1,6-dimesitylhexane | 137512-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,6-dimesitylhexane
• 英文别名: 1,6-Dimesityl-hexan；1,3,5-trimethyl-2-[6-(2,4,6-trimethylphenyl)hexyl]benzene
• CAS: 137512-85-7
• 化学式: C₂₄H₃₄
• 分子量: 322.534
• InChiKey: DWKYGFRSBKPWTK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1-二氯甲醚 、 1,6-dimesitylhexane 在 四氯化钛 作用下， 以 二氯甲烷 为溶剂， 反应 15.0h， 以84%的产率得到1,6-di-(3-formyl-2,4,6-trimethylphenyl)hexane
  参考文献：
  名称：

  Synthesis of sterically hindered aromatic dialdehydes

  摘要：

  A study was carried out on the formylation of a series of aromatic compounds containing two mesitylene or durene residues [dimesityl (I), dimesitylmethane (II), 1,2-dimesitylethane (III), 1,6-dimesitylhexane (IV), dimesityl sulfide (V), 1,1-dimesitylethylene (VI), 1,1-dimesityl-1-butene (VII), and didurylmethane (VIII)) by the action of dichloromethyl methyl ether (DCM) in the presence of AlCl3 and TiCl4. The corresponding dialdehydes are the major products. The formylation products when the reaction is carried out in the presence of AlCl3 in the case of (I) and (V) contain significant amounts of monoaldehydes, while partial cleavage of the substrates with the formation of products containing only one benzene ring is observed in the case of (II) and (VIII) in addition to formylation.

  DOI：

  10.1007/bf00961271
• 作为产物：
  描述：

  1,6-dimesitylhexane-1,6-dione 在 lithium aluminium tetrahydride 、 AlCl₃ etherate 作用下， 反应 1.0h， 以81%的产率得到1,6-dimesitylhexane
  参考文献：
  名称：

  Synthesis of sterically hindered aromatic dialdehydes

  摘要：

  A study was carried out on the formylation of a series of aromatic compounds containing two mesitylene or durene residues [dimesityl (I), dimesitylmethane (II), 1,2-dimesitylethane (III), 1,6-dimesitylhexane (IV), dimesityl sulfide (V), 1,1-dimesitylethylene (VI), 1,1-dimesityl-1-butene (VII), and didurylmethane (VIII)) by the action of dichloromethyl methyl ether (DCM) in the presence of AlCl3 and TiCl4. The corresponding dialdehydes are the major products. The formylation products when the reaction is carried out in the presence of AlCl3 in the case of (I) and (V) contain significant amounts of monoaldehydes, while partial cleavage of the substrates with the formation of products containing only one benzene ring is observed in the case of (II) and (VIII) in addition to formylation.

  DOI：

  10.1007/bf00961271

文献信息

• Sordes, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1932, vol. 195, p. 247
  作者：Sordes

  DOI：——

  日期：——
• YAKUBOV, A. P.;TSYGANOV, D. V.;BELENKIJ, L. I.;KRAYUSHKIN, M. M., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1700-1703
  作者：YAKUBOV, A. P.、TSYGANOV, D. V.、BELENKIJ, L. I.、KRAYUSHKIN, M. M.

  DOI：——

  日期：——
• Synthesis of sterically hindered aromatic dialdehydes
  作者：A. P. Yakubov、D. V. Tsyganov、L. I. Belen'kii、M. M. Krayushkin

  DOI：10.1007/bf00961271

  日期：1991.7

  A study was carried out on the formylation of a series of aromatic compounds containing two mesitylene or durene residues [dimesityl (I), dimesitylmethane (II), 1,2-dimesitylethane (III), 1,6-dimesitylhexane (IV), dimesityl sulfide (V), 1,1-dimesitylethylene (VI), 1,1-dimesityl-1-butene (VII), and didurylmethane (VIII)) by the action of dichloromethyl methyl ether (DCM) in the presence of AlCl3 and TiCl4. The corresponding dialdehydes are the major products. The formylation products when the reaction is carried out in the presence of AlCl3 in the case of (I) and (V) contain significant amounts of monoaldehydes, while partial cleavage of the substrates with the formation of products containing only one benzene ring is observed in the case of (II) and (VIII) in addition to formylation.