2-氯乙基己基硫化物 | 41256-15-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 2-氯乙基己基硫化物
• 英文名称: 2-Chloroethyl hexyl sulfide
• 英文别名: 1-(2-chloroethylsulfanyl)hexane
• CAS: 41256-15-9
• 化学式: C₈H₁₇ClS
• 分子量: 180.742
• InChiKey: PLRWRRRBQRCLAB-UHFFFAOYSA-N

物化性质

• 沸点：
  115-117 °C(Press: 8 Torr)
• 密度：
  0.9852 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  10
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-氯乙基己基硫化物 在 双氧水 、 sodium 、 溶剂黄146 作用下， 反应 10.0h， 生成 N-(β-hexylsulfonylethyl)succinimide
  参考文献：
  名称：

  Allakhverdiev; Kurbanov; Omarov, Journal of applied chemistry of the USSR, 1987, vol. 60, # 2 pt 2, p. 422 - 425

  摘要：

  DOI：

文献信息

• Method of preparation of (substituted-thio)alkyl isothiocyanates
  申请人：The Dow Chemical Company

  公开号：US04780557A1

  公开（公告）日：1988-10-25

  A one-step process for the preparation of (substituted-thio)alkyl isothiocyanates in high yield comprising contacting a haloalkyl sulfide with a thiocyanate salt in the absence of a catalyst under reaction conditions sufficient to produce the desired (substituted-thio)alkyl isothiocyanate is disclosed. Examples of compounds produced by this process include CH.sub.3 SCH.sub.2 CH.sub.2 NCS and n-C.sub.6 H.sub.13 SCH.sub.2 CH.sub.2 NCS. The compounds produced by this process are useful as intermediates in the synthesis or ore flotation chemicals such as substituted thiocarbamates or thioureas.

  本发明公开了一种高产率制备（取代硫）烷基异硫氰酸酯的单步方法，包括在无催化剂存在下，将卤代烷基硫醚与硫氰酸盐在反应条件下接触，以产生所需的（取代硫）烷基异硫氰酸酯。该过程产生的化合物包括CH.sub.3 SCH.sub.2 CH.sub.2 NCS和n-C.sub.6 H.sub.13 SCH.sub.2 CH.sub.2 NCS。该过程产生的化合物可用作合成或矿石浮选化学品（如取代硫代氨基甲酸酯或硫脲）的中间体。
• Radiographic elements with improved covering power
  申请人：Eastman Kodak Company

  公开号：US05292631A1

  公开（公告）日：1994-03-08

  Monocyclic and polycyclic azoles having the following formula enhance the covering power of a developed silver image formed from a radiographic element comprising a radiation sensitive tabular grain silver bromide, silver bromochloride or silver bromoiodide emulsion layer containing grains having a mean equivalent circular diameter of at least 0.3 .mu.m and a grain population wherein at least 50 percent of the total grain population projected area is accounted for by tabular grains having a tabularity of greater than 8, as determined by the relationship: ##EQU1## wherein T is tabularity; ECD is the mean effective circular diameter in .mu.m of the tabular grains; and t is the mean thickness in .mu.m of the tabular grains. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sup.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms; R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms; R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms; L is a divalent aliphatic linking group containing 1 to 8 carbon atoms; T is an aliphatic terminal group containing 1 to 10 carbon atoms; m is 0 or 1; n is an integer of 0 to 4; and p is an integer of 2 to 4.

  具有以下公式的单环和多环杂环化合物增强了由放射成像元素形成的发展银图像的覆盖力，该放射成像元素包括具有平均等效圆直径至少为0.3μm和至少50％的总晶粒面积由具有大于8的平板晶粒的平板状晶粒组成的辐射敏感的板状颗粒银溴化物，银溴氯化物或银溴碘化物乳液层。其中，平板度T由以下关系确定：T =（ECD / t）其中ECD是平板晶粒的平均有效圆直径（μm），t是平板晶粒的平均厚度（μm）。这些杂环化合物的公式为：其中Z为--N.dbd.或--C（R.sup.5）.dbd.，其中R.sup.5为氢，--NH2，1至8个碳原子的脂肪族或1至8个碳原子的芳香族；R.sup.4为氢，1至8个碳原子的脂肪族或1至8个碳原子的芳香族；R.sup.4和R.sup.5共同组成一个含有1至3个环氮原子的5或6元杂环核；L为含有1至8个碳原子的二价脂肪族连接基；T为含有1至10个碳原子的脂肪族末端基；m为0或1；n为0至4的整数；p为2至4的整数。
• Tone control of photographic images
  申请人：Eastman Kodak Company

  公开号：US05292627A1

  公开（公告）日：1994-03-08

  Monocyclic and polycyclic azoles having the following formula modify the tone of a silver image formed from a fine grain radiation sensitive silver bromide or silver bromoiodide emulsion layer in which the silver bromide or silver bromoiodide grains have a mean equivalent circular diameter of less than 0.3 .mu.m. The azoles have the formula: ##STR1## wherein Z is --N.dbd. or --C(R.sup.5).dbd. where R.sup.5 is hydrogen, --NH.sub.2, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms; R.sup.4 is hydrogen, aliphatic of 1 to 8 carbon atoms or aromatic of 1 to 8 carbon atoms; R.sup.4 and R.sup.5 together complete a 5 or 6 membered heterocyclic nucleus containing 1 to 3 ring nitrogen atoms; L is a divalent aliphatic linking group containing 1 to 8 carbon atoms; T is an aliphatic terminal group containing 1 to 10 carbon atoms; m is 0 or 1; n is an integer of 1 to 4; and p is an integer of 2 to 4.

  具有以下公式的单环和多环唑类化合物可以修改由细粒辐射敏感的银溴化银或银溴碘化银乳剂层形成的银图像的色调，其中银溴化银或银溴碘化银晶粒的平均等效圆直径小于0.3微米。唑类化合物的公式如下：##STR1##其中Z是--N.dbd.或--C（R.sup.5）.dbd.，其中R.sup.5是氢，--NH.sub.2，1至8个碳原子的脂肪基或1至8个碳原子的芳香基；R.sup.4是氢，1至8个碳原子的脂肪基或1至8个碳原子的芳香基；R.sup.4和R.sup.5一起形成一个含有1至3个环氮原子的5或6元杂环核；L是含有1至8个碳原子的二价脂肪链连接基；T是含有1至10个碳原子的脂肪末端基；m为0或1；n为1至4的整数；p为2至4的整数。
• Kabachnik,M.I.; Godovikov,N.N., Journal of general chemistry of the USSR, 1963, vol. 33, p. 1888 - 1891
  作者：Kabachnik,M.I.、Godovikov,N.N.

  DOI：——

  日期：——
• Guseinov,Kh.K. et al., Journal of Organic Chemistry USSR (English Translation), 1973, vol. 9, p. 717 - 719
  作者：Guseinov,Kh.K. et al.

  DOI：——

  日期：——