1-tert-butyl-2-(methylthio)benzene | 33775-93-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-tert-butyl-2-(methylthio)benzene
• 英文别名: 2-tert-butylphenyl methyl sulfide；2-tert-butyl(methylthio)benzene；Methyl-<2-tert.-butyl-phenyl>-sulfid；Methyl-o-tert.-butylphenylsulfid；o-t-Butylthioanisol；Benzene, 1-(1,1-dimethylethyl)-2-(methylthio)-；1-tert-butyl-2-methylsulfanylbenzene
• CAS: 33775-93-8
• 化学式: C₁₁H₁₆S
• 分子量: 180.314
• InChiKey: RGTJSTWNDRUGGB-UHFFFAOYSA-N

物化性质

• 沸点：
  118-120 °C(Press: 7 Torr)
• 密度：
  0.96±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-tert-butyl-2-(methylthio)benzene 在 双氧水 作用下， 以 溶剂黄146 为溶剂， 生成 methyl o-t-butylphenyl sulphone
  参考文献：
  名称：

  Lamm,B.; Ankner,K., Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1977, vol. 31, p. 375 - 381

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(叔丁基)-2-溴-4-硝基苯 生成 1-tert-butyl-2-(methylthio)benzene
  参考文献：
  名称：

  Lamm,B.; Ankner,K., Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1977, vol. 31, p. 375 - 381

  摘要：

  DOI：

文献信息

• Organocatalytic Asymmetric Synthesis of Sulfoxides from Sulfenic Acid Anions Mediated by a <i>Cinchona</i>-Derived Phase-Transfer Reagent
  作者：Fabien Gelat、Jayadevan Jayashankaran、Jean-François Lohier、Annie-Claude Gaumont、Stéphane Perrio

  DOI：10.1021/ol2010962

  日期：2011.6.17

  Preliminary results concerning a conceptually novel route to chiral sulfoxides based on the asymmetric alkylation of sulfenate salts with alkyl halides mediated by a chiral phase-transfer catalyst are described. As a representative example, o-anisyl methyl sulfoxide was produced in 96% yield and with an enantiomeric excess of 58% using commercial cinchonidinium derivative 2a.

  本文描述了有关手性亚砜在手性相转移催化剂介导的亚磺酸盐与烷基卤化物的不对称烷基化的基础上获得手性亚砜的新颖方法的初步结果。作为代表性的例子，ö -anisyl甲基亚砜，96％收率和58％对映体过量使用商业金鸡尼丁衍生物制备2A。
• PYRIDONE COMPOUNDS AND AGRICULTURAL AND HORTICULTURAL FUNGICIDES CONTAINING THE SAME AS ACTIVE INGREDIENTS
  申请人：MITSUI CHEMICALS AGRO, INC.

  公开号：US20200172486A1

  公开（公告）日：2020-06-04

  Provided are a pyridone compound represented by Formula (1): wherein R1 represents a C1-C6 alkyl group which may be substituted, etc., R2 represents a halogen atom, a cyano group, etc., R3 and R4 are independent to each other, and each represents a hydrogen atom, a C1-C6 alkyl group which may be substituted, etc., or in combination with the nitrogen atom to which they are bonded form a pyrrolidinyl group, a piperidinyl group, etc., which may be substituted, Y represents a phenyl group which may be substituted, etc., X represents an oxygen atom or a sulfur atom, and an agricultural and horticultural fungicide containing the same as an active ingredient.

  提供的是由化学式（1）表示的吡啶酮化合物： 其中 R1代表一个可能被取代的C1-C6烷基，等等， R2代表一个卤素原子，一个氰基，等等， R3和R4彼此独立，每个代表一个氢原子，一个可能被取代的C1-C6烷基，等等，或者与它们结合的氮原子形成一个可能被取代的吡咯啉基团，一个哌啶基团，等等， Y代表一个可能被取代的苯基，等等， X代表一个氧原子或硫原子， 以及含有该化合物作为活性成分的农业和园艺用杀菌剂。
• CURABLE COMPOSITION, CURED PRODUCT, COLOR FILTER, METHOD FOR PRODUCING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20200385582A1

  公开（公告）日：2020-12-10

  Provided are a curable composition including a compound represented by Formula 1 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm, or a polymer having a structure represented by Formula 2 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm; a polymerizable compound; and a chromatic colorant different from the compound represented by Formula 1 and the polymer represented by Formula 2, as well as a cured product of the curable composition; a color filter including the cured product; a method for producing a color filter; a solid-state imaging element; and an image display device.

  提供一种可治愈的组合物，包括由式1表示的化合物，其最大吸收波长在600纳米或更大且小于700纳米范围内，或者具有由式2表示的结构的聚合物，其最大吸收波长在600纳米或更大且小于700纳米范围内；一种可聚合的化合物；和一种与式1表示的化合物和式2表示的聚合物不同的色素染料，以及所述可治愈组合物的固化产物；包括所述固化产物的彩色滤光片；生产彩色滤光片的方法；固态成像元件；和图像显示装置。
• Pyrazolo[1,5-a]pyridine derivatives or pharmaceutically acceptable salts thereof
  申请人：Unoki Gen

  公开号：US20070072898A1

  公开（公告）日：2007-03-29

  A pyrazolo[1,5-a]pyridine derivative represented by formula (I) and salt thereof exhibit excellent MAPKAP-K2 inhibitory activity. Accordingly, medicines comprising this compound as an active ingredient are expected to be valuable for treating or preventing diseases mediated by MAPKAP-K2 such as inflammatory injury, autoimmune diseases, asteropathia destruens, cancer and/or growth of tumor.

  由式(I)表示的吡唑并[1,5-a]吡啶衍生物及其盐表现出优异的MAPKAP-K2抑制活性。因此，包含该化合物作为活性成分的药物预计对治疗或预防由MAPKAP-K2介导的疾病，如炎症损伤、自身免疫疾病、asteropathia destruens、癌症和/或肿瘤生长具有重要价值。
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20210050532A1

  公开（公告）日：2021-02-18

  Provided are compounds comprising a ligand L A of Formula I

  提供了包含配体LA的化合物，其化学式为I。