anthracene-1,5-diol | 607-62-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: anthracene-1,5-diol
• 英文别名: Anthracen-1,5-diol；1.5-Dioxy-anthracen；Rufol
• CAS: 607-62-5
• 化学式: C₁₄H₁₀O₂
• 分子量: 210.232
• InChiKey: AGTBKJDELLDEOQ-UHFFFAOYSA-N

物化性质

• 沸点：
  475.0±18.0 °C(Predicted)
• 密度：
  1.360±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  anthracene-1,5-diol 在 chromium(VI) oxide 、 sodium acetate 、 溶剂黄146 作用下， 生成 蒽绛酚
  参考文献：
  名称：

  Liebermann; Boeck, Chemische Berichte, 1878, vol. 11, p. 1616

  摘要：

  DOI：
• 作为产物：
  描述：

  蒽-1,5-二磺酸 在 potassium carbonate 作用下， 生成 anthracene-1,5-diol
  参考文献：
  名称：

  Lampe, Chemische Berichte, 1909, vol. 42, p. 1416

  摘要：

  DOI：

文献信息

• COMPOSITION FOR FORMING OPTICAL COMPONENT, OPTICAL COMPONENT, COMPOUND, AND RESIN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20210309595A1

  公开（公告）日：2021-10-07

  Provided is a composition containing a polyphenol compound (B) and a solvent, in which the polyphenol compound (B) is at least one selected from a compound represented by the following formula (1) and a resin having a structure represented by the following formula (2): wherein R Y , R T , X, m, N, r, and L are as described in the description.

  提供的是含有多酚化合物(B)和溶剂的组合物，其中多酚化合物(B)至少选自以下式子(1)所表示的化合物和以下式子(2)所表示的具有结构的树脂之一：其中RY、RT、X、m、N、r和L如说明书中所述。
• Enhanced molecular binding affinity toward aromatic dications by anthracene-derived crown ethers in water
  作者：Jia-Liang Zhou、Yan-Hong Li、Ying-Ming Zhang、Ling Chen、Yu Liu

  DOI：10.1039/d2ob02010f

  日期：——

  the ring of anthracene-derived crown ether via multiple π-stacking and electrostatic interactions. Meanwhile, the obtained association constants are remarkably higher than the ones in the cases of the known benzene- and naphthalene-derived sulfonated crown ethers, substantiating that the appropriate extension of π-conjugation in the molecular skeleton of crown ether is a feasible method in attaining

  在水中使用传统的冠醚追求高分子结合亲和力仍然是超分子化学领域的一项具有挑战性的任务，并且可能在创建先进的生物相容性纳米结构方面具有广阔的前景。在这项工作中，四磺化 1,5-dianthracenyl-42-crown-10 大大增强了与一系列结构相关的阳离子客体的分子结合强度，并通过1 H NMR、UV-vis 和荧光光谱进行了研究, 主客体结合常数在水溶液中可达 10 8 M -1个数量级。X射线晶体衍射分析进一步表明芳香族双阳离子可以紧密包裹在蒽衍生冠醚的环中通过多个 π 堆叠和静电相互作用。同时，得到的缔合常数明显高于已知苯和萘衍生的磺化冠醚的缔合常数，证明在冠醚分子骨架中适当扩展π-共轭是实现该化合物的可行方法。高度亲和的主客情结。综上所述，我们的结果表明，基于蒽的磺化冠醚可以在功能性纳米结构的制造中发展成为一类新的水溶性大环受体。
• Production of 11,11,12,12-Tetracyano-9,10-anthraquinodimethane and derivatives thereof
  申请人：MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

  公开号：EP0076639A1

  公开（公告）日：1983-04-13

  11,11,12,12-Tetracyano-9,10-anthraquinodimethane compounds useful as semiconductors and which have the general formula (I) in which Z1, Z4, Z5 and Za independently represent hydrogen, chlorine, hydroxy or amino and Z2, Z3, Z6 and Z7 independently represent hydrogen, halogen, alkyl which has 1 to 8 carbon atoms, phenyl, alkylphenyl whose alkyl group has 1 or 2 carbon atoms, hydroxyalkyl which has 1 to 8 carbon atoms, carboxyalkyl whose alkyl group has 1 to 8 carbon atoms, hydroxy, amino, or carboxyl, are prepared by introducing dicyanomethyl groups into an anthracene compound of the general formula (II) at the 9- and 10-positions in which Z1 to Z8 have the same meaning as above, and dehydrogenating the dicyanomethyl groups.

  11,11,12,12-四氰基-9,10-蒽醌二甲烷化合物可用作半导体，其通式为 (I) 其中 Z1、Z4、Z5 和 Za 分别代表氢、氯、羟基或氨基，Z2、Z3、Z6 和 Z7 分别代表氢、卤素、具有 1 至 8 个碳原子的烷基、苯基、烷基具有 1 或 2 个碳原子的烷基苯基、具有 1 至 8 个碳原子的羟基烷基、烷基具有 1 至 8 个碳原子的羧基烷基、羟基、氨基或羧基，通过在通式（II）的蒽化合物的 9 位和 10 位引入二氰基甲基来制备。 其中 Z1 至 Z8 的含义与上述相同，然后将二氰基甲基脱氢。
• Poly (ether amide) compositions from reaction of bis-bicyclic amide acetals with bis- and poly-phenolic materials
  申请人：Ashland Oil, Inc.

  公开号：EP0260338A1

  公开（公告）日：1988-03-23

  Novel polymers containing ether-amide groups which can be obtained by reaction of a bis- or poly-bicyclic amide acetal with a bis-phenolic or poly-phenolic material at a temperature of from about 80°C to 200°C are described.

  本文描述了含有醚酰胺基团的新型聚合物，这种聚合物可通过双环或多双环酰胺缩醛与双酚或多酚材料在约 80°C 至 200°C 的温度下进行反应而获得。
• Method of preventing polymer-scale formation
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0320227A2

  公开（公告）日：1989-06-14

  A method of preventing polymer scales from sticking in a polymerization vessel during the polymerization of a monomer having an ethylenically double bond, wherein said polymerization is carried out in a polymerization vessel of which the inner wall and other parts with which said monomer comes into contact during polymerization are previously first coated with (a) a coating solution comprising a cationic dye and the resulting coating is then coated with (b) a coating solution comprising at least one component selected from the group consisting of anionic polymeric compounds, amphoteric polymeric compounds and hydroxyl group-containing organic compounds. Polymer scale formation can be effectively prevented.

  一种在具有乙烯双键的单体聚合过程中防止聚合物鳞片粘附在聚合容器中的方法，其中所述聚合在聚合容器中进行，聚合容器的内壁和在聚合过程中与所述单体接触的其他部分之前先涂有(a)由阳离子染料组成的涂层溶液，然后在所得涂层上涂有(b)由至少一种从阴离子聚合物化合物、两性聚合物化合物和含羟基有机化合物组成的组中选出的组分组成的涂层溶液。可有效防止聚合物结垢。