Bis-(4-isopropyl-benzoyl)-peroxid | 32019-45-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis-(4-isopropyl-benzoyl)-peroxid
• 英文别名: Bis-(p-isopropyl)-benzoylperoxid；bis-(4-isopropyl-benzoyl)-peroxide；Dicuminoylperoxyd；Dicumoyl peroxide；(4-propan-2-ylbenzoyl) 4-propan-2-ylbenzenecarboperoxoate
• CAS: 32019-45-7
• 化学式: C₂₀H₂₂O₄
• 分子量: 326.392
• InChiKey: ZHKNTUZVTZWLEQ-UHFFFAOYSA-N

物化性质

• 沸点：
  430.1±48.0 °C(Predicted)
• 密度：
  1.113±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Bis-(4-isopropyl-benzoyl)-peroxid 在 苯 作用下， 生成 4-异丙基联苯
  参考文献：
  名称：

  Nitrate reductase activation state in leaves of molybdenum-deficient winter wheat

  摘要：

  Nitrate reductase (NR, EC 1.6.6.1) activity, NR activation state, and in vivo nitrate reduction were measured in leaves of winter wheat (Triticum aestivum L. cv. Sadovo 1) in order to study the effect of molybdenum (Mo) deficiency on light-induced changes in NR activation. It was established that dark to light transition of the plants resulted in a fast increase in actual and maximum NR activities (NRA(act) and NRA(max)) and vice versa; the deactivation of NR occurred soon after light to dark transition. The diurnal rhythm of NRA(act) and NRA(max) was similar in phase in Mo-deficient and Mo-supplied plants. However, the absolute values of NRA(act) and NRA(max) were about two to three times higher in Mo-supplied compared to Mo-deficient plants, i.e. only the amplitude of the rhythm was affected by Mo deficiency. The activation state of NR, given as percentage ratio of NRA(act) to NRA(max), was higher in Mo-deficient plants, reaching a maximum of 60-66% in the light, independent of the light intensity over 210 mu mol m(-2) s(-1). In both Mo-deficient and Mo-supplied plants, the level of NRA(act) - thought to reflect the in situ NR activity - exceeded by several times the rate of in vivo nitrate reduction.The results indicate that Mo deficiency itself does not alter the timing of light/dark changes in NR activity, but it reduces significantly the levels of NRA(max) and NRA(act) and results in a higher NR activation state in Mo-deficient plants. A possible mechanism of this effect is discussed.

  DOI：

  10.1016/s0176-1617(00)80104-2
• 作为产物：
  描述：

  4-异丙基苯甲酰氯 在 双氧水 、 sodium hydroxide 作用下， 以 乙醚 、 水 为溶剂， 反应 0.5h， 生成 Bis-(4-isopropyl-benzoyl)-peroxid
  参考文献：
  名称：

  水中8-氨基喹啉酰胺的过渡金属游离氧合

  摘要：

  在不存在过渡金属催化剂的情况下，在水中C5位的过氧化苯甲酰使8-氨基喹啉酰胺氧化，从而以中等至良好的收率提供了所需的产物，产率高达88％。机理研究表明，该反应将涉及一个自由基过程。

  DOI：

  10.1039/c8gc00191j

文献信息

• A convenient synthesis of arylbenzenes
  作者：D. H. Hey、Katherine S. Y. Liang、M. J. Perkins、G. H. Williams

  DOI：10.1039/j39670001153

  日期：——

  An improved procedure for the preparation of arylbenzenes from aroyl peroxides and benzene is described.

  描述了一种由芳基过氧化物和苯制备芳基苯的改进方法。
• External-oxidant-free amino-benzoyloxylation of unactivated alkenes of unsaturated ketoximes with <i>O</i>-benzoylhydroxylamines
  作者：Jiangfei Chen、Yan-Ping Zhu、Jin-Heng Li、Qiu-An Wang

  DOI：10.1039/d1cc01565f

  日期：——

  A new copper-catalyzed two-component amino-benzoyloxylation of unactivated alkenes of unsaturated ketoximes with O-benzoylhydroxylamines as the benzoyloxy sources is developed. Chemoselectivity of this method toward amino-benzoyloxylation or oxy-benzoyloxylation of alkenyl ketoximes relies on the position of the tethered olefins, and provides an external-oxidant-free alkene difunctionalization route

  开发了以O-苯甲酰基羟胺为苯甲酰氧基源的不饱和酮肟未活化烯烃的铜催化双组分氨基苯甲酰氧基化反应。该方法对链烯酮酮肟的氨基苯甲酰氧基化或氧基苯甲酰氧基化的化学选择性依赖于拴系烯烃的位置，并提供了无外部氧化剂的烯烃双官能化路线，该路线直接利用O-苯甲酰羟胺作为苯甲酰氧基自由基前体和内部氧化剂环状硝酮和异恶唑啉的发散合成。
• Brodie, Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1863, p. 317
  作者：Brodie

  DOI：——

  日期：——
• 687. The effect of structure of diacyl peroxides on the rates of initiation of the polymerisation of styrene
  作者：W. Cooper

  DOI：10.1039/jr9510003106

  日期：——