N-环己基丁烷-1,4-二胺 | 79419-72-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-环己基丁烷-1,4-二胺
• 英文名称: N-(4-aminobutyl)cyclohexylamine
• 英文别名: 4-Cyclohexylamino-butylamin；N-cyclohexylbutane-1,4-diamine；N'-cyclohexylbutane-1,4-diamine
• CAS: 79419-72-0
• 化学式: C₁₀H₂₂N₂
• 分子量: 170.298
• InChiKey: XXCZIZBMFPDINL-UHFFFAOYSA-N

物化性质

• 沸点：
  259.8±8.0 °C(Predicted)
• 密度：
  0.90±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-环己基-2-硝基苯磺酰胺 在 platinum(IV) oxide 、 氢气 、 四丁基碘化铵 、 caesium carbonate 作用下， 以 乙醇 、 氯仿 、 乙腈 为溶剂， 反应 29.0h， 生成 N-环己基丁烷-1,4-二胺
  参考文献：
  名称：

  木质素及其类似物木质部形成的化学合成和生物效应

  摘要：

  Xylemin (6) 及其设计的结构类似物 18-23，N-(4-氨基丁基) 烷基胺，通过 2-硝基苯磺酰胺 (Ns) 策略合成。对 20-23 的改进合成的研究导致从市售的相应酮一步合成这些类似物的发展。合成分子的生物学评估表明，木质素 (6) 和类似物 N-(4-氨基丁基) 环戊胺 (21) 促进了热精胺合酶 ACAULIS5 (ACL5) 的表达水平并增强了木质部的形成。此外，发现木质素 (6) 显着促进侧根形成，而木质素类似物 18 – 23 包括 21 则没有。

  DOI：

  10.1002/ejoc.202000322

文献信息

• Polyamidelastomere, ihre Herstellung und ihre Verwendung
  申请人：BAYER AG

  公开号：EP0423577A1

  公开（公告）日：1991-04-24

  Die Erfindung betrifft amorphe Polyamide mit Elastomer­charakter auf Basis von Dimerfettsäuren und speziellen prim./sek.-Diaminen und/oder speziellen disekundären Di­aminen mit einer Glastemperatur von weniger als + 10°C, die Herstellung dieser amorphen Polyamide und ihre Ver­wendung als Kautschuk, Weichmacher bzw. Schlagzähmodifi­katoren für Thermoplaste, als Weichsegmente zum Aufbau thermoplastischer Elastomerer und für andere Zwecke.

  本发明涉及以二聚体脂肪酸和特殊伯/仲二元胺和/或玻璃化转变温度低于 +10°C 的特殊仲二元胺为基础的具有弹性体特性的无定形聚酰胺、这些无定形聚酰胺的生产及其作为热塑性塑料的橡胶、增塑剂或冲击改性剂、作为热塑性弹性体结构的软段以及其他用途的使用。
• METALWORKING FLUID COMPOSITION AND METALWORKING PROCESS
  申请人：KYODO YUSHI CO., LTD.

  公开号：EP1892282A1

  公开（公告）日：2008-02-27

  The present invention provides a water-soluble metal-processing oil composition which is excellent in putrefaction resistant properties and sparingly has any bad influence upon global environment and human body and a method for processing metals which makes use of the metal-processing oil composition. The metal-processing oil composition of the invention comprises an amine carrying a linear or branched alkyl group having not less than 4 carbon atoms (component A) in an amount ranging from 0.5 to 20% and an amine carrying a cycloalkyl ring or a benzene ring (component B) in an amount ranging from 0.5 to 20% and the method for processing metals is characterized in that it uses the metal-processing oil composition.

  本发明提供了一种水溶性金属加工油组合物，它具有优异的抗腐烂性能，对全球环境和人体几乎没有任何不良影响，还提供了一种利用该金属加工油组合物加工金属的方法。 本发明的金属加工油组合物包括含有不少于 4 个碳原子的直链或支链烷基的胺 （成分 A），其用量为 0.5 至 20%；以及含有环烷基或苯环的胺（成分 B），其用量为 0.5 至 20%。
• MODIFIED BLOCK COPOLYMER, METHOD FOR PRODUCING MODIFIED BLOCK COPOLYMER, AND RESIN COMPOSITION
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP3623398A1

  公开（公告）日：2020-03-18

  A modified block copolymer according to the present invention is a modified block copolymer comprising a polymer block comprising a vinyl aromatic compound as a main constituent (A), a polymer block comprising a conjugate diene compound as a main constituent (B), and an atomic group having NHx (x = 0 to 2) (C). In the modified block copolymer, the polymer block comprising a conjugate diene compound as a main constituent (B) is a hydrogenated product, the atomic group having NHx (x = 0 to 2) (C) is contained in a side chain, and a compound forming the atomic group having NHx (x = 0 to 2) (C) satisfies the following condition: Condition: when the compound forming the atomic group having NHx (x = 0 to 2) (C) is reacted with a maleic anhydride-modified group in a maleic anhydride-modified block copolymer, a MFR value at 230°C under a load of 2.16 kg of the modified block copolymer after the reaction is 0.1 times or more a MFR value at 230°C under a load of 2.16 kg of the maleic anhydride-modified block copolymer before the reaction.

  根据本发明，改性嵌段共聚物是一种改性嵌段共聚物，包括以乙烯基芳香族化合物为主要成分的聚合物嵌段（A）、以共轭二烯化合物为主要成分的聚合物嵌段（B）和具有 NHx（x = 0 至 2）的原子团（C）。在改性嵌段聚合物中，由共轭二烯化合物作为主要成分（B）的聚合物嵌段是氢化产物，具有 NHx（x = 0 至 2）（C）的原子团包含在侧链中，形成具有 NHx（x = 0 至 2）（C）的原子团的化合物满足以下条件： 条件：当形成具有 NHx（x = 0 至 2）(C)的原子团的化合物与马来酸酐改性嵌段共聚物中的马来酸酐改性基团反应时，反应后在 230℃、负载 2.16 千克改性嵌段共聚物时的 MFR 值是反应前在 230℃、负载 2.16 千克马来酸酐改性嵌段共聚物时的 MFR 值的 0.1 倍或以上。
• Modified block copolymer, method for producing modified block copolymer, and resin composition
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：US11124593B2

  公开（公告）日：2021-09-21

  A modified block copolymer according to the present invention is a modified block copolymer comprising a polymer block comprising a vinyl aromatic compound as a main constituent (A), a polymer block comprising a conjugate diene compound as a main constituent (B), and an atomic group having NHx (x=0 to 2) (C). In the modified block copolymer, the polymer block comprising a conjugate diene compound as a main constituent (B) is a hydrogenated product, the atomic group having NHx (x=0 to 2) (C) is contained in a side chain, and a compound forming the atomic group having NHx (x=0 to 2) (C).

  根据本发明，改性嵌段共聚物是一种改性嵌段共聚物，包括以乙烯基芳香族化合物为主要成分的聚合物嵌段（A）、以共轭二烯化合物为主要成分的聚合物嵌段（B）和具有 NHx（x=0 至 2）的原子团（C）。在改性嵌段共聚物中，由共轭二烯化合物作为主要成分（B）的聚合物嵌段是氢化产物，具有 NHx（x=0 至 2）（C）的原子团包含在侧链中，以及形成具有 NHx（x=0 至 2）（C）的原子团的化合物。
• Rewritable optical information recording medium, recording and reproducing methods, as well as recording and reproducing apparatus
  申请人：Tamada Sakuya

  公开号：US20060088786A1

  公开（公告）日：2006-04-27

  A rewritable optical information recording medium including a recording layer composed of an organic dye film is provided, in which recording and erasing information can be performed reversibly by laser light irradiation. A rewritable optical information recording medium including at least one organic dye film which is substantially made of only at least one kind of organic dye compounds as a recording film is provided. The recording and erasure of information are performed by a reversible physical change of the organic dye film substance caused by laser light irradiation. Specifically, data recording is performed by a physical change locally caused by the irradiation of recording laser light, data reproduction is performed by detecting change in intensity of returned light of reproducing laser light having less power than the recording laser light, and data erasure is performed by applying at least once continuous light or pulse light having laser power more than the reproducing laser light and less than the recording laser light. The physical change is a change in shape.