benzyl-dithiooxalamide | 78553-99-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyl-dithiooxalamide
• 英文别名: Benzyl-dithiooxalamid；N-benzyldithiooxamide；N'-benzylethanedithioamide
• CAS: 78553-99-8
• 化学式: C₉H₁₀N₂S₂
• 分子量: 210.324
• InChiKey: TXDHOALEDWPQRG-UHFFFAOYSA-N

物化性质

• 熔点：
  86-87 °C(Solv: ligroine (8032-32-4))
• 沸点：
  356.0±35.0 °C(Predicted)
• 密度：
  1.304±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  氰化钾 、 异硫氰酸苯甲酯 生成 benzyl-dithiooxalamide
  参考文献：
  名称：

  Kumelj; Tisler, 1958, vol. 5, p. 69,72

  摘要：

  DOI：

文献信息

• Monosubstituted dithiooxamide compounds and their use
  申请人：——

  公开号：US05124308A1

  公开（公告）日：1992-06-23

  This invention concerns monosubstituted dithiooxamides, and a preferred class comprises those wherein the substituent is such that the resulting dithiooxamide derivative is substantially nonvolatile at about room temperature. Preferred materials are those for which when the monosubstituent dithiooxamide is complexed with a transition metal cation, the resulting polymer is substantially a dark, i.e., preferably blue or blue-black color. Carbonless paper constructions involving use of N-(monosubstituted)dithiooxamides to advantage are described.

  该发明涉及单取代的二硫氧酰胺，其中首选类别包括那些取代基使得得到的二硫氧酰胺衍生物在室温下基本上是非挥发性的。首选材料是当单取代的二硫氧酰胺与过渡金属阳离子配合时，所得到的聚合物基本上是深色的，即优选为蓝色或蓝黑色。描述了利用N-(单取代)二硫氧酰胺优势构建无碳纸的构造。
• Preparation of monosubstituted dithiooxamide compounds
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0431783A1

  公开（公告）日：1991-06-12

  This invention relates to the synthesis of N-­(monosubstituted)dithiooxamides by the transamination of dithiooxamide. Preferred methods, according to the present invention, take advantage of the discovery that yields of N-(monosubstituted)dithiooxamides can be improved in the Wallach Reaction by: controlling the temperature of the reaction mixture; optimizing the initial concentration of the reactants; adding an effective amount of acid in the quenching or processing procedure; and/or, optionally, adding an effective amount of certain nitrogen bases to the reaction mixture.

  本发明涉及通过二硫代草酰氨的反式合成 N-(单取代)二硫代草酰氨。根据本发明，优选的方法利用了以下发现：通过控制反应混合物的温度；优化反应物的初始浓度；在淬火或处理过程中加入有效量的酸；和/或，选择性地在反应混合物中加入有效量的某些氮碱，可以提高瓦拉几反应中 N-（单取代）二硫代恶酰胺的产量。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• Kibbel, H. U.; Kuecken, M.; Peters, E., Journal fur praktische Chemie (Leipzig 1954), 1981, vol. 323, # 1, p. 41 - 48
  作者：Kibbel, H. U.、Kuecken, M.、Peters, E.、Weber, H.

  DOI：——

  日期：——