2-((2-(1H-benzo[d]imidazol-2-yl)hydrazineylidene)methyl)-4,6-di-tert-butylphenol | 1010069-27-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2-((2-(1H-benzo[d]imidazol-2-yl)hydrazineylidene)methyl)-4,6-di-tert-butylphenol
• CAS: 1010069-27-8
• 化学式: C₂₂H₂₈N₄O
• 分子量: 364.491
• InChiKey: VJBODEIDOYOGJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.31
• 重原子数：
  27.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  73.3
• 氢给体数：
  3.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  2-((2-(1H-benzo[d]imidazol-2-yl)hydrazineylidene)methyl)-4,6-di-tert-butylphenol 、 copper dichloride 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Novel mono-and binuclear complexes of Cu(II) with hydrazones of salicylaldehyde derivatives

  摘要：

  A series of new mono-and binuclear metal chelates of Cu(II) with ligands, which are the products of condensation of 3,5-di(tert-butyl)salicylaldehyde with hetarylhydrazines or 4-phenylsemi(thiosemi)carbazide, were synthesized. Their compositions and structures were determined by the elemental analysis, IR and H-1 NMR spectroscopies, magnetochemistry, and conductometry measurements. It was shown for the first time that in the case of hetarylhydrazones, only mononuclear complexes were formed due to steric effect of tert-butyl fragments, whereas arylhydrazones gave binuclear complexes with two Cu atoms bonded by the spin-spin interaction. The exchange parameters 2J were calculated for binuclear metal chelates.

  DOI：

  10.1134/s1070328407040112