(N-(2-[(2-bis(2-pyridylmethyl)aminoethyl)methylamino]ethyl)-2,2-dimethylpropionamide)hydroperoxocopper(II)(1+) | 623924-54-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N-(2-[(2-bis(2-pyridylmethyl)aminoethyl)methylamino]ethyl)-2,2-dimethylpropionamide)hydroperoxocopper(II)(1+)
• CAS: 623924-54-9
• 化学式: C₂₂H₃₄CuN₅O₃
• 分子量: 480.09
• InChiKey: FFRSBHKEHQRXNO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (N-(2-[(2-bis(2-pyridylmethyl)aminoethyl)methylamino]ethyl)-2,2-dimethylpropionamide)copper(II) perchlorate 、 双氧水 在 Et₃N 作用下， 以 乙腈 为溶剂， 生成 (N-(2-[(2-bis(2-pyridylmethyl)aminoethyl)methylamino]ethyl)-2,2-dimethylpropionamide)hydroperoxocopper(II)(1+)
  参考文献：
  名称：

  Copper Hydroperoxo Species Activated by Hydrogen-Bonding Interaction with Its Distal Oxygen

  摘要：

  A novel copper(II)-OOH complex with functional ligand that can form a hydrogen bond with the distal oxygen of hydroperoxide has been designed and prepared as a structural/functional model of dopamine beta-hydroxylases, whose spectroscopic characterization and decomposition rates have indicated that the hydroperoxide is activated through the hydrogen-bonding interaction with the distal oxygen.

  DOI：

  10.1021/ic035080x