECTROLUMINESCENT MATERIALS FOR OLEDS
  申请人：Merck Patent GmbH

  公开号：US20220020934A1

  公开（公告）日：2022-01-20

  The present invention relates to 5,6-diphenyl-5,6-dihydrodibenz[c,e][1,2]azaphosphorin and 6-phenyl-6H-dibenzo[c,e][1,2]thiazine 5,5-dioxide derivatives and similar compounds of the formula (1) as organic electroluminescent materials for use in organic electroluminescent devices, for example in organic light-emitting diodes (OLEDs), where the symbols used are as follows: Z is the same or different at each instance and is PAr 2 or S(═O); E is the same or different at each instance and is O or S when the symbol Z to which this E binds is PAr 2 , and O when the symbol Z to which this E binds is S(═O); L is selected from the group consisting of a single bond, NAr 2 , O, S, S(═O) 2 , P(═O)Ar 2 , —X═X— and —C(═O)—NAr 2 ; the rest of the symbols are defined in the claims. The present invention discloses synthesis examples of inventive compounds, productions of OLEDs containing these example compounds, and results for these electroluminescent devices.
• 975. Synthesis and stereochemistry of heterocyclic phosphorus compounds. Part I. Preparation of (+)- and (–)-10-p-dimethylaminophenyl-9,10-dihydro-9-aza-10-phosphaphenanthrene
  作者：I. G. M. Campbell、J. K. Way

  DOI：10.1039/jr9600005034

  日期：——