4,4'''-difluoro-p-quaterphenyl | 2804-78-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'''-difluoro-p-quaterphenyl
• 英文别名: p,p'-Difluor-p-quaterphenyl；4,4'''-Difloroquaterphenyl；1-Fluoro-4-[4-[4-(4-fluorophenyl)phenyl]phenyl]benzene
• CAS: 2804-78-6
• 化学式: C₂₄H₁₆F₂
• 分子量: 342.388
• InChiKey: SRGASWQUOJYCJD-UHFFFAOYSA-N

物化性质

• 熔点：
  306 °C
• 沸点：
  512.6±35.0 °C(Predicted)
• 密度：
  1.165±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-fluoro-4'-iodo-1,1'-biphenyl 在 间溴硝基苯 作用下， 生成 4,4'''-difluoro-p-quaterphenyl
  参考文献：
  名称：

  Substituent Effects. VI.^1,2 Fluorine Nuclear Magnetic Resonance Spectra of 3'- and 4'-Substituted 4-Fluorobiphenyls and 3″-Substituted 4-Fluoroterphenyls

  摘要：

  DOI：

  10.1021/ja00966a026

文献信息

• Fluorine as a label for detecting reaction mechanism
  作者：P. Miles、H. Suschitzky

  DOI：10.1016/s0040-4020(01)99185-9

  日期：1963.1

  By means of nucleophilically activated fluorine transient ion pair formation is demonstrated during thermal decomposition of the following aryl radical generators in a non-polar solvent: p-fluorophenylazotriphenylmethane, p-fluorophenyldiazopiperidide, p-fluorophenyldiazoaminobenzene, and p-fluorophenylhydrazine. Negative results were obtained with p-fluorobenzoyl peroxide.

  在非极性溶剂中以下芳基自由基生成剂的热分解过程中，通过亲核活化的氟瞬态离子对的形成得到了证明：对氟苯基偶氮三苯基甲烷，对氟苯基重氮哌啶子，对氟苯基重氮氨基苯和对氟苯基肼。用对氟苯甲酰过氧化物获得阴性结果。
• Crystal Structures of the Room-Temperature Phase of 4,4″-Difluoro-<i>p</i>-terphenyl and 4,4″′-Difluoro-<i>p</i>-quaterphenyl
  作者：Hideki Saitoh、Kazuya Saito、Yasuhisa Yamamura、Haruo Matsuyama、Koichi Kikuchi、Masahiko Iyoda、Isao Ikemoto

  DOI：10.1246/bcsj.66.2847

  日期：1993.10

  4,4″-Difluoro-p-terphenyl and 4,4″′-difluoro-p-quaterphenyl were synthesized and their crystal structures were determined at room temperature. These are isostructural to p-terphenyl and p-quaterphenyl, respectively. Some “disorder” in the inner benzene ring orientation was detected and resolved by the split-atom method. A rigid-body librational analysis of each benzene ring around the long molecular

  合成了4,4"-二氟-对三联苯和4,4"'-二氟-对-四联苯，并在室温下测定了它们的晶体结构。它们分别与对三联苯和对四联苯同构。内部苯环取向的一些“紊乱”通过分裂原子方法被检测和解决。对围绕长分子轴的每个苯环进行了刚体振动分析。4,4"-二氟-对三联苯的平面构象势垒高度的粗略估计约为1 kJ mol-1。将结果与对三联苯和对四联苯的性质进行比较，并讨论了与低温相变相关的氟取代对分子性质的影响。
• ORGANIC THIN FILM TRANSISTOR DEVICE AND ORGANIC THIN FILM LIGHT-EMITTING TRANSISTOR
  申请人：Nakano Yuki

  公开号：US20100012929A1

  公开（公告）日：2010-01-21

  An organic thin film transistor including a substrate having thereon at least three terminals of a gate electrode, a source electrode and a drain electrode, an insulator layer and an organic semiconductor layer, with a current between a source and a drain being controlled upon application of a voltage to the gate electrode, wherein the organic semiconductor layer includes a compound having a specified structure; and an organic thin film light emitting transistor utilizing an organic thin film transistor, wherein the organic thin film transistor is one in which light emission is obtained utilizing a current flowing between the source and the drain, and the light emission is controlled upon application of a voltage to the gate electrode, and is made high with respect to the response speed (driving speed) and has a large ON/OFF ratio, are provided.
• US8217389B2
  申请人：——

  公开号：US8217389B2

  公开（公告）日：2012-07-10