[[Fe^II(4,4'-dimethyl-2,2'-bipyridine)₃]²⁺(PF6^-)_2] | 85185-57-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [[Fe^II(4,4'-dimethyl-2,2'-bipyridine)₃]²⁺(PF6^-)_2]
• 英文别名: [[Fe^II(Me₂bpy)₃]²⁺(PF6^-)_2]；[Fe^II(4,4′-dimethyl-2,2′-bipyridine)₃](PF₆)₂；[Fe^II(mbpy)₃](PF₆)₂；[Fe(dmb)₃](PF₆)₂；[Fe(4,4'-dimethyl-2,2'-bipyridine)₃](PF₆)₂；tris(4,4'-dimethyl-2,2'bipyridine)iron(II) hexafluorophosphate；[Fe(4,4'-dimethyl-2,2'-bipyridine)3](hexafluorophosphate)2；{Fe(Me2bpy)3}(PF6)2
• CAS: 85185-57-5
• 化学式: C₃₆H₃₆FeN₆*2F₆P
• 分子量: 898.497
• InChiKey: OITBNWDPACXNMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [[Fe^II(4,4'-dimethyl-2,2'-bipyridine)₃]²⁺(PF6^-)_2] 在 三氟甲磺酸 、 氧气 、 10-甲基-9-均三甲苯基吖啶高氯酸盐 作用下， 以 乙腈 为溶剂， 反应 0.17h， 生成 [tris(4,4'-dimethyl-2,2'-bipyridine)iron(III)]
  参考文献：
  名称：

  9-间甲氧基-10-甲基rid离子对双氧催化光催化氧化铁（II）配合物的作用

  摘要：

  在有机溶剂中，使用有机光催化剂，9-间甲氧基-10-甲基ac离子（Acr + -Mes）和2-苯基-4-（1-萘基）喹啉离子（QuPh + -NA）进行双氧氧化铁（II）配合物。可见光下乙腈中存在三氟甲磺酸

  DOI：

  10.1039/c6cc00359a
• 作为产物：
  描述：

  ammonium iron(II) sulfate hexahydrate 、 4,4'-二甲基-2,2'-联吡啶 、 ammonium hexafluorophosphate 以 水 为溶剂， 反应 0.25h， 以87%的产率得到[[Fe^II(4,4'-dimethyl-2,2'-bipyridine)₃]²⁺(PF6^-)_2]
  参考文献：
  名称：

  Electrochemical characterization of polypyridine iron(II) and cobalt(II) complexes for organic redox flow batteries

  摘要：

  The electrochemical properties of a series of complexes based on chelate ligands were explored with the aim of finding promising candidates for applications in high voltage organic flow cells. The combination of Co(II)/(I) and Fe(III)/(II) as the cathodic and the anodic couple leads to open circuit voltages close to 2 V and to limiting current of the order of 30 mA/cm(2) in 0.3 M concentration in a mixture of Ethylene and Propylene carbonates. The best solubility was found for bis-cationic complexes as triflate (OTf) salts, reaching >0.6 M at room temperature. Potentiostatic and potentiodynamic experiments point to a substantial chemical and electrochemical stability at carbon based electrodes as well. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2017.12.001

文献信息

• Octahedral Fe(II) and Ru(II) Complexes Based on a New Bis 1,10-Phenanthroline Ligand That Imposes a Well Defined Axis
  作者：Didier Pomeranc、Valérie Heitz、Jean-Claude Chambron、Jean-Pierre Sauvage

  DOI：10.1021/ja011250y

  日期：2001.12.1

  of L1 with [Fe(dmbp)(3)](PF(6))(2) (dmbp = 4,4'-dimethyl-2,2'-bipyridine). On the other hand, its Ru(II) complex, [RuL1(dmbp)](PF(6))(2), was prepared in two steps from Ru(CH(3)CN)(4)Cl(2) and L1, followed by reaction with dmbp. X-ray crystal structure analyses show that in the two octahedral complexes, ligand L1 coils around the metal by coordination of the axial and two equatorial positions. It defines

  双螯合配体 (L1)，由与 p-(CH(2))(2)C(6)H(4) 连接的两个 7-(p-茴香基)-1,10-菲咯啉 (phen) 亚基组成)(CH(2))(2) 间隔物通过它们的 4 个位置，已经使用 Skraup 合成和 4-methyl-7-anisyl-1,10-phenanthroline 的阴离子与 alpha,alpha'-dibromo-对二甲苯。其 Fe(II) 配合物 [FeL1(dmbp)](PF(6))(2) 是通过 L1 与 [Fe(dmbp)(3)](PF(6))(2) 反应一步制备的) (dmbp = 4,4'-二甲基-2,2'-联吡啶)。另一方面，其 Ru(II) 络合物 [RuL1(dmbp)](PF(6))(2) 是由 Ru(CH(3)CN)(4)Cl(2) 和L1，然后与dmbp反应。X 射线晶体结构分析表明，在两个八面体配合物中，配体 L1 通过轴
• Effect of dendrimer generation on electron self-exchange kinetics between metal tris(bipyridine) core dendrimers
  作者：Young-Rae Hong、Christopher B. Gorman

  DOI：10.1039/b704585a

  日期：——

  Here we report the first measurement of homogeneous electron transfer between oxidized and reduced metal tris(bipyridine) core dendrimers by NMR line-broadening; the results indicated that, as the generation of the dendrimer increased, the rate of self-exchange decreased.

  我们在此报告了通过核磁共振线宽测量氧化和还原金属三（联吡啶）核心树枝状分子之间的均相电子转移的首次测量结果；结果表明，随着树枝状分子生成的增加，自交换速率降低。
• Determination of Labile Chiral Supramolecular Ion Pairs by Chromatographic NMR Spectroscopy
  作者：Manjunatha Reddy G. N.、Rafael Ballesteros-Garrido、Jérôme Lacour、Stefano Caldarelli

  DOI：10.1002/anie.201209616

  日期：2013.3.11

  Chiral recognition: Silica‐enhanced NMR diffusometry can distinguish the signals of diastereoisomeric mixtures of supramolecular ion pairs (see picture; DOSY=diffusion‐ordered spectroscopy). The experiment has a shorter timescale than liquid chromatography, thus allowing an easier characterization of species that are even configurationally labile on the minutes timescale.

  手性识别：硅胶增强的NMR散射法可以区分超分子离子对的非对映异构体混合物的信号（参见图片； DOSY =扩散有序光谱学）。该实验比液相色谱法具有更短的时间尺度，因此可以更容易地表征在几分钟的时间尺度上甚至形状不稳定的物质。
• Serr, Barbara R.; Andersen, Kevin A.; Elliott, C. Michael, Inorganic Chemistry, 1988, vol. 27, # 24, p. 4499 - 4504
  作者：Serr, Barbara R.、Andersen, Kevin A.、Elliott, C. Michael、Anderson, Oren P.

  DOI：——

  日期：——
• Ion-Pair-Mediated Asymmetric Synthesis of a Configurationally Stable Mononuclear Tris(diimine)-Iron(II) Complex
  作者：David Monchaud、Jonathan J. Jodry、Didier Pomeranc、Valérie Heitz、Jean-Claude Chambron、Jean-Pierre Sauvage、Jérôme Lacour

  DOI：10.1002/1521-3773(20020703)41:13<2317::aid-anie2317>3.0.co;2-w

  日期：2002.7.3