2-(1-phenylethyl)-6-pyridin-2-ylpyridine;trichlorogold | 185609-69-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(1-phenylethyl)-6-pyridin-2-ylpyridine;trichlorogold
• CAS: 185609-69-2
• 化学式: C₁₈H₁₆AuCl₃N₂
• 分子量: 563.664
• InChiKey: LLZFGJFONJZRQM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-(1-phenylethyl)-6-pyridin-2-ylpyridine;trichlorogold 以 水 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of gold(III) adducts and cyclometallated derivatives with 6-benzyl- and 6-alkyl-2,2′-bipyridines

  摘要：

  The reaction of a series of 6-substituted-2,2'-bipyridines HL (N(2)C(10)H(7)R, R = CH(2)Ph, CHMePh, CMe(2)Ph, CH(2)Me, CMe(3) or CH(2)CMe(3)) with HAuCl4 or Na[AuCl4] has been investigated. Under different experimental conditions, salts [H(2)L][AuCl4], adducts [Au(HL)Cl-3] or cyclometallated derivatives [Au(L)Cl][X] (X = AuCl4, BF4 or PF6) have been isolated. The cyclometallated species arise from direct activation of a C-H bond either of a phenyl or a methyl substituent. The structures of an adduct [Au{N2C10H7(CHMePh)-6}Cl-3] and two metallated species [Au{N2C10H7(CMe(2)C(6)H(4))-6}Cl][AuCl4] and [Au{N2C10H7(CMe(2)CH(2))-6}Cl][BF4] . 0.5H(2)O have been determined by X-ray diffraction. In the adduct the gold atom is bonded to the nitrogen atom of the unsubstituted pyridine ring: a long-range interaction with the other nitrogen atom is observed, Au ... N 2.758(4) Angstrom. In the two cyclometallated species the bipyridines act as tridentate N,N,C anions, giving a [5,6] and a [5,5]-fused ring system, respectively. In [Au{N2C10H7(CMe(2)C(6)H4)-6}Cl](+) the hexaatomic N,C ring adopts a boat-like conformation: the structure reveals a rather short interaction between one hydrogen of the Me group in axial position and the gold atom, Au ... H2.62 Angstrom. The pentaatomic N,C ring in [Au{N2C10H7(CMe(2)CH(2))-6}Cl](+) is not planar: the co-ordination around the gold atom is essentially square planar. The new cyclometallated complexes [Au(N,N,C)Cl](+) are compared with those derived from similarly substituted pyridines described previously.

  DOI：

  10.1039/dt9960004217
• 作为产物：
  描述：

  四氯金酸水合物 、 6-(1-methylbenzene)-2-(2'-pyridyl)pyridine 以 水 、 乙腈 为溶剂， 以80%的产率得到2-(1-phenylethyl)-6-pyridin-2-ylpyridine;trichlorogold
  参考文献：
  名称：

  Synthesis and characterization of gold(III) adducts and cyclometallated derivatives with 6-benzyl- and 6-alkyl-2,2′-bipyridines

  摘要：

  The reaction of a series of 6-substituted-2,2'-bipyridines HL (N(2)C(10)H(7)R, R = CH(2)Ph, CHMePh, CMe(2)Ph, CH(2)Me, CMe(3) or CH(2)CMe(3)) with HAuCl4 or Na[AuCl4] has been investigated. Under different experimental conditions, salts [H(2)L][AuCl4], adducts [Au(HL)Cl-3] or cyclometallated derivatives [Au(L)Cl][X] (X = AuCl4, BF4 or PF6) have been isolated. The cyclometallated species arise from direct activation of a C-H bond either of a phenyl or a methyl substituent. The structures of an adduct [Au{N2C10H7(CHMePh)-6}Cl-3] and two metallated species [Au{N2C10H7(CMe(2)C(6)H(4))-6}Cl][AuCl4] and [Au{N2C10H7(CMe(2)CH(2))-6}Cl][BF4] . 0.5H(2)O have been determined by X-ray diffraction. In the adduct the gold atom is bonded to the nitrogen atom of the unsubstituted pyridine ring: a long-range interaction with the other nitrogen atom is observed, Au ... N 2.758(4) Angstrom. In the two cyclometallated species the bipyridines act as tridentate N,N,C anions, giving a [5,6] and a [5,5]-fused ring system, respectively. In [Au{N2C10H7(CMe(2)C(6)H4)-6}Cl](+) the hexaatomic N,C ring adopts a boat-like conformation: the structure reveals a rather short interaction between one hydrogen of the Me group in axial position and the gold atom, Au ... H2.62 Angstrom. The pentaatomic N,C ring in [Au{N2C10H7(CMe(2)CH(2))-6}Cl](+) is not planar: the co-ordination around the gold atom is essentially square planar. The new cyclometallated complexes [Au(N,N,C)Cl](+) are compared with those derived from similarly substituted pyridines described previously.

  DOI：

  10.1039/dt9960004217