4,4'-methylene-bis[3-methoxy]benzenamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-methylene-bis[3-methoxy]benzenamine
• 英文别名: 4,4'-methylenedi(3-methoxyaniline)；4,4'-Methanediylbis(3-methoxyaniline)；4-[(4-amino-2-methoxyphenyl)methyl]-3-methoxyaniline
• 化学式: C₁₅H₁₈N₂O₂
• 分子量: 258.32
• InChiKey: JONHCPXLZRZWKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4,4'-methylene-bis[3-methoxy]benzenamine 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 N-{4-[4-(maleimido)-2-methoxybenzyl]-2-methoxyphenyl}imide of endo,exo-1,2,3,4,11,11-hexachlorotricyclo[6.2.1.0^5,10]undec-2-ene-7,8-dicarboxylic acid
  参考文献：
  名称：

  Synthesis of polychlorinated mono- and bisimides of cyclic dicarboxylic acids containing diene-dienophile fragments

  摘要：

  Polychlorinated diene-dienophile mono- and bisimides formed at the acylation of N-aminoimides of 1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3- and endo,exo-1,2,3,4,11,11-hexachlorotricyclo[6.2.1.0(5,10)]-undec-2-ene-7,8-dicarboxylic acids with maleic anhydride in DMF.

  DOI：

  10.1134/s1070428014020122
• 作为产物：
  描述：

  间氨基苯甲醚 、 1,3,5,7-四氮杂三环[3.3.2.2(3,7)]十二烷 以 乙醇 、 水 为溶剂， 反应 8.0h， 以46%的产率得到4,4'-methylene-bis[3-methoxy]benzenamine
  参考文献：
  名称：

  AN EFFICIENT APPROACH TO 1,3,5-TRIS-ARYLHEXAHYDRO-1,3,5-TRIAZINES

  摘要：

  In this paper we report a facile and efficient procedure for the synthesis of 1,3,5-tris-arylhexahydro-1,3,5-triazines (3) by reaction of anilines 1 with 1,3,6,8-tetrazatricyclo[4.4.1.1(3.8)]- dodecane (TATD) (2). The diequatorial chair conformational preference of 3b (Ar = p-tolyl) in the solid state was established by X-ray crystallography and agrees well with molecular mechanics calculations.

  DOI：

  10.1081/scc-120003638

文献信息

• Hydrogenation of aromatic amines to alicyclic amines using a lithium aluminate-based catalyst
  申请人：Vedage Ananda Gamini

  公开号：US20070066849A1

  公开（公告）日：2007-03-22

  The present invention relates to processes for the catalytic hydrogenation of aromatic amines to their acyclic counterparts using a ruthenium catalyst on a lithium aluminate support. The hydrogenation process comprises contacting an aromatic amine with hydrogen in the presence of a ruthenium catalyst under temperature and pressure conditions suitable to effect ring hydrogenation. The process is especially useful for hydrogenating aniline to cyclohexylamine.

  本发明涉及使用锂铝酸盐支撑上的钌催化剂进行芳香胺的催化氢化反应，将其转化为其非环状对应物的过程。氢化过程包括在适宜于环氢化的温度和压力条件下，在钌催化剂存在下将芳香胺与氢气接触。该过程特别适用于将苯胺氢化为环己胺。
• PHOTOSENSITIVE RESIN COMPOSITION, POLYAMIDE RESIN, METHOD FOR PRODUCING POLYAMIDE RESIN, COMPOUND, METHOD FOR PRODUCING COMPOUND, METHOD FOR PRODUCING CURED FILM, AND CURED FILM
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20180107114A1

  公开（公告）日：2018-04-19

  A photosensitive resin composition capable of forming a cured film with satisfactory adhesion to substrates and excellent transparency, a polyamide resin which is used in the photosensitive resin composition, a method for producing the polyamide resin, a compound which is used as a raw material of the polyamide resin, a method for producing the compound, a method for producing a cured film using the photosensitive resin composition, and a cured film which is obtained by curing the photosensitive resin composition. The photosensitive resin composition including a resin and a photopolymerization initiator. The resin is a polyamide resin including a structural unit, which includes a specific saturated alicyclic skeleton, and at least one carboxy group esterified by a unit containing a polymerizable group of a predetermined structure.

  一种具有良好粘附性和优异透明度的光敏树脂组合物，用于形成固化膜，其中包括用于光敏树脂组合物的聚酰胺树脂，制备聚酰胺树脂的方法，用作聚酰胺树脂原料的化合物，制备该化合物的方法，使用光敏树脂组合物制备固化膜的方法，以及通过固化光敏树脂组合物获得的固化膜。光敏树脂组合物包括树脂和光聚合引发剂。该树脂是一种聚酰胺树脂，包括结构单元，其中包括特定的饱和脂环骨架，以及至少一个由具有预定结构的可聚合基含有的单元酯化的羧基。
• Novel diamine compounds, production of the same and polyamideimide resins produced therefrom
  申请人：TOMOEGAWA PAPER CO. LTD.

  公开号：EP0387106A1

  公开（公告）日：1990-09-12

  A diamine compound represented by general formula (I). wherein R is a C₁-C₁₂ alkylene group which is unsubstituted or substituted, a group of formula (II) where R¹ and R², which are the same or different, each represents a hydrogen atom, a lower alkyl group, a halogen atom, a nitrile group, a nitro group, an alkoxy group or a hydroxyl group, or a group of formula (III) where R¹ and R² have the same meanings as defined above, and Z is a simple chemical bond, -O-, >C=O, -CH₂-, -S-, -­SO-, or -SO₂-. The diamine compound is produced by reducing a dinitro compound of general formula (IV) wherein R has the same meaning as defined above. Imidation of the diamine compound with a tetracarboxylic acid dianhydride produces a polyamideimide resin having a repeating unit represented by general formula (V) : wherein Ar and Ar¹, which are the same or different, each represents a tetravalent aromatic residue to which two pairs of carbonyl groups are attached directly at four carbon atoms thereof, respectively, the two carbonyl groups in each one of the two pairs of carbonyl groups being attached to neighboring carbon atoms; R³ is a group of general formula (VI) below: where R has the same meaning as defined above; R⁴ is a divalent organic residue selected from aliphatic, aromatic and alicyclic groups other than those represented by R³; and m and n are each zero or a positive integer which satisfy m ≧ 2n.

  通式 (I) 所代表的二胺化合物。 其中 R 是未取代或取代的 C₁-C₁₂亚烷基、式 (II) 的基团 其中 R¹ 和 R² 相同或不同，各自代表一个氢原子、一个低级烷基、一个卤素原子、一个腈基、一个硝基、一个烷氧基或一个羟基，或一个式 (III) 基团 其中 R¹ 和 R² 的含义与上述定义相同，Z 为简单化学键、-O-、>C=O、-CH₂-、-S-、-SO- 或 -SO₂-。二胺化合物是通过还原通式 (IV) 的二硝基化合物制得的 其中 R 的含义与上述定义相同。用四羧酸二酐对二胺化合物进行酰亚胺化，可生成具有通式 (V) 所代表重复单元的聚酰胺酰亚胺树脂： 其中 Ar 和 Ar¹相同或不同，各自代表四价芳香族残基，其中两对羰基分别直接连接在其四个碳原子上，两对羰基中的每一个中的两个羰基连接在相邻的碳原子上；R³是下式通式(VI)的基团： 其中 R 的含义与上文定义相同；R⁴ 是二价有机残基，选自 R³ 所代表基团以外的脂肪族、芳香族和脂环族基团；m 和 n 均为零或满足 m ≧ 2n 的正整数。
• Verfahren zur Herstellung von Polyamidsäuren und Polyimiden
  申请人：BASF Lacke + Farben AG

  公开号：EP0437732A1

  公开（公告）日：1991-07-24

  Verfahren zur Herstellung von Polyamidsäuren und davon abgeleiteten Polyimiden, wobei Tetracarbonsäuredianhydride mit Halbaminalen von Diaminen, die zumindest zu 10 % in der Halbaminalform vorliegen, zur Polyamidsäure umgesetzt werden.

  一种制备聚氨基甲酸酯及其衍生的聚酰亚胺的工艺，其中四羧酸二酐与二胺的半氨基（其中至少 10%以半氨基形式存在）反应生成聚氨基甲酸酯。
• TREATING AGENT FOR LIQUID CRYSTAL ALIGNMENT LAYER AND LIQUID CRYSTAL DEVICE USING THE SAME, AND METHOD FOR ALIGNMENT OF LIQUID CRYSTAL
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1111442A1

  公开（公告）日：2001-06-27

  Object Liquid crystal-alignment agent where uniform liquid alignment of liquid crystals is effectively manifested by the irradiation with light over the liquid crystal alignment film without rubbing treatment of the liquid crystal alignment film thereof, and further manifests liquid crystal alignment with high stability and high light resistance, liquid crystals device with the use of said alignment agent and the method of the liquid crystal alignment by the use of said liquid crystal alignment agent. Constitution Liquid crystal alignment agent where polymer compound having bonds shown in the general formula (1) - (7) below wherein R1, R2 and R3 are independently of each other hydrogen, alkyl, substituted alkyl, aryl or propargyl; in the polymer compound thereof with number-average molecular weight of 1,000 - 300,000, and said bond makes the direct bond with either divalent or trivalent aromatic group at the both ends of said bond or with divalent or trivalent aromatic group making the direct bond at one end while at the other forming the direct bond with divalent or trivalent alicyclic hydrocarbon group, liquid crystal device by the use of said liquid crystal alignment agent and the method of the liquid crystal alignment by the use of said liquid crystal alignment agent.

  目标 无需对液晶对位膜进行摩擦处理，通过对液晶对位膜进行光照射，即可有效实现液晶的均匀液态对位，并进一步实现高稳定性和高耐光性液晶对位的液晶对位剂、使用所述对位剂的液晶装置以及使用所述液晶对位剂的液晶对位方法。 构成 液晶配向剂，其中的聚合物化合物具有以下通式（1）-（7）所示的键 其中 R1、R2 和 R3 相互独立地为氢、烷基、取代烷基、芳基或丙基；在其平均分子量为 1,000 - 300,000 的聚合物化合物中，所述键在所述键的两端与二价或三价芳香族基团直接键合，或在一端与二价或三价芳香族基团直接键合，而在另一端与二价或三价脂环烃基团直接键合，通过使用所述液晶配向剂的液晶装置和通过使用所述液晶配向剂的液晶配向方法。