O,O,S-Triphenyl-phosphordithioat | 67821-09-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: O,O,S-Triphenyl-phosphordithioat
• 英文别名: Diphenoxy-phenylsulfanyl-sulfanylidene-lambda5-phosphane；diphenoxy-phenylsulfanyl-sulfanylidene-λ5-phosphane
• CAS: 67821-09-4
• 化学式: C₁₈H₁₅O₂PS₂
• 分子量: 358.422
• InChiKey: BTTADQHBYSGIDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  O,O-diphenyl phosphorodithioic acid 以 四氢呋喃 、 1,4-二氧六环 为溶剂， 反应 18.0h， 生成 O,O,S-Triphenyl-phosphordithioat
  参考文献：
  名称：

  硫代磷酸二酯及相关化合物与二芳基碘盐的无金属 S-芳基化

  摘要：

  我们使用二芳基碘盐开发了硫代磷酸二酯的直接无金属S-芳基化。该方法允许在简单条件下制备范围广泛的S-芳基硫代磷酸酯，包括复杂分子（例如，二核苷酸或 TADDOL 衍生物），以及在硫属元素芳基化的其他相关有机磷化合物。反应在磷原子处完全保留立体异构中心的情况下进行，从而方便地获得 P-手性产物。使用DFT计算建立了反应机理。

  DOI：

  10.1021/acs.orglett.2c04310

文献信息

• Catalyst and process for the polymerization of alpha-olefins and a process for preparing an alpha-olefin polymerization catalyst component
  申请人：Standard Oil Company

  公开号：EP0013744A1

  公开（公告）日：1980-08-06

  High activity alpha-olefin polymerization catalysts comprising an organometallic promoter and a component prepared from at least one compound of a Group IVB, VB, or VIB metal, at least one support material which is a divalent metal salt of a phosphorus acid ester having at least one phosphorus acid ester group bonded to metal through oxygen or sulfur, and at least one alkylaluminium halide.

  高活性α-烯烃聚合催化剂，包括有机金属促进剂和由至少一种 IVB、VB 或 VIB 族金属化合物制备的组分，至少一种支撑材料，该支撑材料是磷酸酯的二价金属盐，其中至少有一个磷酸酯基团通过氧或硫与金属键合，以及至少一种烷基卤化铝。
• LUBRICANT COMPOSITION AND DRIVING FORCE TRANSMITTING SYSTEM USING SAME
  申请人：Nippon Oil Corporation

  公开号：EP1816183A1

  公开（公告）日：2007-08-08

  The invention provides a lubricating oil composition comprising a lubricating base oil, a phosphorus compound and at least one organic acid salt selected from among alkaline earth metal sulfonates, alkaline earth metal phenates and alkaline earth metal salicylates, wherein the contents of the phosphorus compound and organic acid salt satisfy the conditions represented by the following formulas (1) to (3). In formulas (1)-(3), W(P) represents the content of phosphorus compound, in terms of phosphorus element, based on the total amount of the lubricating oil composition, and W(M) represents the content of organic acid salt content, in terms of alkaline earth metal elements, based on the total amount of the lubricating oil composition.

  本发明提供了一种润滑油组合物，该组合物由润滑基础油、磷化合物和至少一种选自碱土金属磺酸盐、碱土金属苯酸盐和碱土金属水杨酸盐的有机酸盐组成，其中磷化合物和有机酸盐的含量满足以下公式(1)至(3)所代表的条件。在公式(1)至(3)中，W(P)表示磷化合物的含量（以磷元素计），以润滑油组合物的总量为基础；W(M)表示有机酸盐的含量（以碱土金属元素计），以润滑油组合物的总量为基础。
• Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
  申请人：TAYCA CORPORATION

  公开号：US10208160B2

  公开（公告）日：2019-02-19

  There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.

  本发明提供了一种用于生产导电聚合物的氧化剂掺杂剂及其溶液，它们能够生产导电聚合物，适用于生产泄漏电流较低的电解质电容器。此外，还提供了使用其中任一种制备的导电聚合物。还提供了一种具有低泄漏电流的电解质电容器。氧化剂掺杂剂包括：有机铁磺酸盐；以及至少一种选自磷酸、磷酸盐、磷酸、亚磷酸盐、硼酸、硼酸盐、硫代磷酸、硫代磷酸、二硫代磷酸和二硫代磷酸组成的组。溶液包括溶解在水、醇或水与醇混合物中的氧化剂掺杂剂。导电聚合物是通过单体（如噻吩或其衍生物）的氧化聚合而制备的。导电聚合物用作电解质，以提供电解质电容器。
• Method for preparing an electrolyte capacitor
  申请人：TAYCA CORPORATION

  公开号：US10336859B2

  公开（公告）日：2019-07-02

  The method for preparing an electrolyte capacitor includes: providing an oxidant dopant agent for preparing the conductive polymer including: ferric naphthalenesulfonate; and at least one compound selected from the group consisting of phosphate, phosphite, borate, thiophosphate, and dithiophosphate. The method also includes preparing a conductive polymer by using the oxidant dopant agent to obtain an electrolyte comprising the conductive polymer.

  制备电解质电容器的方法包括：提供用于制备导电聚合物的氧化剂掺杂剂，包括：萘磺酸铁；以及至少一种选自磷酸盐、亚磷酸盐、硼酸盐、硫代磷酸盐和二硫代磷酸盐的化合物。该方法还包括使用氧化剂掺杂剂制备导电聚合物，以获得包含导电聚合物的电解液。
• Lubricating oil composition
  申请人：Nippon Oil Corporation

  公开号：US20040192562A1

  公开（公告）日：2004-09-30

  A lubricating oil composition which comprises (A) a base oil, (B) calcium salicylate having a base number of 50 to 300 mgKOH/g in an amount of 0.005 to 0.07 percent by mass in terms of calcium, (C) an SP type extreme pressure additive in an amount of 0.005 to 0.07 percent by mass in terms of phosphorous, (D) a specific succinimide compound in an amount of 0.1 to 6 percent by mass, and (E) a boron-containing ashless dispersant in an amount of 0.001 to 0.05 percent by mass in terms of boron, based on the total mass of the composition. The lubricating oil composition can prevent pitching of a transmission, resulting in the extended fatigue life thereof, and exhibits excellent and long-lasting anti-shudder properties.

  一种润滑油组合物，包括：(A)基础油；(B)水杨酸钙，其碱基数为 50 至 300 mgKOH/g，钙的用量为 0.005 至 0.07%（以质量计）；(C)SP 型极压添加剂，其用量为 0.005 至 0.(D) 特定琥珀酰亚胺化合物，质量百分比为 0.1% 至 6%；以及 (E) 含硼无灰分散剂，以组合物总质量为基准，硼的质量百分比为 0.001% 至 0.05%。该润滑油组合物可以防止变速器的跳动，从而延长其疲劳寿命，并表现出卓越而持久的防抖特性。