1-N,1-N,4-N-triphenyl-4-N-[4-(N-[4-(N-phenylanilino)phenyl]anilino)phenyl]benzene-1,4-diamine | 141546-10-3

分子结构分类

有机化合物 - 有机氮化合物

中文名称

——

中文别名

——

英文名称

1-N,1-N,4-N-triphenyl-4-N-[4-(N-[4-(N-phenylanilino)phenyl]anilino)phenyl]benzene-1,4-diamine

英文别名

FTP；N~4~,N~4'~-(1,4-Phenylene)bis(N~1~,N~1~,N~4~-triphenylbenzene-1,4-diamine)

1-N,1-N,4-N-triphenyl-4-N-[4-(N-[4-(N-phenylanilino)phenyl]anilino)phenyl]benzene-1,4-diamine化学式

CAS

141546-10-3

化学式

C₅₄H₄₂N₄

mdl

——

分子量

746.954

InChiKey

OLUMNEXGMXIAMJ-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

物化性质

密度：

1.216±0.06 g/cm3(Predicted)

计算性质

辛醇/水分配系数(LogP)：

14.9
重原子数：

58
可旋转键数：

12
环数：

9.0
sp3杂化的碳原子比例：

0.0
拓扑面积：

13
氢给体数：

0
氢受体数：

4

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
N,N'-二苯基-1,4-苯二胺	N,N'-diphenyl-1,4-phenylenediamine	74-31-7	C₁₈H₁₆N₂	260.338
4-溴三苯胺	4-N,N-diphenylamino-1-bromobenzene	36809-26-4	C₁₈H₁₄BrN	324.22

反应信息

作为产物：

描述：

N,N'-二苯基-1,4-苯二胺、 4-溴三苯胺在三叔丁基膦、 potassium tert-butylate 、 palladium diacetate 作用下，以甲苯为溶剂，反应 12.0h，以87.9%的产率得到1-N,1-N,4-N-triphenyl-4-N-[4-(N-[4-(N-phenylanilino)phenyl]anilino)phenyl]benzene-1,4-diamine

参考文献：

名称：

具有四电子氧化还原中心的聚三苯胺衍生物，可作为高自由基密度的有机阴极†

摘要：

高自由基密度的聚三苯胺衍生物，poly（1- N，1- N，4- N -triphenyl-4- N- [4-（N- [4-（N-苯基苯胺基）苯基]苯胺基）苯基]苯-1,4-二胺）（PFTP）首次被研究用作有机自由基电池的正极材料。用拉曼光谱（RS），电子自旋共振（ESR），热解-气相色谱-质谱（Py-GC-MS）对所制备聚合物的分子结构，热稳定性，形貌，光谱特征和电化学性质进行了表征。 MALDI-TOF质谱，热重分析（TGA），紫外可见光谱（UV-vis），扫描电子显微镜（SEM），循环伏安法（CV）和电化学阻抗谱（EIS）。另外，通过恒电流充放电测试研究了所制备聚合物的充放电性能。与PTPA相比，发现PFTP不仅具有改善的热稳定性和形态，而且还表现出明显的四电子氧化还原特性。放电电流为20 mA g-1，PFTP电极具有多级放电平台，与PTPA相比，放电容量提高了74.2 mA hg

DOI：

10.1039/c6ra03248f

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文献信息

Functional thin film

申请人：Takahashi Tamotsu

公开号：US20050240061A1

公开（公告）日：2005-10-27

The present invention provides organic electroluminescent elements selected from polyacene derivatives represented by general formula (I) below: [wherein, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , A 1 and A 2 , which are the same or different, each represents hydrogen atom, a hydrocarbon group, etc., and n denotes an integer of not less than 1]. The organic electroluminescent elements of the present invention can provide materials for organic electroluminescent elements and organic electroluminescent elements, which are excellent in stability, durability, luminance and luminance efficiency.

本发明提供了选择自下述一般式（I）所代表的聚芳烃衍生物的有机电致发光元件：[其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2，它们相同或不同，分别代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供用于有机电致发光元件和有机电致发光元件的材料，这些元件在稳定性、耐久性、亮度和发光效率方面都表现出优异的特性。
ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC THIN FILM, AND TRIAMINE COMPOUNDS

申请人：IDEMITSU KOSAN COMPANY LIMITED

公开号：EP0805143A1

公开（公告）日：1997-11-05

The present invention provides a triamine compound represented by general formula (I): an organic luminescence device which comprises an organic layer and a pair of electrodes disposed on both sides of the organic layer wherein the organic layer at least contains a layer of a light emitting zone and a layer of a hole transporting zone which comprises a hole injecting layer containing the triamine compound and a hole transporting layer, and an organic thin film comprising two layers which are a layer containing a compound represented by general formula (I) and having a thickness of 5 nm to 5 µm and a layer containing a compound represented by general formula (II): and having a thickness of 5 nm to 5 µm. According to the present invention, an organic electroluminescence device which has little possibility of dielectric breakdown after storage for a long time and shows a remarkably high efficiency of light emission, an organic electroluminescence device which shows a remarkable stability of light emission after continuous use for a long time and has a long life, and an organic thin film which shows excellent hole injecting and transporting properties can be provided.

本发明提供了通式(I)代表的三胺化合物：一种有机发光器件，它包括有机层和设置在有机层两侧的一对电极，其中有机层至少包含一层发光区和一层空穴传输区，空穴传输区包括含有三胺化合物的空穴注入层和空穴传输层；以及一种有机薄膜，它包括两层，一层是含有通式(I)代表的化合物且厚度为5纳米至5微米的薄膜，另一层是含有通式(II)代表的化合物且厚度为5纳米至5微米的薄膜：且厚度为 5 纳米至 5 微米。根据本发明，可以提供一种有机电致发光器件，该器件在长期储存后发生介电击穿的可能性很小，并显示出极高的光发射效率；一种有机电致发光器件，该器件在长期连续使用后显示出极高的光发射稳定性，并具有较长的使用寿命；以及一种有机薄膜，该薄膜显示出优异的空穴注入和传输特性。
HYDROCARBON COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT

申请人：Mitsui Chemicals, Inc.

公开号：EP1221434A1

公开（公告）日：2002-07-10

An electroluminescent element in which at least one layer containing at least one of novel hydrocarbon compounds with an anthracene ring and a fluorene ring directly bound is held between a pair of electrodes. The compounds can advantageously be used in a luminescent element and provide an organic electroluminescent element having an excellent luminescent efficiency and a long luminescent life.

一种电致发光元件，其中至少有一层含有直接结合了蒽环和芴环的新型碳氢化合物。这些化合物可以很好地应用于发光元件中，并提供一种发光效率高、发光寿命长的有机电致发光元件。
Organic electroluminescent device

申请人：Kabushiki Kaisha Toyota Jidoshokki

公开号：EP1414081A2

公开（公告）日：2004-04-28

An organic electroluminescent device of the present invention includes a substrate (11), an anode (12), an organic layer (13) having a light emitting layer (17), and a cathode (14) capable of transmitting light. The cathode has an electron injection layer (18) of calcium and a protective layer (19) of silver. The protective layer covers the surface of the electron injection layer.

本发明的一种有机电致发光装置包括基板（11）、阳极（12）、具有发光层（17）的有机层（13）和能够透光的阴极（14）。阴极有一个钙电子注入层（18）和一个银保护层（19）。保护层覆盖在电子注入层的表面。
FUNCTIONAL THIN FILM

申请人：Japan Science and Technology Agency

公开号：EP1493796A1

公开（公告）日：2005-01-05

The present invention provides organic electroluminescent elements selected from polyacene derivatives represented by general formula (I) below: [wherein, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, A1 and A2, which are the same or different, each represents hydrogen atom, a hydrocarbon group, etc., and n denotes an integer of not less than 1]. The organic electroluminescent elements of the present invention can provide materials for organic electroluminescent elements and organic electroluminescent elements, which are excellent in stability, durability, luminance and luminance efficiency.

本发明提供的有机电致发光元件选自以下通式 (I) 所代表的聚乙炔衍生物： [其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2相同或不同，各自代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供稳定性、耐久性、亮度和发光效率都非常优异的有机电致发光元件材料和有机电致发光元件。