1,3-dibromo-5-dodecyl-5,6-dihydro-4H-thieno[3,4-c]pyrrole | 773881-50-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3-dibromo-5-dodecyl-5,6-dihydro-4H-thieno[3,4-c]pyrrole
• 英文别名: 1,3-Dibromo-5-dodecyl-4,6-dihydrothieno[3,4-c]pyrrole；1,3-dibromo-5-dodecyl-4,6-dihydrothieno[3,4-c]pyrrole
• CAS: 773881-50-8
• 化学式: C₁₈H₂₉Br₂NS
• 分子量: 451.309
• InChiKey: ZIWZKPJWSDOVMT-UHFFFAOYSA-N

物化性质

• 熔点：
  51-52 °C
• 沸点：
  443.7±45.0 °C(Predicted)
• 密度：
  1.350±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  22
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,4-噻吩二羧酸酐 在 N-溴代丁二酰亚胺(NBS) 、 氯化亚砜 、 硼烷四氢呋喃络合物 作用下， 以 四氢呋喃 、 硫酸 、 甲苯 、 三氟乙酸 为溶剂， 反应 66.0h， 生成 1,3-dibromo-5-dodecyl-5,6-dihydro-4H-thieno[3,4-c]pyrrole
  参考文献：
  名称：

  New Regiosymmetrical Dioxopyrrolo- and Dihydropyrrolo-Functionalized Polythiophenes

  摘要：

  We present the synthesis of two N-alkylated poly(dioxopyrrolothiophene)s and two N-alkylated poly(dlhydropyrrolothiophene)s with potential application in the field of conducting polymers. The polymers are synthesized from the corresponding 2,5-dibromothiophenes by an Ullmann-type polymerization and a Stille-type polymerization, respectively. The two N-alkylated poly(dihydropyrrolothiophene)s are the first examples of amino-functionalized polythiophenes built from regiosymmetrical thiophene monomers.

  DOI：

  10.1021/ol048659n

文献信息

• New Regiosymmetrical Dioxopyrrolo- and Dihydropyrrolo-Functionalized Polythiophenes
  作者：Christian B. Nielsen、Thomas Bjørnholm

  DOI：10.1021/ol048659n

  日期：2004.9.1

  We present the synthesis of two N-alkylated poly(dioxopyrrolothiophene)s and two N-alkylated poly(dlhydropyrrolothiophene)s with potential application in the field of conducting polymers. The polymers are synthesized from the corresponding 2,5-dibromothiophenes by an Ullmann-type polymerization and a Stille-type polymerization, respectively. The two N-alkylated poly(dihydropyrrolothiophene)s are the first examples of amino-functionalized polythiophenes built from regiosymmetrical thiophene monomers.