2-[2,2']bithiophen-5-yl-quinoline | 34243-32-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 2-[2,2']bithiophen-5-yl-quinoline
• 英文别名: 2-[2,2']bithienyl-5-yl-quinoline；2-[2,2']Bithienyl-5-yl-chinolin；5-(2-Chinolyl)-2,2'-dithiophen；5-(2-Quinolyl)-2,2'-Bithionyl；2-(2,2'-Bithienyl-5-yl)quinoline；2-(5-thiophen-2-ylthiophen-2-yl)quinoline
• CAS: 34243-32-8
• 化学式: C₁₇H₁₁NS₂
• 分子量: 293.413
• InChiKey: GDQWVDZPWMRJKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-[2,2']bithiophen-5-yl-quinoline 在 copper(II) nitrate 作用下， 以 溶剂黄146 为溶剂， 生成 5-(2-Chinolyl)-3'-nitro-2,2'-dithienyl
  参考文献：
  名称：

  Nitration of 2-(2-quinolyl)thiophene and 5-(2-quinolyl)-2,2?-dithiophene

  摘要：

  DOI：

  10.1007/bf00470152
• 作为产物：
  描述：

  2-[2,2']bithiophenyl-5-yl-quinoline-4-carboxylic acid 在 soda lime 作用下， 生成 2-[2,2']bithiophen-5-yl-quinoline
  参考文献：
  名称：

  Steinkopf; v. Petersdorff, Justus Liebigs Annalen der Chemie, 1940, vol. 543, p. 119,126

  摘要：

  DOI：

文献信息

• Organometallic complexes as phosphorescent emitters in organic LEDs
  申请人：The Trustees of Princeton University

  公开号：US10629827B2

  公开（公告）日：2020-04-21

  Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

  描述了有机发光器件，其中发射层包括含有发射分子的主材料，当在异质结构上施加电压时，发射分子发光，发射分子选自磷光有机金属络合物组，包括环金属化铂、铱和锇络合物。有机发光器件可选择包含激子阻挡层。此外，使用包含式 L2MX 的过渡金属有机金属络合物的发射层可提高有机发光器件的电致发光效率，其中 L 和 X 是不同的双齿配位体。与以前的方法相比，这种式子的化合物更容易合成，而且合成方法允许在磷光配合物中插入荧光分子、配体来微调发射颜色，以及配体来捕获载流子。
• Kauffmann,T. et al., Angewandte Chemie, 1971, vol. 83, # 20, p. 799 - 800
  作者：Kauffmann,T. et al.

  DOI：——

  日期：——
• ORGANOMETALLIC COMPLEXES AS PHOSPHORESCENT EMITTERS IN ORGANIC LEDS
  申请人：The Trustees of Princeton University

  公开号：US20170301869A9

  公开（公告）日：2017-10-19

  Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L 2 MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.
• Steinkopf; v. Petersdorff, Justus Liebigs Annalen der Chemie, 1940, vol. 543, p. 119,126
  作者：Steinkopf、v. Petersdorff

  DOI：——

  日期：——
• Nitration of 2-(2-quinolyl)thiophene and 5-(2-quinolyl)-2,2?-dithiophene
  作者：M. N. Zemtsova、A. E. Lipkin、A. V. Zimichev

  DOI：10.1007/bf00470152

  日期：1974.10