3-acetoxy-10H-phenothiazine | 99525-91-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 3-acetoxy-10H-phenothiazine
• 英文别名: 3-acetoxy-10H-phenothiazine；acetic acid phenothiazin-3-yl ester；Essigsaeure-phenothiazin-3-ylester；3-Acetoxy-phenothiazin；3-Acetoxyphenothiazine；10H-phenothiazin-3-yl acetate
• CAS: 99525-91-4
• 化学式: C₁₄H₁₁NO₂S
• 分子量: 257.313
• InChiKey: KTCUOBWXTKQAHI-UHFFFAOYSA-N

物化性质

• 熔点：
  197.5 °C
• 沸点：
  438.1±34.0 °C(Predicted)
• 密度：
  1.291±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-acetoxy-10H-phenothiazine 在 sodium hydroxide 、 间氯过氧苯甲酸 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 20.33h， 生成 3-hydroxy-10H-phenothiazine 5,5-dioxide
  参考文献：
  名称：

  First synthesis of sulfoxides and sulfones in the 3H-phenothiazin-3-one and 5H-benzo[a]phenothiazin-5-one ring systems. Addition reactions with nucleophiles

  摘要：

  DOI：

  10.1021/jo00227a012
• 作为产物：
  描述：

  吩噻嗪-3-酮 在 吡啶 、 sodium disulfite 作用下， 以 水 、 乙酸乙酯 为溶剂， 反应 1.33h， 生成 3-acetoxy-10H-phenothiazine
  参考文献：
  名称：

  First synthesis of sulfoxides and sulfones in the 3H-phenothiazin-3-one and 5H-benzo[a]phenothiazin-5-one ring systems. Addition reactions with nucleophiles

  摘要：

  DOI：

  10.1021/jo00227a012

文献信息

• Cymerman-Craig et al., Australian Journal of Chemistry, 1956, vol. 9, p. 397,402
  作者：Cymerman-Craig et al.

  DOI：——

  日期：——
• Daneke,J.; Wanzlick,H.-W., Justus Liebigs Annalen der Chemie, 1970, vol. 740, p. 52 - 62
  作者：Daneke,J.、Wanzlick,H.-W.

  DOI：——

  日期：——
• GIRARD, YVES;HAMEL, PIERRE;THERIEN, MICHEL;SPRINGER, JAMES P.;HIRSHFIELD,+, J. ORG. CHEM., 52,(1987) N 18, 4000-4006
  作者：GIRARD, YVES、HAMEL, PIERRE、THERIEN, MICHEL、SPRINGER, JAMES P.、HIRSHFIELD,+

  DOI：——

  日期：——
• Exterior electrochromic reflective mirror element for a vehicular rearview mirror assembly
  申请人：Varaprasad V. Desaraju

  公开号：US20070184284A1

  公开（公告）日：2007-08-09

  An exterior electrochromic reflective mirror element for a vehicular exterior rearview mirror assembly comprises an electrochromic cross-linked polymeric solid film disposed between a first substrate and a second substrate. The electrochromic cross-linked polymeric solid film contacts a transparent conductive layer of the first substrate and a conductive layer comprising a metallic reflective layer of the second substrate. A visual indicator display is disposed to the rear of said second substrate and is part of a blind spot detection and display system and is actuated to emit light responsive to a detection of another overtaking vehicle in a side lane. Light emitted by the visual indicator display passes through the second substrate, through the electrochromic cross-linked polymeric solid film and through the first substrate to be viewed by a driver of the vehicle equipped with the exterior electrochromic reflective mirror element.
• VEHICULAR EXTERIOR MIRROR
  申请人：Varaprasad V. Desaraju

  公开号：US20080094685A1

  公开（公告）日：2008-04-24

  An exterior mirror suitable for use in a vehicular exterior rearview mirror assembly includes a reflective mirror element having a light transmitting substrate with a mirror reflector having a metallic reflective layer coated thereon. A visual indicator display is disposed to the rear of the light transmitting substrate and actuated to emit light when powered. Light emitted by light sources of the display passes through the light transmitting substrate so as to be viewed by a driver of the vehicle equipped with the reflective mirror element. The mirror element has portions of the metallic reflective layer at least partially removed by laser scribing to establish at least partially light transmissive portions of the mirror reflector so that light emitted by light sources, when powered, passes through the respective at least partially light transmissive portions to be viewed by a viewer viewing from the front of the reflective mirror element.