| 474902-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 474902-50-6
• 化学式: C₆₂H₇₂N₈Zr
• 分子量: 1020.53
• InChiKey: PPXYMKOSDPVFDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 正戊烷 以 乙醚 、 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Chiral Biarylamido Complexes of Zirconium

  摘要：

  The palladium-catalyzed arylation of 2,2'-diamino-6,6'-dimethylbiphenyl with (variously) bromo-3,5-di-tert-butylbenzene, 2-bromopyridine, 2-methylbromopyridine, bromomesitylene, and 2-bromo-4-methylanisole gives three C-2-symmetric and three C-1-symmetric biaryl-bridged diamino proligands H2L. The subsequent amine elimination (protonolysis) reactions of these with tetrakis(dimethylamido)zirconium yields a range of crystalline complexes [Zr(L)(NMe2)(2)]. X-ray crystallography reveals molecular structures of five examples with ligated amido, aminopridinato, and aminoanisolato units.

  DOI：

  10.1021/om020471p
• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Chiral Biarylamido Complexes of Zirconium

  摘要：

  The palladium-catalyzed arylation of 2,2'-diamino-6,6'-dimethylbiphenyl with (variously) bromo-3,5-di-tert-butylbenzene, 2-bromopyridine, 2-methylbromopyridine, bromomesitylene, and 2-bromo-4-methylanisole gives three C-2-symmetric and three C-1-symmetric biaryl-bridged diamino proligands H2L. The subsequent amine elimination (protonolysis) reactions of these with tetrakis(dimethylamido)zirconium yields a range of crystalline complexes [Zr(L)(NMe2)(2)]. X-ray crystallography reveals molecular structures of five examples with ligated amido, aminopridinato, and aminoanisolato units.

  DOI：

  10.1021/om020471p